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    • 5. 发明申请
    • Process for the Gas-Phase Polymerization of Olefins
    • 烯烃气相聚合方法
    • US20130090436A1
    • 2013-04-11
    • US13703613
    • 2011-06-09
    • Enrico BalestraTiziana CaputoAntonio MazzuccoRiccardo RinaldiSilvia Soffritti
    • Enrico BalestraTiziana CaputoAntonio MazzuccoRiccardo RinaldiSilvia Soffritti
    • C08F2/01
    • C08F2/01C08F210/06C08F2/001C08F2/34C08F210/14C08F210/16
    • A process for the gas-phase copolymerization of: (a) propylene, (b) at least one C4-C8 α-olefin, and (c) optionally ethylene, the process being carried out in a reactor having two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, leave said downcomer and are reintroduced into said riser, thus establishing a circulation of polymer between the riser and the downcomer, the gas mixture present in the riser being at least partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid barrier having a composition different from the gaseous mixture present in the riser and comprising at least one C4-C8 α-olefin in a total amount of from 0.1% to 35% by mol.
    • 一种用于气相共聚的方法:(a)丙烯,(b)至少一种C 4 -C 8α-烯烃和(c)任选的乙烯,该方法在具有两个互连的聚合区的反应器中进行,其中 生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区(提升管),离开所述提升管并进入第二个所述聚合区(降液管),通过它们以致密形式向下流动,离开所述降液管并重新引入 由此,在立管和降液管之间形成聚合物的循环,存在于提升管中的气体混合物至少部分地被阻止通过将所述降液管的上部引入到具有不同于 存在于提升管中的气态混合物包含总量为0.1%至35%摩尔的至少一种C 4 -C 8α-烯烃。
    • 6. 发明授权
    • Process for the gas-phase polymerization of olefins
    • 烯烃气相聚合方法
    • US08785572B2
    • 2014-07-22
    • US13703613
    • 2011-06-09
    • Enrico BalestraTiziana CaputoAntonio MazzuccoRiccardo RinaldiSilvia Soffritti
    • Enrico BalestraTiziana CaputoAntonio MazzuccoRiccardo RinaldiSilvia Soffritti
    • C08F2/00C08F210/00C08F110/02B01J19/00B01J8/18
    • C08F2/01C08F210/06C08F2/001C08F2/34C08F210/14C08F210/16
    • A process for the gas-phase copolymerization of: (a) propylene, (b) at least one C4-C8 α-olefin, and (c) optionally ethylene, the process being carried out in a reactor having two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, leave said downcomer and are reintroduced into said riser, thus establishing a circulation of polymer between the riser and the downcomer, the gas mixture present in the riser being at least partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid barrier having a composition different from the gaseous mixture present in the riser and comprising at least one C4-C8 α-olefin in a total amount of from 0.1% to 35% by mol.
    • 一种用于气相共聚的方法:(a)丙烯,(b)至少一种C 4 -C 8α-烯烃和(c)任选的乙烯,该方法在具有两个互连的聚合区的反应器中进行,其中 生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区(提升管),离开所述提升管并进入第二个所述聚合区(降液管),通过它们以致密形式向下流动,离开所述降液管并重新引入 由此,在立管和降液管之间形成聚合物的循环,存在于提升管中的气体混合物至少部分地被阻止通过将所述降液管的上部引入到具有不同于 存在于提升管中的气态混合物包含总量为0.1%至35%摩尔的至少一种C 4 -C 8α-烯烃。