会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 4. 发明授权
    • Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same
    • 钌复分解催化剂及使用其的复分解反应产生烯烃反应产物的方法
    • US06313365B1
    • 2001-11-06
    • US09666049
    • 2000-09-20
    • Yoji HoriYukiharu IwayaTsutomu HashimotoToshimitsu Hagiwara
    • Yoji HoriYukiharu IwayaTsutomu HashimotoToshimitsu Hagiwara
    • C07C604
    • C07C6/04B01J31/0231B01J31/2286B01J31/2295B01J31/24B01J31/2404B01J31/30B01J2231/14B01J2231/543B01J2531/821C07C2531/24
    • The invention has an object of safely and simply preparing a large amount of a ruthenium metathesis catalyst, which is used as a catalyst for a carbon-carbon bond formation using, particularly, a metathesis reaction. The metathesis catalyst has the following complex composition (A) or (B). The composition (A) includes RuX12(arene)(PR1R2R3) and R4CHX22, R5C ≡CH or R4CHX2 and a reducing agent, wherein X1 and X2 respectively are a halogen atom; arene is a hydrocarbon having a benzene ring; R1, R2 and R3, which may be the same or different, respectively are an alkyl group having 1-8 carbon atoms, a cycloalkyl group having 3-8 carbon atoms or an optionally substituted aryl group, wherein the substituent group is an alkyl group having 1-8 carbon atoms, an alkoxy group having 1-8 carbon atoms, an alkylamino group having 1-8 carbon atoms or a halogen atom; R4 is an alkyl group which has 1-8 carbon atoms and may have an ether bond or an ester bond, an optionally subsituted aryl group, wherein the substituent group is a halogen atom or a hydroxyl group; or cycloalkyl group having 3-8 carbon atoms; and R5 is an optionally substituted alkyl group which has 1-8 carbon atoms and may have an ether bond or an ester bond, wherein the substituent group is a halogen atom or a hydroxyl group, an aryl group or a cycloalkyl group having 3-8 carbon atoms. The composition B includes [RuX12(arene)]2, PR1R2R3, R5C≡CH or R4CHX2 and a reducing agent, wherein X1, arene, R1, R2, R3, R4 and R5 are the same as defined above.
    • 本发明的目的是安全简单地制备大量的钌复分解催化剂,其用作碳 - 碳键形成催化剂,特别是用于复分解反应。 复分解催化剂具有以下复合组成(A)或(B)。 组合物(A)包括RuX12(芳烃)(PR1R2R3)和R4CHX22,R5C = CH或R4CHX2和还原剂,其中X1和X2分别是卤素原子; 芳烃是具有苯环的烃; R 1,R 2和R 3可以相同或不同,分别为具有1-8个碳原子的烷基,具有3-8个碳原子的环烷基或任选取代的芳基,其中取代基是烷基 具有1-8个碳原子,具有1-8个碳原子的烷氧基,具有1-8个碳原子的烷基氨基或卤素原子; R4是具有1-8个碳原子并且可以具有醚键或酯键的烷基,任选取代的芳基,其中取代基是卤素原子或羟基; 或具有3-8个碳原子的环烷基; R5是具有1-8个碳原子并且可以具有醚键或酯键的任意取代的烷基,其中取代基是卤素原子或羟基,芳基或具有3-8个碳原子的环烷基 碳原子。 组合物B包括[RuX 12(芳烃)] 2,PR 1 R 2 R 3,R 5 C = CH或R 4 CHX 2和还原剂,其中X 1,R 6,R 1,R 2,R 3,R 4和R 5与上述定义相同。
    • 5. 发明授权
    • Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same
    • 钌复分解催化剂及使用其的复分解反应产生烯烃反应产物的方法
    • US06175047B1
    • 2001-01-16
    • US09219351
    • 1998-12-23
    • Yoji HoriYukiharu IwayaTsutomu HashimotoToshimitsu Hagiwara
    • Yoji HoriYukiharu IwayaTsutomu HashimotoToshimitsu Hagiwara
    • C07C604
    • C07C6/04B01J31/0231B01J31/2286B01J31/2295B01J31/24B01J31/2404B01J31/30B01J2231/14B01J2231/543B01J2531/821C07C2531/24
    • The invention has an object of safely and simply preparing a large amount of a ruthenium metathesis catalyst, which is used as a catalyst for a carbon-carbon bond formation using, particularly, a metathesis reaction. The metathesis catalyst has the following complex composition (A) or (B). The composition (A) includes RuX12(arene)(PR1R2R3) and R4CHX22, R5C≡CH or R4CHX2 and a reducing agent, wherein X1 and X2 respectively are a halogen atom; arene is a hydrocarbon having a benzene ring; R1, R2 and R3, which may be the same or different, respectively are an alkyl group having 1-8 carbon atoms, a cycloalkyl group having 3-8 carbon atoms or an optionally substituted aryl group, wherein the substituent group is an alkyl group having 1-8 carbon atoms, an alkoxy group having 1-8 carbon atoms, an alkylamino group having 1-8 carbon atoms or a halogen atom; R4 is an alkyl group which has 1-8 carbon atoms and may have an ether bond or an ester bond, an optionally subsituted aryl group, wherein the substituent group is a halogen atom or a hydroxyl group; or cycloalkyl group having 3-8 carbon atoms; and R5 is an optionally substituted alkyl group which has 1-8 carbon atoms and may have an ether bond or an ester bond, wherein the substituent group is a halogen atom or a hydroxyl group, an aryl group or a cycloalkyl group having 3-8 carbon atoms. The composition B includes [RuX12(arene)]2, PR1R2R3, R5C≡CH or R4CHX2 and a reducing agent, wherein X1, arene, R1, R2, R3, R4 and R5 are the same as defined above.
    • 本发明的目的是安全简单地制备大量的钌复分解催化剂,其用作碳 - 碳键形成催化剂,特别是用于复分解反应。 复分解催化剂具有以下复合组成(A)或(B)。 组合物(A)包括RuX12(芳烃)(PR1R2R3)和R4CHX22,R5C = CH或R4CHX2和还原剂,其中X1和X2分别是卤素原子; 芳烃是具有苯环的烃; R 1,R 2和R 3可以相同或不同,分别为具有1-8个碳原子的烷基,具有3-8个碳原子的环烷基或任选取代的芳基,其中取代基是烷基 具有1-8个碳原子,具有1-8个碳原子的烷氧基,具有1-8个碳原子的烷基氨基或卤素原子; R4是具有1-8个碳原子并且可以具有醚键或酯键的烷基,任选取代的芳基,其中取代基是卤素原子或羟基; 或具有3-8个碳原子的环烷基; R5是具有1-8个碳原子并且可以具有醚键或酯键的任意取代的烷基,其中取代基是卤素原子或羟基,芳基或具有3-8个碳原子的环烷基 碳原子。 组合物B包括[RuX 12(芳烃)] 2,PR 1 R 2 R 3,R 5 C = CH或R 4 CHX 2和还原剂,其中X 1,R 6,R 1,R 2,R 3,R 4和R 5与上述定义相同。