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    • 1. 发明授权
    • Organopolysiloxane compositions
    • 有机聚硅氧烷组合物
    • US5447987A
    • 1995-09-05
    • US362948
    • 1994-12-23
    • Shinichi SatoTakashi MatsudaKenichi FukudaTomofumi Sutou
    • Shinichi SatoTakashi MatsudaKenichi FukudaTomofumi Sutou
    • C08L83/04C08K5/54
    • C08L83/04C08G77/12C08G77/20C08G77/70
    • Organopolysiloxane compositions of the present invention are the curable compositions of the addition curable type, which comprise (A) an organopolysiloxane having aliphatic unsaturated groups, (B) an organohydrogen polysiloxane having SiH groups, (C) a fluorine containing organopolysiloxane expressed by the following general chemical formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 through R.sup.6, and R.sup.8 are monovalent hydrocarbon groups such as alkyl groups, R.sup.3 and R.sup.7 are bivalent hydrocarbon groups, such as alkylene groups, Rf is either a perfluoroalkyl group or a perfluoroalkyl ether group, subscripts k, p, and m are integers of at least 1, and the subscript n is an integer of at least 0, and (D) a platinum group metallic catalyst. The cured products obtained from the compositions of the present invention exhibit a superior adhesiveness towards substances to be adhered, such as glass, aluminum, iron and epoxy resins.
    • 本发明的有机聚硅氧烷组合物是可加成固化型的可固化组合物,其包含(A)具有脂族不饱和基团的有机聚硅氧烷,(B)具有SiH基团的有机氢聚硅氧烷,(C)由以下通式表示的含氟有机聚硅氧烷 化学式(1):nd R8是一价烃基,例如烷基,R 3和R 7是二价烃基,例如亚烷基,R f是全氟烷基或全氟烷基醚基,下标k,p和m是 整数为1以上,下标n为0以上的整数,(D)铂族金属催化剂。 由本发明组合物获得的固化产物对玻璃,铝,铁和环氧树脂等粘合物质的粘附性显示出优异的表现。
    • 3. 发明申请
    • Primer composition for a fluorinated elastomer or a fluorinated gel
    • 含氟弹性体或氟化凝胶的底漆组合物
    • US20060178459A1
    • 2006-08-10
    • US11177304
    • 2005-07-11
    • Takashi MatsudaYasuhisa OsawaKenichi Fukuda
    • Takashi MatsudaYasuhisa OsawaKenichi Fukuda
    • C08K5/54
    • B05D5/083B05D7/544B05D7/546C08L71/02C09D171/02Y10T428/31663C08L83/00
    • A primer composition for a fluorinated elastomer or a fluorinated gel, said primer composition comprising: 100 parts by weight of (a) a linear perfluoro polyether compound having at least two alkenyl groups per molecule, a perfluoro polyether backbone having repeating units represented by the formula, —CaF2aO—, wherein a is an integer of from 1 to 6, and a weight average molecular weight of from 5,000 to 100,000, (b) an organosiloxane compound having one or more fluorine atom and at least two SiH bonds per molecule, in such an amount that a molar ratio of the SiH bond in the organosiloxane compound to the alkenyl group in Component (a) ranges from 0.8 to 5.0, a catalytic amount of (c) a hydrosilylation catalyst, 5 to 100 parts by weight of (d) an organosiloxane compound having, per molecule, at least one SiH bond and at least one epoxy group and/or trialkoxysilyl group bonded to a silicon atom of said organosiloxane via an organic group which may have an oxygen atom, and 100 to 10000 parts by weight, per total 100 parts by weight of said components (a), (b), (c) and (d), of (e) an organic solvent having a fluorine atom and a boiling point of not higher than 150° C. at atmospheric pressure.
    • 一种氟化弹性体或氟化凝胶的底漆组合物,所述底漆组合物包含:100重量份的(a)每分子具有至少两个烯基的直链全氟聚醚化合物,全氟聚醚主链具有由式 ,其中a为1至6的整数,重均分子量为5,000至100,000,(b)一种或多种 在分子中具有一个或多个氟原子和至少两个SiH键的有机硅氧烷化合物的量使得组分(a)中有机硅氧烷化合物中的SiH键与烯基的摩尔比为0.8-5.0,催化剂 (c)氢化硅烷化催化剂的量,5〜100重量份的(d)有机硅氧烷化合物,其每分子具有至少一个SiH键和至少一个环氧基和/或与所述卤素键的硅原子键合的环氧基和/或三烷氧基甲硅烷基 有机硅氧烷通过可能具有氧的有机基团 om,100〜10000重量份,相对于(e)具有氟原子和沸点的有机溶剂的总计100重量份组分(a),(b),(c)和(d)), 在大气压下不高于150℃。
    • 5. 发明授权
    • Primer composition for a fluorinated elastomer or a fluorinated gel
    • 含氟弹性体或氟化凝胶的底漆组合物
    • US07485693B2
    • 2009-02-03
    • US11177304
    • 2005-07-11
    • Takashi MatsudaYasuhisa OsawaKenichi Fukuda
    • Takashi MatsudaYasuhisa OsawaKenichi Fukuda
    • C08G77/24C08G77/00C08G77/12B32B9/04
    • B05D5/083B05D7/544B05D7/546C08L71/02C09D171/02Y10T428/31663C08L83/00
    • A primer composition for a fluorinated elastomer or a fluorinated gel, said primer composition comprising: 100 parts by weight of (a) a linear perfluoro polyether compound having at least two alkenyl groups per molecule, a perfluoro polyether backbone having repeating units represented by the formula, —CaF2aO—, wherein a is an integer of from 1 to 6, and a weight average molecular weight of from 5,000 to 100,000, (b) an organosiloxane compound having one or more fluorine atom and at least two SiH bonds per molecule, in such an amount that a molar ratio of the SiH bond in the organosiloxane compound to the alkenyl group in Component (a) ranges from 0.8 to 5.0, a catalytic amount of (c) a hydrosilylation catalyst, 5 to 100 parts by weight of (d) an organosiloxane compound having, per molecule, at least one SiH bond and at least one epoxy group and/or trialkoxysilyl group bonded to a silicon atom of said organosiloxane via an organic group which may have an oxygen atom, and 100 to 10000 parts by weight, per total 100 parts by weight of said components (a), (b), (c) and (d), of (e) an organic solvent having a fluorine atom and a boiling point of not higher than 150° C. at atmospheric pressure.
    • 一种氟化弹性体或氟化凝胶的底漆组合物,所述底漆组合物包含:100重量份的(a)每分子具有至少两个烯基的直链全氟聚醚化合物,全氟聚醚主链具有由式 ,-CaF2aO-,其中a为1至6的整数,重均分子量为5,000至100,000,(b)每分子具有一个或多个氟原子和至少两个SiH键的有机硅氧烷化合物,在 (a)中的有机硅氧烷化合物中的SiH键与烯基的摩尔比为0.8〜5.0,(c)氢化硅烷化催化剂的催化量为5〜100重量份(d )每分子具有至少一个SiH键和至少一个环氧基和/或三烷氧基甲硅烷基的有机硅氧烷化合物,其通过可能具有氧原子的有机基团与所述有机硅氧烷的硅原子键合,并且100至10000p (e)具有氟原子且沸点不高于150°的有机溶剂的组分(a),(b),(c)和(d))的总重量为100重量份 C.在大气压下。