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1. 发明申请

US20100275509A1 METHOD FOR PRODUCING COMPOSITION USING ALCOHOL AS STARTING MATERIAL 有权
标题翻译：使用醇作为起始材料生产组合物的方法
公开(公告)号：US20100275509A1
公开(公告)日：2010-11-04
申请号：US12246386
申请日：2008-10-06
申请人： Shuji Sakuma , Takashi Tsuchida , Tetsuya Yoshioka
发明人： Shuji Sakuma , Takashi Tsuchida , Tetsuya Yoshioka
IPC分类号： C10L1/182
CPC分类号： C10G3/45 , B01J25/02 , B01J27/14 , B01J35/0006 , B01J35/1014 , C10G3/47 , C10G3/52 , C10G45/00 , C10G45/32 , C10G45/44 , C10G2400/02 , C10L1/02 , Y02P30/20
摘要： The present invention is to provide compositions comprising organic compounds useful as a chemical industrial material or a fuel composition with the use of an alcohol such as ethanol as a material. It is a method for producing compositions using alcohol as a starting material and comprising: allowing alcohol to contact with an alcohol conversion catalyst such as hydroxyapatite (first step) and conducting a hydrogenation reaction respectively for all reaction products consisting of a liquid phase including alcohols, water and hydrocarbons of 4-12 carbons and a gas phase which is light gas containing paraffins, alcohols and olefins; all liquid phase reaction products consisting of all reaction products from which light gas has been removed; a liquid phase dehydration reaction products consisting of all reaction products from which light gas, unreacted alcohol and product water have been removed; and light gas (second step).
摘要翻译：本发明提供包含可用作化学工业材料的有机化合物或使用醇如乙醇作为材料的燃料组合物的组合物。它是以醇为原料制备组合物的方法，其包括：使醇与醇转化催化剂如羟基磷灰石接触（第一步），并分别对由包括醇的液相组成的所有反应产物进行氢化反应， 4-12个碳原子的水和碳氢化合物，以及含有链烷烃，醇和烯烃的轻质气体的气相; 由所有反应产物组成的所有液相反应产物都被除去; 由除去轻质气体，未反应的醇和产物水的所有反应产物组成的液相脱水反应产物; 和轻气（第二步）。

2. 发明申请

US20090056204A1 METHOD OF SYNTHESIZING CHEMICAL INDUSTRY RAW MATERIALS AND FUEL COMPOSITIONS 审中-公开
标题翻译：合成化学工业原料和燃料组合物的方法
公开(公告)号：US20090056204A1
公开(公告)日：2009-03-05
申请号：US12198059
申请日：2008-08-25
申请人： Takashi Tsuchida , Shuji Sakuma , Tetsuya Yoshioka , Jun Kubo
发明人： Takashi Tsuchida , Shuji Sakuma , Tetsuya Yoshioka , Jun Kubo
IPC分类号： C10L1/18
CPC分类号： C07C29/34 , C07C31/12 , C07C31/10 , C07C31/125
摘要： The present invention is to provide a novel method for manufacturing various organic compounds from 2 or more kinds of alcohol, or 1 kind of alcohol having 3 or more carbon atoms. It is a method for synthesizing 1 kind of, or 2 or more kinds of organic compounds comprising allowing 2 or more kinds of alcohol or 1 kind of alcohol having 3 or more carbon atoms to contact hydroxyapatite (except those supporting metal catalysts or metal ion catalysts acting on alcohol).
摘要翻译：本发明提供一种由2种以上的醇或1种具有3个以上碳原子的醇制造各种有机化合物的新方法。合成1种或2种以上有机化合物的方法，包括使2种以上的醇或1种具有3个以上碳原子的醇与羟基磷灰石接触（除载体金属催化剂或金属离子催化剂作用于酒精）。

3. 发明授权

US08603201B2 Method of synthesizing chemical industry raw materials and fuel compositions 有权
标题翻译：化学工业原料与燃料成分合成方法
公开(公告)号：US08603201B2
公开(公告)日：2013-12-10
申请号：US12391254
申请日：2009-02-23
申请人： Takashi Tsuchida , Shuji Sakuma , Tetsuya Yoshioka , Jun Kubo
发明人： Takashi Tsuchida , Shuji Sakuma , Tetsuya Yoshioka , Jun Kubo
IPC分类号： C07C29/34 , C10L1/18
CPC分类号： C07B61/00 , C07C29/34 , C07C31/10 , C07C31/12 , C07C31/125
摘要： The present invention is to provide a novel method for manufacturing various organic compounds from two or more kinds of alcohol, or one kind of alcohol having three or more carbon atoms. It is a method for synthesizing one kind of, or two or more kinds of organic compounds comprising allowing two or more kinds of alcohol or one kind of alcohol having three or more carbon atoms to contact a calcium phosphate catalyst such as hydroxyapatite, or hydrotalcite.
摘要翻译：本发明提供一种由两种或更多种醇或一种具有三个或更多个碳原子的醇制备各种有机化合物的新方法。它是合成一种或两种或更多种有机化合物的方法，包括使两种或更多种醇或一种具有三个或更多个碳原子的醇接触磷酸钙催化剂如羟基磷灰石或水滑石。

4. 发明授权

US08187347B2 Method for producing composition using alcohol as starting material 有权
标题翻译：使用醇作为起始原料生产组合物的方法
公开(公告)号：US08187347B2
公开(公告)日：2012-05-29
申请号：US12246386
申请日：2008-10-06
申请人： Shuji Sakuma , Takashi Tsuchida , Tetsuya Yoshioka
发明人： Shuji Sakuma , Takashi Tsuchida , Tetsuya Yoshioka
IPC分类号： C10L1/18
CPC分类号： C10G3/45 , B01J25/02 , B01J27/14 , B01J35/0006 , B01J35/1014 , C10G3/47 , C10G3/52 , C10G45/00 , C10G45/32 , C10G45/44 , C10G2400/02 , C10L1/02 , Y02P30/20
摘要： The present invention is to provide compositions comprising organic compounds useful as a chemical industrial material or a fuel composition with the use of an alcohol such as ethanol as a material. It is a method for producing compositions using alcohol as a starting material and comprising: allowing alcohol to contact with an alcohol conversion catalyst such as hydroxyapatite (first step) and conducting a hydrogenation reaction respectively for all reaction products consisting of a liquid phase including alcohols, water and hydrocarbons of 4-12 carbons and a gas phase which is light gas containing paraffins, alcohols and olefins; all liquid phase reaction products consisting of all reaction products from which light gas has been removed; a liquid phase dehydration reaction products consisting of all reaction products from which light gas, unreacted alcohol and product water have been removed; and light gas (second step).
摘要翻译：本发明提供包含可用作化学工业材料的有机化合物或使用醇如乙醇作为材料的燃料组合物的组合物。它是以醇为原料制备组合物的方法，其包括：使醇与醇转化催化剂如羟基磷灰石接触（第一步），并分别对由包括醇的液相组成的所有反应产物进行氢化反应， 4-12个碳原子的水和碳氢化合物，以及含有链烷烃，醇和烯烃的轻质气体的气相; 由所有反应产物组成的所有液相反应产物都被除去; 由除去轻质气体，未反应的醇和产物水的所有反应产物组成的液相脱水反应产物; 和轻气（第二步）。

5. 发明授权

US09056811B2 Method for producing alcohol by guerbet reaction 有权
标题翻译：通过吉尔贝特反应生产醇的方法
公开(公告)号：US09056811B2
公开(公告)日：2015-06-16
申请号：US13822047
申请日：2011-09-14
申请人： Tetsuya Yoshioka , Takashi Tsuchida , Jun Kubo , Shuji Sakuma
发明人： Tetsuya Yoshioka , Takashi Tsuchida , Jun Kubo , Shuji Sakuma
IPC分类号： C07C29/34 , C07C31/10 , C07C31/12 , C07C31/125 , B01J21/10 , B01J23/00 , B01J27/18 , B01J29/08 , B01J37/03
CPC分类号： C07C29/34 , B01J21/10 , B01J23/007 , B01J27/18 , B01J29/082 , B01J37/03 , C07C31/12 , C07C31/10 , C07C31/125
摘要： A method for increasing the yield of alcohols by a Guerbet reaction in a gas phase and reducing production cost is provided. A method for producing alcohols by a Guerbet reaction, wherein the reaction is performed in a gas phase and at a total pressure of less than 1 atm and preferably from 0.01 to 0.5 atm, using one or more raw material alcohols.
摘要翻译：提供了一种通过Guerbet反应在气相中提高醇的产率并降低生产成本的方法。通过Guerbet反应制备醇的方法，其中使用一种或多种原料醇在气相和小于1atm，优选0.01至0.5atm的总压下进行反应。

6. 发明申请

US20130172634A1 METHOD FOR PRODUCING ALCOHOL BY GUERBET REACTION 有权
标题翻译：通过反应生产醇的方法
公开(公告)号：US20130172634A1
公开(公告)日：2013-07-04
申请号：US13822047
申请日：2011-09-14
申请人： Tetsuya Yoshioka , Takashi Tsuchida , Jun Kubo , Shuji Sakuma
发明人： Tetsuya Yoshioka , Takashi Tsuchida , Jun Kubo , Shuji Sakuma
IPC分类号： C07C29/34
CPC分类号： C07C29/34 , B01J21/10 , B01J23/007 , B01J27/18 , B01J29/082 , B01J37/03 , C07C31/12 , C07C31/10 , C07C31/125
摘要： A method for increasing the yield of alcohols by a Guerbet reaction in a gas phase and reducing production cost is provided. A method for producing alcohols by a Guerbet reaction, wherein the reaction is performed in a gas phase and at a total pressure of less than 1 atm and preferably from 0.01 to 0.5 atm, using one or more raw material alcohols.
摘要翻译：提供了一种通过Guerbet反应在气相中提高醇的产率并降低生产成本的方法。通过Guerbet反应制备醇的方法，其中使用一种或多种原料醇在气相和小于1atm，优选0.01至0.5atm的总压下进行反应。

7. 发明授权

US08080695B2 Method of synthesizing higher-molecular alcohol 有权
标题翻译：合成高分子醇的方法
公开(公告)号：US08080695B2
公开(公告)日：2011-12-20
申请号：US11757588
申请日：2007-06-04
申请人： Takashi Tsuchida , Shuji Sakuma
发明人： Takashi Tsuchida , Shuji Sakuma
IPC分类号： C07C31/02
CPC分类号： C07C29/34 , C07C31/12
摘要： The present invention provides a production method with which high molecular alcohols having an even number of carbon atoms such as 1-butanol, hexanol, octanol and decanol, and a mixture of these are efficiently collected through clean processes with the use of ethanol as a raw material. High molecular alcohols are produced from ethanol by using calcium phosphate-based compounds such as hydroxyapatite Ca10(PO4)6(OH)2, tricalcium phosphate Ca3(PO4)2, calcium monohydrogen phosphate CaHPO4.(0˜2)H2O, calcium diphosphate Ca2P2O7, octacalcium phosphate Ca8H2(PO4)6.5H2O, tetracalcium phosphate Ca4(PO4)2O or amorphous calcium phosphate Ca3(PO4)2. nH2O as a catalyst, using ethanol as a starting material, and setting a contact time at 0.4 second or longer.
摘要翻译：本发明提供一种制备方法，通过使用乙醇作为原料，通过清洁方法有效地收集具有偶数个碳原子的高分子醇如1-丁醇，己醇，辛醇和癸醇，以及它们的混合物材料。高分子醇通过使用磷酸钙基化合物如羟基磷灰石Ca10（PO4）6（OH）2，磷酸三钙Ca3（PO4）2，磷酸一氢钙CaHPO 4（0-2）H 2 O，二磷酸钙Ca 2 P 2 O 7 ，磷酸三钙Ca8H2（PO4）6.5H2O，磷酸四钙Ca4（PO4）2O或无定形磷酸钙Ca3（PO4）2。 nH 2 O作为催化剂，使用乙醇作为原料，并将接触时间设定为0.4秒以上。

8. 发明申请

US20070255079A1 Method of Synthesizing Higher-Molecular Alcohol 有权
标题翻译：合成高分子醇的方法
公开(公告)号：US20070255079A1
公开(公告)日：2007-11-01
申请号：US11757588
申请日：2007-06-04
申请人： Takashi Tsuchida , Shuji Sakuma
发明人： Takashi Tsuchida , Shuji Sakuma
IPC分类号： C07C31/02
CPC分类号： C07C29/34 , C07C31/12
摘要： The present invention provides a production method with which high molecular alcohols having an even number of carbon atoms such as 1-butanol, hexanol, octanol and decanol, and a mixture of these are efficiently collected through clean processes with the use of ethanol as a raw material. High molecular alcohols are produced from ethanol by using calcium phosphate-based compounds such as hydroxyapatite Ca10(PO4)6(OH)2, tricalcium phosphate Ca3(PO4)2, calcium monohydrogen phosphate CaHPO4.(0˜2)H2O, calcium diphosphate Ca2P2O7, octacalcium phosphate Ca8H2(PO4)6.5H2O, tetracalcium phosphate Ca4(PO4)2O or amorphous calcium phosphate Ca3(PO4)2.nH2O as a catalyst, using ethanol as a starting material, and setting a contact time at 0.4 second or longer.
摘要翻译：本发明提供一种制备方法，通过使用乙醇作为原料，通过清洁方法有效地收集具有偶数个碳原子的高分子醇如1-丁醇，己醇，辛醇和癸醇，以及它们的混合物材料。高分子醇通过使用磷酸钙基化合物如羟基磷灰石Ca（PO 4）6（OH）N（OH））由乙醇制备磷酸三钙Ca 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 （0〜2）H 2 O 2，二磷酸钙Ca 2 P 2 O 7，磷酸三钙Ca 8 H 2（PO 4）6 5 H 2 O，四氢化锇磷酸盐Ca 3（PO 4）2 O 2或无定形磷酸钙Ca 3（PO 4）作为催化剂，使用乙醇作为起始原料，并将接触时间设定为0.4秒以上，作为催化剂。

9. 发明授权

US06323383B1 Synthesis method of chemical industrial raw material and high-octane fuel, and high-octane fuel composition 有权
标题翻译：化学工业原料和高辛烷值燃料的合成方法，高辛烷值燃料组成
公开(公告)号：US06323383B1
公开(公告)日：2001-11-27
申请号：US09601139
申请日：2000-09-27
申请人： Takashi Tsuchida , Kiminori Atsumi , Shuji Sakuma , Tomoyuki Inui
发明人： Takashi Tsuchida , Kiminori Atsumi , Shuji Sakuma , Tomoyuki Inui
IPC分类号： C01L118
CPC分类号： C10L1/023 , B01J27/1806 , C07C1/20 , C07C1/24 , C07C41/09 , C07C45/002 , C07C2527/167 , C10G3/45 , C10G3/49 , C10G2300/301 , C10G2400/02 , C10G2400/20 , Y02P20/52 , Y02P30/42 , C07C11/167 , C07C11/04 , C07C47/06 , C07C43/06
摘要： A process for the synthesis of chemical industrial feedstock and high-octane fuel, wherein calcium phosphate which is controlled in the molar Ca/P ratio and/or one which contains an activating metal (M) at a molar (Ca+M)/P ratio of 1 to 2 is used as the catalyst and ethanol is used as the feedstock.
摘要翻译：一种用于合成化学工业原料和高辛烷值燃料的方法，其中以摩尔Ca / P比控制磷酸钙和/或以摩尔浓度（Ca + M）/ P 使用1〜2的比例作为催化剂，使用乙醇作为原料。

10. 发明授权

US07088304B2 Antenna coil, and RFID-use tag using it, transponder-use antenna 失效
标题翻译：天线线圈和使用它的RFID使用标签，应答器使用天线
公开(公告)号：US07088304B2
公开(公告)日：2006-08-08
申请号：US10490704
申请日：2002-09-26
申请人： Takanori Endo , Seirou Yahata , Takashi Tsuchida , Tadashi Yonezawa
发明人： Takanori Endo , Seirou Yahata , Takashi Tsuchida , Tadashi Yonezawa
IPC分类号： H01Q7/08
CPC分类号： H01Q1/2225 , G06K19/0726 , G06K19/07749 , G06K19/07771 , G06K19/07779 , G06K19/07783 , H01Q1/22 , H01Q1/38 , H01Q7/00 , H01Q7/06 , H01Q9/27
摘要： An antenna coil includes an air-core coil wound helically in a plane and a plate magnetic core member inserted in the air-core coil to be approximately parallel with a plane of the air-core coil. The magnetic core member is formed by a soft magnetic metal, an amorphous or ferrite, or a composite member of a powder, flake and plastic, or rubber. The magnetic core member is formed by performing an injection molding operation or a compressing molding operation of the composite member. Alternatively, the magnetic core member is a magnetic coating formed by applying and drying the composite member. A non-magnetic conductive plate that has a conductivity is layered on a surface of the air-core coil through which the magnetic core member is inserted. The conductive plate is made of a copper, a copper alloy, an aluminum or an aluminum alloy having 0.01 to 2 mm thickness. The antenna coil is operated by relatively high frequency while it is rigid relatively.
摘要翻译：天线线圈包括在平面中螺旋地卷绕的空芯线圈和插入空心线圈中的板状磁芯构件，以与空心线圈的平面大致平行。磁芯构件由软磁金属，非晶体或铁氧体，或粉末，薄片和塑料或橡胶的复合构件形成。通过进行复合构件的注射成型操作或压缩成型操作来形成磁芯构件。或者，磁芯构件是通过施加和干燥复合构件而形成的磁性涂层。具有导电性的非磁性导电板层叠在空芯线圈的插入磁芯部件的表面上。导电板由厚度为0.01〜2mm的铜，铜合金，铝或铝合金制成。天线线圈相对较硬时，频率相对较高。

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