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1. 发明授权

US07279534B2 Poly(heteroaromatic) block copolymers with electrical conductivity 失效
标题翻译：具有导电性的聚（杂芳族）嵌段共聚物
公开(公告)号：US07279534B2
公开(公告)日：2007-10-09
申请号：US10234968
申请日：2002-09-03
申请人： Silvia DeVito Luebben , Brian Elliott , Carolina Wilson
发明人： Silvia DeVito Luebben , Brian Elliott , Carolina Wilson
IPC分类号： C08F26/06 , C08F234/04
CPC分类号： C08G61/126 , C08F293/00 , C08F293/005 , C08F295/00 , C08F297/00 , C08F297/04 , C08G61/123 , C08G61/124 , C08L53/00 , C08L53/02 , C08L2666/24
摘要： The present invention provides block copolymers containing at least one block of a poly(heteroaromatic) polymer and at least two blocks of a non-conjugated polymer. The chemically different blocks of the copolymer are covalently bonded to each other in an alternating fashion through an appropriate linkage group. The poly(heteroaromatic) block may exist in its neutral or oxidized form, and when in the oxidized form, it associates with organic or inorganic counter-anions to balance the charge. The poly(heteroaromatic) polymer is an intrinsically conducting polymer (ICP), and when in the oxidized form it is electrically conducting. When the ICP block or blocks of the block copolymer are in the doped form, the block copolymer is electrically conducting. Preferably the conducting block copolymers have conductivities in the range 10−6-103 S/cm. Block copolymers of this invention are soluble or dispersible in water, one or more organic solvents, or in a mixture thereof at a level of at least about 0.1 g/liter.
摘要翻译：本发明提供含有至少一个聚（杂芳族）聚合物嵌段和至少两个非共轭聚合物嵌段的嵌段共聚物。共聚物的化学上不同的嵌段通过适当的连接基团以交替的方式彼此共价键合。聚（杂芳族）嵌段可以其中性或氧化形式存在，并且当以氧化形式时，其与有机或无机反阴离子相结合以平衡电荷。聚（杂芳族）聚合物是本征导电聚合物（ICP），当处于氧化形式时，它是导电的。当嵌段共聚物的ICP嵌段或嵌段是掺杂形式时，嵌段共聚物是导电的。优选地，导电嵌段共聚物的导电率在10 -6 -3 3 / S / cm的范围内。本发明的嵌段共聚物以至少约0.1g /升的水平可溶或分散于水，一种或多种有机溶剂或其混合物中。

2. 发明授权

US07244498B2 Nanoparticles modified with multiple organic acids 失效
标题翻译：用多种有机酸改性的纳米颗粒
公开(公告)号：US07244498B2
公开(公告)日：2007-07-17
申请号：US11120650
申请日：2005-05-03
申请人： Ronald Lee Cook , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith , Brian John Elliott , Cory Kreutzer , Carolina Wilson , Manfred Meiser
发明人： Ronald Lee Cook , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith , Brian John Elliott , Cory Kreutzer , Carolina Wilson , Manfred Meiser
IPC分类号： B32B5/66
CPC分类号： B01J2/30 , B82Y30/00 , C01P2002/72 , C01P2004/04 , C01P2004/64 , C01P2006/12 , C08K3/22 , C08K3/346 , C08K9/04 , C09C1/24 , C09C1/407 , C09D5/082 , C09D163/00 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2998 , C08L2666/54
摘要： Surface-modified nanoparticles of boehmite, and methods for preparing the same. Aluminum oxyhydroxide nanoparticles are surface modified by reaction with selected amounts of organic acids. In particular, the nanoparticle surface is modified by reactions with two or more different carboxylic acids, at least one of which is an organic carboxylic acid. The product is a surface modified boehmite nanoparticle that has an inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core and a surface-bonded organic shell. Organic carboxylic acids of this invention contain at least one carboxylic acid group and one carbon-hydrogen bond. One embodiment of this invention provides boehmite nanoparticles that have been surface modified with two or more acids one of which additional carries at least one reactive functional group. Another embodiment of this invention provides boehmite nanoparticles that have been surface modified with multiple acids one of which has molecular weight or average molecular weight greater than or equal to 500 Daltons. Yet, another embodiment of this invention provides boehmite nanoparticles that are surface modified with two or more acids one of which is hydrophobic in nature and has solubility in water of less than 15 by weight. The products of the methods of this invention have specific useful properties when used in mixture with liquids, as filler in solids, or as stand-alone entities.
摘要翻译：勃姆石的表面改性纳米颗粒及其制备方法。羟基氧化铝纳米颗粒通过与选定量的有机酸反应进行表面改性。特别地，通过与两种或多种不同羧酸的反应来修饰纳米颗粒表面，其中至少一种是有机羧酸。该产品是具有无机氢氧化铝核心或部分羟基氧化铝核心和表面键合有机壳体的表面改性勃姆石纳米颗粒。本发明的有机羧酸含有至少一个羧酸基和一个碳 - 氢键。本发明的一个实施方案提供已经用两种或多种酸进行表面改性的勃姆石纳米颗粒，其中一种还含有至少一个反应性官能团。本发明的另一个实施方案提供已经用多种酸进行表面改性的勃姆石纳米颗粒，其中一种具有大于或等于500道尔顿的分子量或平均分子量。然而，本发明的另一个实施方案提供了用两种或更多种酸进行表面改性的勃姆石纳米粒子，其中一种酸性质是疏水性的，并且在水中的溶解度小于15重量％。当与液体混合使用时，本发明方法的产品具有特定的有用特性，作为固体中的填料或作为独立实体。

3. 发明授权

US06986943B1 Surface modified particles by multi-step addition and process for the preparation thereof 失效
标题翻译：通过多步添加的表面改性颗粒及其制备方法
公开(公告)号：US06986943B1
公开(公告)日：2006-01-17
申请号：US10171402
申请日：2002-06-12
申请人： Ronald Lee Cook , Brian John Elliott , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith
发明人： Ronald Lee Cook , Brian John Elliott , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith
IPC分类号： B05D1/36 , B32B1/00
CPC分类号： C09C1/407 , B01J2/30 , B82Y30/00 , C01P2002/82 , C01P2004/64 , C09C1/24 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： The present invention relates to a new class of surface modified particles and to a multi-step surface modification process for the preparation of the same. The multi-step surface functionalization process involves two or more reactions to produce particles that are compatible with various host systems and/or to provide the particles with particular chemical reactivities. The initial step comprises the attachment of a small organic compound to the surface of the inorganic particle. The subsequent steps attach additional compounds to the previously attached organic compounds through organic linking groups.
摘要翻译：本发明涉及一类新的表面改性颗粒和一种多步表面改性方法的制备方法。多步骤表面官能化过程涉及两个或更多个反应以产生与各种主体体系相容的颗粒和/或提供具有特定化学反应性的颗粒。初始步骤包括将小的有机化合物附着到无机颗粒的表面。随后的步骤通过有机连接基团将附加的化合物连接到先前连接的有机化合物上。

4. 发明授权

US08097348B2 Pi-conjugated organoboron polymers in thin-film organic electronic devices 失效
标题翻译：在薄膜有机电子器件中的π共轭有机硼聚合物
公开(公告)号：US08097348B2
公开(公告)日：2012-01-17
申请号：US12293372
申请日：2007-03-19
申请人： Silvia DeVito Luebben , Shawn Sapp
发明人： Silvia DeVito Luebben , Shawn Sapp
IPC分类号： H01L51/54
CPC分类号： H01L51/0035 , C08G79/08 , C08G2261/94 , C09K11/06 , C09K2211/1425 , C09K2211/1433 , C09K2211/1466 , C09K2211/1475 , C09K2211/1483 , H01L51/0039 , H01L51/004 , H01L51/0043 , H01L51/008 , H01L51/0541 , H01L51/0545 , H01L51/4246 , H01L51/4253 , H01L51/5012 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： Pi-conjugated organoboron polymers for use in thin-film organic polymer electronic devices. The polymers contain aromatic and or unsaturated repeat units and boron atoms. Pi-conjugated organoboron polymers which are end capped, derivatized with solubilizing groups or both exhibit improved solubility and handling properties beneficial for the formation of thin films useful for device fabrication. The vacant p-orbital of the boron atoms conjugate with the pi-conjugated orbital system of the aromatic or unsaturated monomer units extending the pi-conjugation length of the polymer across the boron atoms. The pi-conjugated organoboron polymers are electron-deficient and, therefore, exhibit n-type semiconducting properties, photoluminescence, and electroluminescence. The invention provides thin-film organic polymer electronic devices, such as organic photovoltaic cells (OPVs), organic diodes, organic photodiodes, organic thin-film transistors (TFTs), organic field-effect transistors (OFETs), printable or flexible electronics, such as radio-frequency identification (RFID) tags, electronic papers, and printed circuit elements, organic light-emitting diodes (OLEDs), polymer light-emitting diodes (PLEDs), and energy storage devices employing the pi-conjugated organoboron polymers. In OLED and PLED applications these materials are used as the electron transport layer (ETL) to improve device efficiency. The polymers which exhibit photo- and electroluminescence are also useful as light-emitting material in PLEDs.
摘要翻译：用于薄膜有机聚合物电子器件的Pi共轭有机硼聚合物。聚合物含有芳族和/或不饱和的重复单元和硼原子。末端封端，用增溶基团衍生的P 2共轭有机硼聚合物表现出改善的溶解度和处理性能，有利于形成用于器件制造的薄膜。与芳族或不饱和单体单元的π-共轭轨道体系共轭的硼原子的空位p轨道将聚合物的π-共轭长度延伸穿过硼原子。 π共轭有机硼聚合物是电子缺陷的，因此表现出n型半导体性质，光致发光和电致发光。本发明提供薄膜有机聚合物电子器件，例如有机光伏电池（OPV），有机二极管，有机光电二极管，有机薄膜晶体管（TFT），有机场效应晶体管（OFET），可印刷或柔性电子器件作为射频识别（RFID）标签，电子纸和印刷电路元件，有机发光二极管（OLED），聚合物发光二极管（PLED）和使用π-共轭有机硼聚合物的储能装置。在OLED和PLED应用中，这些材料用作电子传输层（ETL）以提高器件效率。显示光致发光和电致发光的聚合物也可用作PLED中的发光材料。

5. 发明授权

US06887517B1 Surface modified particles by multi-step Michael-type addition and process for the preparation thereof 失效
标题翻译：通过多步迈克尔型添加的表面改性颗粒及其制备方法
公开(公告)号：US06887517B1
公开(公告)日：2005-05-03
申请号：US10171422
申请日：2002-06-12
申请人： Ronald Lee Cook , Brian John Elliott , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith
发明人： Ronald Lee Cook , Brian John Elliott , Silvia DeVito Luebben , Andrew William Myers , Bryan Matthew Smith
IPC分类号： B05D1/36 , B32B1/00 , C09C1/24 , C09C1/40 , C09C1/42 , C09C3/08 , C09C3/10
CPC分类号： C09C1/407 , B82Y30/00 , C01P2004/64 , C01P2004/84 , C01P2006/12 , C09C1/24 , C09C1/42 , C09C3/08 , C09C3/10 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A new class of surface modified particles and a multi-step Michael-type addition surface modification process for the preparation of the same is provided. The multi-step Michael-type addition surface modification process involves two or more reactions to compatibilize particles with various host systems and/or to provide the particles with particular chemical reactivities. The initial step comprises the attachment of a small organic compound to the surface of the inorganic particle. The subsequent steps attach additional compounds to the previously attached organic compounds through reactive organic linking groups. Specifically, these reactive groups are activated carbon—carbon pi bonds and carbon and non-carbon nucleophiles that react via Michael or Michael-type additions.
摘要翻译：提供了一类新的表面改性颗粒和用于其制备的多步迈克尔型添加表面改性方法。多步迈克尔型加成表面改性方法涉及两种或多种使各种主体体系相容的颗粒的反应和/或提供具有特定化学反应性的颗粒。初始步骤包括将小的有机化合物附着到无机颗粒的表面。随后的步骤通过反应性有机连接基团将附加的化合物连接到先前连接的有机化合物上。具体来说，这些反应性基团是通过迈克尔或迈克尔型添加物反应的活性碳 - 碳键和碳和非碳亲核试剂。

6. 发明申请

US20090127547A1 PI-CONJUGATED ORGANOBORON POLYMERS IN THIN-FILM ORGANIC ELECTRONIC DEVICES 失效
标题翻译：薄膜有机电子器件中的PI-CONJGGGORO ORGANOBORON聚合物
公开(公告)号：US20090127547A1
公开(公告)日：2009-05-21
申请号：US12293372
申请日：2007-03-19
申请人： Silvia DeVito Luebben , Shawn Sapp
发明人： Silvia DeVito Luebben , Shawn Sapp
IPC分类号： H01L51/30 , C08G79/08
CPC分类号： H01L51/0035 , C08G79/08 , C08G2261/94 , C09K11/06 , C09K2211/1425 , C09K2211/1433 , C09K2211/1466 , C09K2211/1475 , C09K2211/1483 , H01L51/0039 , H01L51/004 , H01L51/0043 , H01L51/008 , H01L51/0541 , H01L51/0545 , H01L51/4246 , H01L51/4253 , H01L51/5012 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要： Pi-conjugated organoboron polymers for use in thin-film organic polymer electronic devices. The polymers contain aromatic and or unsaturated repeat units and boron atoms. Pi-conjugated organoboron polymers which are end capped, derivatized with solubilizing groups or both exhibit improved solubility and handling properties beneficial for the formation of thin films useful for device fabrication. The vacant p-orbital of the boron atoms conjugate with the pi-conjugated orbital system of the aromatic or unsaturated monomer units extending the pi-conjugation length of the polymer across the boron atoms. The pi-conjugated organoboron polymers are electron-deficient and, therefore, exhibit n-type semiconducting properties, photoluminescence, and electroluminescence. The invention provides thin-film organic polymer electronic devices, such as organic photovoltaic cells (OPVs), organic diodes, organic photodiodes, organic thin-film transistors (TFTs), organic field-effect transistors (OFETs), printable or flexible electronics, such as radio-frequency identification (RFID) tags, electronic papers, and printed circuit elements, organic light-emitting diodes (OLEDs), polymer light-emitting diodes (PLEDs), and energy storage devices employing the pi-conjugated organoboron polymers. In OLED and PLED applications these materials are used as the electron transport layer (ETL) to improve device efficiency. The polymers which exhibit photo- and electroluminescence are also useful as light-emitting material in PLEDs.
摘要翻译：用于薄膜有机聚合物电子器件的Pi共轭有机硼聚合物。聚合物含有芳族和/或不饱和的重复单元和硼原子。末端封端，用增溶基团衍生的P 2共轭有机硼聚合物表现出改善的溶解度和处理性能，有利于形成用于器件制造的薄膜。与芳族或不饱和单体单元的π-共轭轨道体系共轭的硼原子的空位p轨道将聚合物的π-共轭长度延伸穿过硼原子。 π共轭有机硼聚合物是电子缺陷的，因此表现出n型半导体性质，光致发光和电致发光。本发明提供薄膜有机聚合物电子器件，例如有机光伏电池（OPV），有机二极管，有机光电二极管，有机薄膜晶体管（TFT），有机场效应晶体管（OFET），可印刷或柔性电子器件作为射频识别（RFID）标签，电子纸和印刷电路元件，有机发光二极管（OLED），聚合物发光二极管（PLED）和使用π-共轭有机硼聚合物的储能装置。在OLED和PLED应用中，这些材料用作电子传输层（ETL）以提高器件效率。显示光致发光和电致发光的聚合物也可用作PLED中的发光材料。

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