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1. 发明授权

US4992202A Non-linear optics 失效
标题翻译：非线性光学
公开(公告)号：US4992202A
公开(公告)日：1991-02-12
申请号：US420719
申请日：1989-10-13
申请人： Simon Allen , Paul F. Gordon , John O. Morley
发明人： Simon Allen , Paul F. Gordon , John O. Morley
IPC分类号： G02F1/35 , C07D231/06 , G02F1/355 , G02F1/361
CPC分类号： C07D231/06 , C09K19/54 , C09K19/586 , G02F1/3612
摘要： Optical elements having non-linear optical properties comprising a compound of the formula: ##STR1## wherein E is an electron donorA is an electron acceptor;and W, X, Y & Z are each independently H or any group capable of attachment to the pyrazolyl ring; in which the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and compounds of formula I.
摘要翻译：具有非线性光学性质的光学元件包括下式化合物：其中E是电子给体A是电子受体; 并且W，X，Y和Z各自独立地为H或能够连接到吡唑基环的任何基团; 其中化合物的分子对准，使得元件具有净非中心对称性，其制备方法，包含这些元件的光学器件和式I化合物。

2. 发明授权

US4992203A Non-linear optics 失效
标题翻译：非线性光学
公开(公告)号：US4992203A
公开(公告)日：1991-02-12
申请号：US420720
申请日：1989-10-13
申请人： Simon Allen , Paul F. Gordon , John O. Morley
发明人： Simon Allen , Paul F. Gordon , John O. Morley
IPC分类号： C07D231/06 , C09K19/52 , G02F1/065 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3612 , C09K19/54 , C09K19/586 , G02F1/065
摘要： Optical elements having non-linear optical properties comprising a compound of the formula: ##STR1## wherein D is an electron donorA is an electron acceptor;and W, X, Y and Z are each independently H or any group capable of attachment to the pyrazolyl ring; in which the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and compounds of formula I.
摘要翻译：具有非线性光学性质的光学元件包括下式化合物：其中D是电子给体A是电子受体; 并且W，X，Y和Z各自独立地为H或能够连接至吡唑基环的任何基团; 其中化合物的分子对准，使得元件具有净非中心对称性，其制备方法，包含这些元件的光学器件和式I化合物。

3. 发明授权

US4965020A Non-linear optical device 失效
标题翻译：非线性光学器件
公开(公告)号：US4965020A
公开(公告)日：1990-10-23
申请号：US10610
申请日：1987-02-04
申请人： Simon Allen , Paul F. Gordon , John O. Morley
发明人： Simon Allen , Paul F. Gordon , John O. Morley
IPC分类号： G02B6/12 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3613 , G02F1/3611 , G02F1/3612
摘要： Optical elements comprising a non-centrosymmetric compound comprising an electron donor and an electron acceptor linked by a conjugated bridging group, in which the electron acceptor is a nitroso group, in which element the molecules of the compound are aligned so that the element has a net non-centrosymmetry, a method for their preparation, optical devices comprising such elements, and some of the compounds.
摘要翻译：光学元件包括包含电子给体的非中心对称化合物和通过共轭桥接基团连接的电子受体，其中电子受体是亚硝基，其中化合物的分子被排列成使得元件具有网非中心对称性，其制备方法，包含这些元素的光学器件和一些化合物。

4. 发明授权

US4804747A Azo compound having one or two aliphatic or cycloaliphatic groups containing a total of 8 to 40 carbon atoms therein 失效
标题翻译：具有一个或两个含有总共8至40个碳原子的脂族或脂环族基团的偶氮化合物
公开(公告)号：US4804747A
公开(公告)日：1989-02-14
申请号：US919640
申请日：1986-10-16
申请人： Simon Allen , Paul F. Gordon , Richard A. Hann
发明人： Simon Allen , Paul F. Gordon , Richard A. Hann
IPC分类号： C09B29/01 , G02F1/361 , G02F1/377 , C09B29/06 , C09B29/08 , C09B29/09
CPC分类号： G02F1/3612 , C09B29/0007 , G02F1/3611 , G02F1/3614 , G02F1/377 , Y10S430/141 , Y10S430/146 , Y10S534/02
摘要： (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is S, O, ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 and R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 and R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; andR.sup.6 and R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; orR.sup.4 and R.sup.6 together comprise ring fused to Ring A and R.sup.5 and R.sup.7 are as hereinbefore defined; orR.sup.5 and R.sup.7 together comprise ring fused to Ring A and R.sup.4 and R.sup.6 are as hereinbefore defined; orR.sup.2 and R.sup.4 together with the N atom to which R.sup.2 is attached form a ring fused to Ring A and R.sup.3 and R.sup.5 are as hereinbefore defined; orR.sup.3 and R.sup.5 together with the N atom to which R.sup.3 is attached form a ring fused to Ring A and R.sup.2 and R.sup.4 are as hereinbefore defined;provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by R.sup.2, R.sup.3, R.sup.4 and R.sup.5 ;(ii) an optical element comprising a compound of Formula I having non-linear optical (NLO) properties for use in the generation of NLO signals,(iii) a method of preparation of such an optical element comprising a plurality of monomolecular layers of the compound of Formula I on the surface of a transparent or reflecting substrate by a Langmuir-Blodgett technique; and(iv) an optical device incorporating such an optical element.
摘要翻译：（i）下式的化合物：其中R是H，金属或含有四价N原子的基团; X为S，O，R1为NO2，CN或COOY; Y是H，C 1-4 - 烷基，金属或含有四价N原子的基团; R2和R3各自独立地为H或含有至多30个碳原子的非亲水性脂族或脂环族基团; R4和R5各自独立地为H或含有至多30个碳原子的非亲水脂族或脂环族基团; 并且R 6和R 7各自独立地为H或含有至多4个碳原子的非亲水基团; 或R 4和R 6一起包含稠环至环A的环，R 5和R 7如上文所定义; 或者R 5和R 7一起包含与环A稠合的环，R 4和R 6如上文所定义; 或R 2和R 4与R 2所连接的N原子一起形成稠环至环A的环，且R 3和R 5如上所定义; 或R3和R5与R3所连接的N原子一起形成稠环至环A的环，R2和R4如上所定义; 条件是在一个或两个独立由R 2，R 3，R 4和R 5表示的基团中总共有8至40个碳原子; （ii）包含具有用于产生NLO信号的非线性光学（NLO）性质的式I化合物的光学元件，（iii）制备这种光学元件的方法，该光学元件包括多个单分子层通过Langmuir-Blodgett技术在透明或反射底物的表面上的式I化合物; 和（iv）包含这种光学元件的光学装置。

5. 发明授权

US5047516A Azo compound suitable for use in non-linear optics 失效
标题翻译：适用于非线性光学的偶氮化合物
公开(公告)号：US5047516A
公开(公告)日：1991-09-10
申请号：US190672
申请日：1988-05-05
申请人： Simon Allen , Paul F. Gordon
发明人： Simon Allen , Paul F. Gordon
IPC分类号： G02B6/12 , C07C67/00 , C07C241/00 , C07C245/08 , C07C255/59 , C09B29/01 , C09B29/08 , C09B29/085 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3611 , C07C245/08 , C09B29/0003 , C09B29/0816 , C09K19/24 , C09K19/601
摘要： An azo compound of the formula: ##STR1## wherein R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms;m is 0 or 1;R.sup.1 is NO.sub.2, CN or COOR.sup.2 ;R.sup.2 is H or C.sub.1-4 -alkyl;n is from 1 to 4 andR.sup.3 is H, a metal or a group containing a tetravalent N atom.The compound has non-linear optical properties which make it suitable for use in an optical element such as a waveguide, for altering the characteristics of light passing through the element.

6. 发明授权

US4981612A Optical element having non-linear optical properties 失效
标题翻译：具有非线性光学特性的光学元件
公开(公告)号：US4981612A
公开(公告)日：1991-01-01
申请号：US190433
申请日：1988-05-05
申请人： Simon Allen , Paul F. Gordon , Joseph Zyss
发明人： Simon Allen , Paul F. Gordon , Joseph Zyss
IPC分类号： C09B67/22 , C09B29/01 , C09B29/08 , C09B29/36 , G02B6/12 , G02F1/313 , G02F1/35 , G02F1/355 , G02F1/361 , G02F1/37 , C09B29/06 , C07C245/08 , G11B7/24
CPC分类号： B82Y20/00 , C09B29/0003 , C09B29/0807 , C09B29/0816 , C09B29/36 , G02F1/3132 , G02F1/3618 , Y10S534/02
摘要： An optical element, such as a wave guide, having non-linear optical properties, suitable for use in optical devices in which it is desirable to alter the characteristics of the light, comprising a transparent or reflecting substrate having at least a partial superficial coating comprising alternating monolayers of a first non-linear optical (NLO) compound of the formula: ##STR1## wherein R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms;m is 1 or 2;R.sup.1 is NO.sub.2, CN or COOR.sup.2 ;R.sup.2 is H or C.sub.1-4 -alkyl;n is from 1 to 4; andR.sup.3 is H, a metal or a group containing a tetravalent N atom anda second NLO compound of the formula: ##STR2## wherein T is H, a metal or a group containing a tetravalent N atom;X is S, O, ##STR3## T.sup.1 is NO.sub.2, CN or COOY; Y is selected from H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;T.sup.2 and T.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;T.sup.4 and T.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; andT.sup.6 and T.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; orT.sup.4 and T.sup.6 together comprise ring fused to Ring A and T.sup.5 and T.sup.7 are as hereinbefore defined; orT.sup.5 and T.sup.7 together comprise ring fused to Ring A and T.sup.4 and T.sup.6 are as hereinbefore defined; orT.sup.2 and T.sup.4 together with the N atom to which T.sup.2 is attached form a ring fused to Ring A and T.sup.3 and T.sup.5 are as hereinbefore defined; orT.sup.3 and T.sup.5 together with the N atom to which T.sup.3 is attached form a ring fused to Ring A and T.sup.2 and T.sup.4 are as hereinbefore defined;provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by T.sup.2, T.sup.3, T.sup.4 and T.sup.5.

7. 发明授权

US4946629A Optical element having non-linear optical properties including a substrate having a coating of an azo compound 失效
标题翻译：具有非线性光学特性的光学元件包括具有偶氮化合物涂层的基底
公开(公告)号：US4946629A
公开(公告)日：1990-08-07
申请号：US274926
申请日：1988-11-25
申请人： Simon Allen , Paul F. Gordon , Richard A. Hann
发明人： Simon Allen , Paul F. Gordon , Richard A. Hann
IPC分类号： C09B29/01 , G02F1/361 , G02F1/377 , G02B1/04 , G02B1/08 , G02B6/00
CPC分类号： G02F1/3612 , C09B29/0007 , G02F1/3611 , G02F1/3614 , G02F1/377 , Y10S430/141 , Y10S430/146 , Y10S534/02
摘要： (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 & R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 & R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;and R.sup.6 & R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms;or R.sup.4 & R.sup.6 together comprise ring fused to Ring A and R.sup.5 & R.sup.7 are as hereinbefore defined;or R.sup.5 & R.sup.7 together comprise ring fused to Ring A and R.sup.4 & R.sup.6 are as hereinbefore defined;or R.sup.2 & R.sup.4 together with the N atom to which R.sup.2 is attached from a ring fused to Ring A and R.sup.3 & R.sup.5 are as hereinbefore defined;or R.sup.3 & R.sup.5 together with the N atom to which R.sup.3 is attached form a ring fused to Ring A and R.sup.2 & R.sup.4 are as hereinbefore defined;provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by R.sup.2, R.sup.3, R.sup.4 & R.sup.5 ;(ii) an optical element comprising a compound of Formula I having non-linear optical (NLO) properties for use in the generation of NLO signals.(iii) a method of preparation of such an optical element comprising a plurality of monomolecular layers of the compound of Formula I on the surface of a transparent or reflecting substrate by a Langmuir-Blodgett technique; and(iv) an optical device incorporating such an optical element.

8. 发明授权

US5137798A A pit-forming optical recording media and process for producing the same 失效
标题翻译：凹坑形成光学记录介质及其制造方法
公开(公告)号：US5137798A
公开(公告)日：1992-08-11
申请号：US548189
申请日：1990-07-05
申请人： Peter J. Duggan , Paul F. Gordon , Stephen J. Abbott , Akihiko Kuroiwa , Toshiki Aoi , Tezumbumi Kamijo
发明人： Peter J. Duggan , Paul F. Gordon , Stephen J. Abbott , Akihiko Kuroiwa , Toshiki Aoi , Tezumbumi Kamijo
IPC分类号： B41M5/26 , G03C1/72 , G11B7/24 , G11B7/244 , G11B7/248
CPC分类号： G11B7/248 , Y10S430/146 , Y10S430/165
摘要： A pit-forming optical recording medium comprises a substrate supporting a film of optically deformable recording material comprising an organic dye for absorbing optical signals of modulated electromagnetic radiation applied to the film and thereby causing corresponding deformations of the film when the signal intensities exceed predetermined threshold levels. The dye is a phthalocyanine compound or mixture of phtalocyanine compounds in which each of at least five of the peripheral carbon atoms in the 1, 4, 5, 8,9, 12, 13 or 16 positions (the "3,6-positions") of the phthalocyanine nucleus, as shown in Formula I, is linked by an atom from Group VB or Group VIB of the Periodic Table to a carbon atom of an organic radical. In preferred compounds each of the eight 3,6-positions is linked by an atom from Group VB or Group VIB, especially sulphur, selenium or nitrogen, to an organic radical. ##STR1##
摘要翻译：凹坑形成光学记录介质包括支撑光学可变形记录材料的薄膜的基底，其包含有机染料，用于吸收施加到薄膜上的调制的电磁辐射的光信号，从而当信号强度超过预定阈值水平时引起薄膜的相应变形。该染料是酞菁化合物或酞菁化合物的混合物，其中1,4,5,8,9,12,13或16位中的至少五个外周碳原子（“3,6位” ）酞菁核，如式I所示，通过元素周期表第VB族或第VIB族的原子与有机基团的碳原子连接。在优选的化合物中，八个3,6-位中的每一个通过VB或VIB族的原子，特别是硫，硒或氮连接到有机基团。我

9. 发明授权

US4894186A Substituted pyrazoline having non-linear optical properties 失效
标题翻译：具有非线性光学性质的取代吡唑啉
公开(公告)号：US4894186A
公开(公告)日：1990-01-16
申请号：US262391
申请日：1988-09-23
申请人： Paul F. Gordon , Brian Bothwell
发明人： Paul F. Gordon , Brian Bothwell
IPC分类号： C07D231/06 , C09K19/34 , G02F1/361
CPC分类号： C07D231/06 , C09K19/3483 , G02F1/3612
摘要： A compound of the formula: ##STR1## wherein E is an ethenyl group of the formula: ##STR2## in which X is H when Y is NO.sub.2 ;Y is H when X is NO.sub.2 ; orX is CN when Y is CNwhich has the capacity to form a crystal in which the molecules are aligned substantially in the same manner giving it non-linear optical properties. The crystalline product is thus adapted for use in devices exhibiting non-linear optical effects.

10. 发明授权

US4742173A Dithiene derivative 失效
标题翻译：二噻烯衍生物
公开(公告)号：US4742173A
公开(公告)日：1988-05-03
申请号：US909247
申请日：1986-09-19
申请人： Damien G. McDonnell , Paul F. Gordon , Anthony J. Hughes , David J. Thompson
发明人： Damien G. McDonnell , Paul F. Gordon , Anthony J. Hughes , David J. Thompson
IPC分类号： C07F15/00 , C09K19/40
CPC分类号： C09K19/40 , C07C321/00 , C07C323/00
摘要： A metal dithiene of the formula: ##STR1## wherein R.sup.1 is C.sub.3 to C.sub.20 alkyl;R.sup.2 is selected from alkyl, alkylamino, dialkylamino, alkylthio and alkoxy in which each alkyl contains up to 20 carbon atoms;R.sup.3 is H, halogen or a group represented by R.sup.2 ; andM is a metal selected from Groups Ib, IIb, VIIb, and VIIIb of the Periodic Table,and a composition of the metal dithiene in a liquid crystal medium. The composition is suitable for use in a light valve for a laser-addressed liquid crystal display.

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