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    • 1. 发明授权
    • Process for producing a polymer
    • 聚合物的制造方法
    • US07951887B2
    • 2011-05-31
    • US10558814
    • 2004-05-26
    • Shoji YamaguchiHideo Kubo
    • Shoji YamaguchiHideo Kubo
    • C08F112/04
    • C08F297/02
    • The object of the present invention is to provide a process for industrially advantageously producing a polymer having a high molecular weight and a narrow, monodispersed molecular weight distribution, and more particularly, a block copolymer of an anionic polymerizable monomer and an acrylic monomer. The object of the present invention was able to be achieved by reacting an acrylic monomer with a polymer anion, the terminal of which has been modified by a compound that forms a living carbanion capable of polymerizing an anionic polymerizable monomer by reacting with an anion, but which itself does not polymerize, in the presence of a compound represented by formula (1): (R1)nM (wherein, R1 represents a C1-C20 alkyl group or a C6-C20 aryl group, R1 may be the same or different in the case n is 2 or more, M represents an atom belonging to Group 2, 12 or 13 of the long form of the periodic table, and n represents the valency of M).
    • 本发明的目的是提供一种工业上有利地制备具有高分子量和窄的单分散分子量分布的聚合物的方法,更具体地说,是阴离子可聚合单体和丙烯酸单体的嵌段共聚物。 本发明的目的是通过使丙烯酸类单体与聚合物阴离子反应来实现,该阴离子的末端已经被能够通过与阴离子反应而形成可阴离子聚合的单体聚合的活性碳负离子的化合物改性,但是 (R1)nM(其中R1表示C1-C20烷基或C6-C20芳基)表示的化合物,其自身不聚合,R1可以相同或不同, 情况n为2以上,M表示属于长周期表的第2,12或13族的原子,n表示M的化合价。
    • 2. 发明申请
    • Process for producing polymer
    • 生产聚合物的方法
    • US20070015890A1
    • 2007-01-18
    • US10558814
    • 2004-05-26
    • Shoji YamaguchiHideo Kubo
    • Shoji YamaguchiHideo Kubo
    • C08F118/02
    • C08F297/02
    • The object of the present invention is to provide a process for industrially advantageously producing a polymer having a high molecular weight and a narrow, monodispersed molecular weight distribution, and more particularly, a block copolymer of an anionic polymerizeable monomer and an acrylic monomer. The object of the present invention was able to be achieved by reacting an acrylic monomer with a polymer anion, the terminal of which has been modified by a compound that forms a living carbanion capable of polymerizing an anionic polymerizeable monomer by reacting with an anion, but which itself does not polymerize, in the presence of a compound represented by formula (1): (R1)nM (wherein, R1 represents a C1-C20 alkyl group or a C6-C20 aryl group, R1 may be the same or different in the case n is 2 or more, M represents an atom belonging to Group 2, 12 or 13 of the long form of the periodic table, and n represents the valency of M).
    • 本发明的目的是提供一种工业上有利地制备具有高分子量和窄的单分散分子量分布的聚合物的方法,更具体地说,是阴离子聚合单体和丙烯酸类单体的嵌段共聚物。 本发明的目的是通过使丙烯酸类单体与聚合物阴离子反应来实现,该阴离子的末端已经被能够通过与阴离子反应而形成能够使阴离子聚合性单体聚合的活性碳负离子的化合物改性,但是 (R1)nM(其中R1表示C1-C20烷基或C6-C20芳基)表示的化合物,其自身不聚合,R1可以相同或不同, 情况n为2以上,M表示属于长周期表的第2,12或13族的原子,n表示M的化合价。
    • 4. 发明授权
    • Block copolymers
    • 嵌段共聚物
    • US08193285B2
    • 2012-06-05
    • US12300512
    • 2007-05-16
    • Eiji TakahashiShoji Yamaguchi
    • Eiji TakahashiShoji Yamaguchi
    • C08F293/00C08F291/06C08L53/00
    • C08F297/026C08F293/005C08F297/02C08L53/00C08L2666/02
    • It is to provide a block copolymer that can form a microphase separation structure even with a small molecular size, and that can form a microphase separation structure with a small domain size.It is a block copolymer represented by the formula A-C-B (wherein A represents a segment which is a homopolymer or random or block copolymer consisting of at least 1 kind or repeat units represented by formula (II); B represents a segment which is a homopolymer, or random or block copolymer consisting of at least 1 kind of repeat units represented by formula (III); C represents A, B or A-B; however, at least 1 segment of each A has a water-repellent group, or at least 1 segment of each B has a polar group); which block copolymer has a mass average molecular weight of 50,000 or less, and that can form a microphase separation structure.
    • 提供即使具有小分子尺寸也可以形成微相分离结构的嵌段共聚物,并且可以形成具有小畴尺寸的微相分离结构。 它是由式ACB表示的嵌段共聚物(其中A表示由至少1种或由式(II)表示的重复单元组成的均聚物或无规或嵌段共聚物的链段; B表示均聚物的链段, 或由式(III)表示的至少1种重复单元组成的无规或嵌段共聚物; C表示A,B或AB;但是,每个A的至少1个链段具有拒水性基团或至少1个片段 每个B具有极性基团); 该嵌段共聚物的质均分子量为50,000以下,可以形成微相分离结构。
    • 5. 发明授权
    • Flat detector and medium detector
    • 平板检测器和介质检测器
    • US07888615B2
    • 2011-02-15
    • US12434163
    • 2009-05-01
    • Eizo KuriharaTsukasa MatsudaKunihiro TakahashiHiroyoshi InoueMario FuseShoji Yamaguchi
    • Eizo KuriharaTsukasa MatsudaKunihiro TakahashiHiroyoshi InoueMario FuseShoji Yamaguchi
    • B07C5/344
    • G01N27/725
    • A flat detector includes a first flat member and a second flat member both made of a nonmagnetic nonmetal, a first conductive wiring that generates an alternating magnetic field, the first conductive wiring being disposed on a surface of the first flat member facing toward the second flat member, a first layer made of a nonmagnetic metal and disposed at least on a surface of the first flat member, a second conductive wiring that detects a signal generated by magnetization reversal of a magnetic material, the magnetization reversal being caused by the alternating magnetic field generated by the first conductive wiring, the second conductive wiring being disposed on a surface of the second flat member facing toward the first flat member, and a second layer made of a nonmagnetic metal and disposed at least on a surface of the second flat member.
    • 平板检测器包括由非磁性非金属制成的第一平坦构件和第二平坦构件,产生交变磁场的第一导电布线,第一导电布线设置在面向第二平面的第一平坦构件的表面上 构件,由非磁性金属制成的第一层并且至少设置在所述第一平坦构件的表面上;第二导电布线,其检测由磁性材料的磁化反转产生的信号,所述磁化反转是由交变磁场引起的 由所述第一导电布线产生,所述第二导电布线设置在所述第二平坦构件的面向所述第一平坦构件的表面上,所述第二层由非磁性金属制成并且至少设置在所述第二平坦构件的表面上。