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    • 1. 发明授权
    • Method for producing iron carbide
    • 碳化铁生产方法
    • US6004373A
    • 1999-12-21
    • US876232
    • 1997-06-16
    • Shoji HayashiYoshiaki Iguchi
    • Shoji HayashiYoshiaki Iguchi
    • C01B31/30C21B13/00C21B15/00C22B5/06C22B5/12C22B5/14
    • C01B31/30C21B13/0073C22B5/06C22B5/12Y02P10/136
    • A method for producing iron carbide by bringing iron ore into contact with a reducing gas containing hydrogen and a carbon compound at a high reaction temperature and at a reaction pressure of the atmospheric pressure or more to reduce and carburize the iron ore with the participation of a sulfur component, the method includes measuring the reaction temperature, partial pressure P(H.sub.2) of the hydrogen and partial pressure P(H.sub.2 S) of hydrogen sulfide contained in the reducing gas, calculating sulfur activity a.sub.s in the reducing gas from Equation (1) shown below, and adjusting the partial pressure P(H.sub.2 S) of the hydrogen sulfide in the reducing gas to obtain a.sub.s =1.0 to 2.0 at reaction temperatures of 550.degree. C. and above but less than 650.degree. C., a.sub.s =0.7 to 2.0 at 650.degree. C., and a.sub.s =0.05 to 1.0 at over 650.degree. C. and up to 950.degree. C.: (1) a.sub.s =(P(H.sub.2 S)/P(H.sub.2))/(P(H.sub.2 S)/P(H.sub.2)).sub.E where (P(H.sub.2 S)/P(H.sub.2)) represents the ratio between the partial pressures of H.sub.2 S and H.sub.2 in the reducing gas and (P(H.sub.2 S)/P(H.sub.2)).sub.E is the ratio between the partial pressures of H.sub.2 S and H.sub.2 in a condition where the reaction of Equation (2) below is in equilibrium: (2) FeS(s)+H.sub.2 (g)=Fe(s)+H.sub.2 S(g) where (s) and (g) represent solid and gaseous phases, respectively. The method includes controlling the reaction pressure to the atmospheric pressure or more in accordance with the oxidizing gas contained in a reducing gas at a reaction temperature of 650.degree. C. or more.
    • 一种通过在高反应温度和大气压或更大的反应压力下使铁矿石与含有氢和碳化合物的还原气体接触来生产碳化铁的方法,以减少和渗碳铁矿石,参与 硫组分,该方法包括测量氢气中的反应温度,分压P(H2)和还原气体中所含的硫化氢的分压P(H2S),计算如下所示的式(1)的还原气体中的硫活性 并且在550℃以上但小于650℃的反应温度下调节还原气体中的硫化氢的分压P(H 2 S),以获得= 1.0〜2.0,= 0.7〜2.0 650℃,并且在650℃和= 950℃下= 0.05〜1.0(1)as =(P(H2S)/ P(H2))/(P(H2S)/ P H2))E其中(P(H2S)/ P(H2))表示还原气体中的H 2 S和H 2的分压与(P(H 2 S)/ P(H 2) )E是下式(2)的反应处于平衡状态的H2S和H2的分压之间的比例:(2)FeS(s)+ H2(g)= Fe(s)+ H2S )其中(s)和(g)分别表示固相和气相。 该方法包括在650℃以上的反应温度下,根据还原气体中所含的氧化气体,将反应压力控制为大气压以上。
    • 2. 发明授权
    • Method of producing iron carbide
    • 生产碳化三铁的方法
    • US5683489A
    • 1997-11-04
    • US588310
    • 1996-01-18
    • Shoji HayashiYoshiaki IguchiYukihiro HidaSatoshi Sawai
    • Shoji HayashiYoshiaki IguchiYukihiro HidaSatoshi Sawai
    • C01B31/30C21B13/00C21B15/00C22B5/14
    • C01B31/303C21B13/0033C22B5/14C01P2006/80Y02P10/136Y02P10/143
    • A method for producing iron carbide by bringing iron ore into contact with a reducing gas containing hydrogen and a carbon compound at a specified reaction temperature to reduce and carburize the iron ore with the participation of a sulfur component, the method includes measuring the reaction temperature, partial pressure P(H.sub.2) of the hydrogen and partial pressure P(H.sub.2 S) of hydrogen sulfide contained in the reducing gas, calculating sulfur activity as in the reducing gas from equation (1) shown below, and adjusting the partial pressure P(H.sub.2 S) of the hydrogen sulfide in the reducing gas to obtain as=1.0 to 2.0. at reaction temperatures of 550.degree. C. and above but less than 650.degree. C., as=0.7 to 2.0 at 650.degree. C., and as=0.05 to 1.0 at over 650.degree. C. and up to 950.degree. C.: as=(P(H.sub.2 S)/P(H.sub.2))/(P(H.sub.2 S)/P(H.sub.2))E (1) where (P(H.sub.2 S)/P(H.sub.2)) represents the ratio between the partial pressures of H.sub.2 S and H.sub.2 in the reducing gas and (P(H.sub.2 S)/p(H.sub.2))s is the ratio between the partial pressures of H.sub.2 S and H.sub.2 in a condition where the reaction of equation (2) below is in equilibrium: FeS(s)+H.sub.2 (g)=Fe(s)+H.sub.2 S(g) (2) where (s) and (g) represent solid and gaseous phases, respectively.
    • 该方法包括测定反应温度,该方法包括:测定反应温度,测定反应温度,测定反应温度, 包含在还原气体中的氢的分压P(H2)和硫化氢的分压P(H2S),如下所示的式(1)计算硫还原气体中的硫活性,并调节分压P(H2S) 的还原气体中的硫化氢,得到= 1.0〜2.0。 在550℃以上但小于650℃的反应温度下,在650℃下= 0.7〜2.0,在650℃以上为0.05〜1.0,最高为950℃。 =(P(H2S)/ P(H2))/(P(H2S)/ P(H2))E(1)其中(P(H2S)/ P(H2))表示H2S和 还原气体中的H2和(P(H2S)/ p(H2))s是在下式(2)的反应处于平衡状态下的H 2 S和H 2的分压之间的比例:FeS(s)+ H2(g)= Fe(s)+ H2S(g)(2)其中(s)和(g)分别表示固相和气相。