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    • 1. 发明授权
    • Multilayer film containing a biaxially oriented polypropylene film
    • 含有双轴取向聚丙烯薄膜的多层薄膜
    • US4883698A
    • 1989-11-28
    • US141728
    • 1988-01-11
    • Lothar BotheGuenther CrassSiegfried JanochaGunter Schloegl
    • Lothar BotheGuenther CrassSiegfried JanochaGunter Schloegl
    • B32B15/08C08F2/08G03G9/087
    • B32B15/08C08F2/08G03G9/08702Y10S428/91Y10T428/1359Y10T428/24975Y10T428/2826Y10T428/31663Y10T428/31667Y10T428/31913
    • For packaging purposes, metallized multilayer films containing a biaxially oriented polypropylene film as a base layer should have high scratch resistance, good heat-sealing properties, such as low heat-sealing temperature, attractive visual properties, such as high metallic luster, excellent metallizability of the base layer or of a covering layer, and also good processing properties during metallization, printing, slitting, and during processing on fast-running packaging machines. This requirement profile is fulfilled by a multilayer film of asymmetric structure containing a biaxially oriented base layer 4 composed of polypropylene, a heat-sealing layer 3 which contains an additive combination composed of pigment in platelet form and siloxane and which is optionally modified by an addition of polypropylene and a hydrocarbon resin, and of a corona-treated polypropylene covering layer 2 which is not capable of being heat-sealed. A corona-treated, heat-sealable copolymer may also be used as the covering layer 2, instead of a covering layer 2 composed of non-heat-sealable polypropylene. The covering layer 2 can also be omitted; in that case the surface of the base layer 4 is metallized. Tubular bags, jackets, containers of various shape for packaging foodstuffs, including the vacuum packaging of foodstuffs, are manufactured from this multilayer film.
    • 为了包装目的,含有作为基层的双轴取向聚丙烯薄膜的金属化多层膜应具有高的耐擦伤性,良好的热封性能,例如低的热封温度,有吸引力的视觉特性,例如高的金属光泽,优异的金属化性 基层或覆盖层,以及在快速运行的包装机器的金属化,印刷,切割和加工过程中也具有良好的加工性能。 该需求曲线通过包含由聚丙烯构成的双轴取向基底层4的不对称结构的多层膜来实现,该热封层3含有由片状的颜料和硅氧烷组成的添加剂组合,并且其任选地通过加成 的聚丙烯和烃树脂,以及不能被热密封的经电晕处理的聚丙烯覆盖层2。 也可以使用电晕处理的可热封的共聚物作为覆盖层2,而不是由不可热封的聚丙烯构成的覆盖层2。 覆盖层2也可以省略; 在这种情况下,基底层4的表面被金属化。 用这种多层膜制造包装食品的各种形状的管状袋,夹克,容器,包括食品的真空包装。
    • 6. 发明授权
    • Coextruded, biaxially oriented multilayer film
    • 共挤出双轴取向多层膜
    • US4975329A
    • 1990-12-04
    • US274334
    • 1988-11-21
    • Lothar BotheGuenther CrassGunter SchloeglThomas Wilheim
    • Lothar BotheGuenther CrassGunter SchloeglThomas Wilheim
    • B29C55/12B29K23/00B29K105/34B29L9/00B32B27/32C08L23/12H01B17/60H01G4/18
    • H01G4/18B32B27/32C08L23/12C08L23/06C08L23/0815C08L23/10C08L23/20C08L53/00Y10S428/91Y10T428/31692Y10T428/31913
    • A coextruded, biaxailly oriented multilayer film comprises a base layer comprising an extremely pure raw material and outer layer. It is suitable for use as an electrically insulating film, as a dielectric in an electrical capacitor, and has improved dielectrical properties for this purpose. The base layer and the outer layer or layers contain propylene polymer on one or both sides and stabilizers for propylene polymers. The raw material for the base layer has an idealized thermal oxidation temperature in the range of 260.degree. to 300.degree. C., preferably in the range 260.degree. to 280.degree. C., and the raw material for the outer layer or layers has an idealized thermal oxidation temperature in the region of 240.degree. to 300.degree. C., preferably in the range 240.degree. to 270.degree. C. The multilayer film as a whole has an idealized thermal oxidation temperature in the range 250.degree. to 290.degree. C., in paticular in the range 250.degree. to 275.degree. C. The content of organic neutralizing agents, in particular calcium stearate, in the raw materials is less than or equal to 100 ppm.
    • 共挤出的双轴取向多层膜包括包含极纯原料和外层的基层。 它适合用作电绝缘膜,作为电容器中的电介质,并且为此目的具有改进的介电特性。 基层和外层或层在一侧或两侧含有丙烯聚合物和用于丙烯聚合物的稳定剂。 用于基层的原料具有理想的热氧化温度在260℃至300℃的范围内,优选在260℃至280℃的范围内,而外层的原料具有理想的 热氧化温度在240℃至300℃的范围内,优选在240℃至270℃的范围内。多层膜整体具有理想的热氧化温度在250°至290℃的范围内, 在250〜275℃的范围内,原料中的有机中和剂,特别是硬脂酸钙的含量小于或等于100ppm。
    • 9. 发明授权
    • Biaxially oriented opaque polyolefin multi-layer film
    • 双轴取向不透明聚烯烃多层膜
    • US4983447A
    • 1991-01-08
    • US95448
    • 1987-09-11
    • Guenther CrassSiegfried JanochaLothar Bothe
    • Guenther CrassSiegfried JanochaLothar Bothe
    • B29C55/12B29K23/00B29L9/00B32B27/18B32B27/32B65D65/40
    • B32B27/18B32B27/32Y10S428/906Y10T428/24975Y10T428/258Y10T428/259Y10T428/2826Y10T428/31663Y10T428/31913
    • An opaque polyolefin film having a base layer composed essentially of propylene polymers and having sealing layers present on both sides, composed essentially of sealable olefin polymers, is disclosed. From about 0.2% to 1.5% by weight, relative to the layer of polydialkylsiloxane is incorporated in one of the two sealing layers, and this layer has not been subjected to corona treatment. The other sealing layer has been subjected to corona treatment and has polydialkylsiloxane, not incorporated, but present on the outer surface of this layer, the polydialkylsiloxane having been transferred to this layer by contact between the sealing layer in which polydialkylsiloxane is incorporated. The relative polydialkylsiloxane occupancy of this layer, which is determined by means of ESCA spectroscopy, is not more than 15. The three-layer opaque polyolefin film is prepared by the coextrusion process. It is particularly suitable for use as a packaging film on high-speed packaging machines.
    • 公开了一种不透明聚烯烃膜,其具有基本上由丙烯聚合物组成并具有基本上由可密封的烯烃聚合物组成的两侧上的密封层的基层。 相对于聚二烷基硅氧烷层,约0.2重量%至1.5重量%掺入两个密封层之一中,该层未进行电晕处理。 另一个密封层已进行电晕处理,并且具有未加入的聚二烷基硅氧烷,但存在于该层的外表面上,聚二烷基硅氧烷通过其中掺入聚二烷基硅氧烷的密封层之间的接触转移到该层。 通过ESCA光谱法测定的该层的相对聚二烷基硅氧烷占有率不超过15.三层不透明聚烯烃膜通过共挤出法制备。 特别适用于高速包装机上的包装薄膜。