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    • 10. 发明申请
    • Radiation Curable Composition and Curing Product Thereof, and Laminate Including the Same
    • 辐射固化组合物及其固化产品及其包括的层压材料
    • US20080102262A1
    • 2008-05-01
    • US11718835
    • 2005-11-08
    • Akira EsakiOsamu Matsuda
    • Akira EsakiOsamu Matsuda
    • B32B27/00C08F2/46
    • B32B27/36C08G18/44C08G18/4854C08G18/672C09D175/16G11B7/24056G11B7/2433G11B7/2531G11B7/2533G11B7/2534G11B7/2542G11B7/2545G11B7/2585C08G18/6692C08G18/0823C08G18/6659
    • A radiation-curable composition capable of giving a cured product which has excellent transparency, mechanical strength and an excellent balance between surface hardness and resistance to deformation by heat/humidity; the cured product; and a multilayer structure which has a layer of the cured product and is suitable for use as an optical recording medium, etc, are provided A radiation-curable composition which comprises a monomer having a radiation-curable group and gives a cured product having the following properties: (1) when the cured product has a thickness of 100±5 μm, the cured product has a light transmittance at a wavelength of 550 nm of 80% or higher; (2) a multilayer structure where a layer of the cured product having a thickness of 100±5 μm is formed on a poly(ethylene terephthalate) film having a thickness of 100±5 μm, has a surface hardness of HB or higher; and (3) when a multilayer structure where the cured product having a thickness of 100±5 μm is formed on a disk made of a polycarbonate having a diameter of 130 mm and a thickness of 1.2±0.2 mm, is placed in an environment of 80° C. and 85% RH for 100 hours, then an absolute value |a| of an amount of warpage, a (mm), on the circumference of the multilayer structure is 0.5 mm or less.
    • 能够提供透明性,机械强度以及表面硬度与耐热/湿度变形抗性之间优异平衡的固化物的可辐射固化组合物; 固化产品; 提供具有固化产物层并适合用作光学记录介质等的多层结构体。一种可辐射固化组合物,其包含具有可辐射固化基团的单体,并得到具有以下成分的固化产物 性质:(1)固化物的厚度为100±5μm时,固化物的波长550nm的透光率为80%以上, (2)在厚度为100±5μm的聚对苯二甲酸乙二酯膜上形成厚度为100±5μm的固化物层的多层结构体,其表面硬度为HB以上; 和(3)当在由直径为130mm,厚度为1.2±0.2mm的聚碳酸酯制成的圆盘上形成厚度为100±5μm的固化产物的多层结构体置于 80℃和85%RH下100小时,则绝对值| a | 在多层结构的圆周上的翘曲量(mm)为0.5mm以下。