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    • 9. 发明授权
    • Methods of preparing a polymerization catalyst
    • 制备聚合催化剂的方法
    • US08697599B2
    • 2014-04-15
    • US13029309
    • 2011-02-17
    • Elizabeth A. BenhamMax P. McDanielKathy S. CollinsStephen M. Wharry
    • Elizabeth A. BenhamMax P. McDanielKathy S. CollinsStephen M. Wharry
    • B01J21/00B01J23/00C08F110/02C08F4/24
    • C08F10/02C08F110/02C08F4/69C08F4/24C08F2500/10C08F2500/08C08F2500/12
    • A method comprising (a) contacting a support and a chromium-containing compound to form chromium-containing support, (b) heat treating the chromium-containing support in an oxidizing atmosphere to form a treated support, (c) contacting the treated support with carbon monoxide to form a CO-contacted support, and (d) contacting the CO-contacted support with hydrogen to form a catalyst. A method comprising oxidizing a chromium-treated support to form a polymerization catalyst, contacting the polymerization catalyst with carbon monoxide to form a reduced polymerization catalyst, contacting the reduced polymerization catalyst with hydrogen to form an activated polymerization catalyst, and contacting the activated polymerization catalyst with ethylene in a reaction zone under suitable reaction conditions to form a random copolymer. A method comprising reducing a polymerization catalyst comprising Cr(VI) to form a polymerization catalyst comprising Cr(II), and treating the polymerization catalyst comprising Cr(II) with hydrogen.
    • 一种方法,包括(a)使载体和含铬化合物接触以形成含铬载体,(b)在氧化气氛中热处理含铬载体以形成经处理的载体,(c)使经处理的载体与 一氧化碳以形成CO-接触的载体,和(d)使CO-接触的载体与氢接触以形成催化剂。 一种方法,包括氧化铬处理的载体以形成聚合催化剂,使聚合催化剂与一氧化碳接触以形成还原的聚合催化剂,使还原的聚合催化剂与氢接触以形成活化的聚合催化剂,并使活化的聚合催化剂与 乙烯在合适的反应条件下在反应区中形成无规共聚物。 一种包括还原包含Cr(VI)的聚合催化剂以形成包含Cr(II)的聚合催化剂并用氢气处理包含Cr(II)的聚合催化剂的方法。