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    • 1. 发明申请
    • Block copolymer mixture containing star-branched block copolymer
    • 含有星形支链嵌段共聚物的嵌段共聚物混合物
    • US20060211818A1
    • 2006-09-21
    • US10549572
    • 2004-03-19
    • Hiroyuki KurimuraJun WatanabeTakeshi OotsukaShigeru SuzukiTakeshi OdaNorihiro Shimizu
    • Hiroyuki KurimuraJun WatanabeTakeshi OotsukaShigeru SuzukiTakeshi OdaNorihiro Shimizu
    • C08L53/00
    • C08F297/04C08F297/044C08L25/04C08L53/02C08L2666/04
    • To provide a block copolymer mixture containing a branched block copolymer such that it is excellent in balance between transparency and impact resistance, and a molded product formed from it by injection molding particularly under a high shearing force is less likely to have anisotropy and is thereby excellent in impact resistance. A block copolymer mixture containing a branched block copolymer characterized in that it has at least three types of polymer blocks with different molecular weights, each comprising a vinyl aromatic hydrocarbon as monomer units, the molecular weight distribution of a mixture of the polymer blocks S1, S2 and S3 each comprising a vinyl aromatic hydrocarbon as monomer units is within a specific range, and in a gel permeation chromatogram of the mixture of three types of the polymer blocks S1, S2 and S3, M1/M3 and M2/M3 are within specific ranges, where M1, M2 and M3 are peak top molecular weights of the respective polymer blocks.
    • 为了提供含有支链嵌段共聚物的嵌段共聚物混合物,其透明性和耐冲击性之间的平衡优异,特别是在高剪切力下通过注射成型而形成的成型体不太可能具有各向异性,因此优异 耐冲击性。 含有支链嵌段共聚物的嵌段共聚物混合物,其特征在于其具有至少三种具有不同分子量的聚合物嵌段,每种聚合物嵌段包含乙烯基芳族烃作为单体单元,聚合物嵌段S1,S2的混合物的分子量分布 和包含乙烯基芳烃作为单体单元的S3均在特定范围内,并且在三种类型的聚合物嵌段S1,S2和S3的混合物的凝胶渗透色谱图中,M1 / M3和M2 / M3在特定范围内 其中M1,M2和M3是各聚合物嵌段的峰顶分子量。
    • 6. 发明授权
    • Linear block copolymer composition
    • 线性嵌段共聚物组成
    • US07977428B2
    • 2011-07-12
    • US10549574
    • 2004-03-19
    • Hiroyuki KurimuraJun WatanabeTakeshi OdaNorihiro Shimizu
    • Hiroyuki KurimuraJun WatanabeTakeshi OdaNorihiro Shimizu
    • C08L53/02C08F297/04
    • C08L53/02C08F297/04C08L53/00
    • To provide a block copolymer composition excellent in balance of transparency, impact resistance, etc. in the form of not only an excluded product and a blow molded product but also an injection molded product.A linear block copolymer composition having at least three types of polymer blocks with different molecular weights each comprising a vinyl aromatic hydrocarbon as monomer units, wherein the molecular weight distribution of a mixture of the polymer blocks is within a specific range, and in GPC of the mixture, M1/M2 is within a specific range, where M1 is the peak top molecular weight corresponding to a peak at which the peak top molecular weight becomes maximum among peaks forming a proportion of the area of at least 30% to the whole peak area, and M2 is the peak top molecular weight corresponding to a peak at which the peak top molecular weight becomes minimum among peaks at which the peak top molecular weight is at most 50,000 and which form a proportion of the area of at least 20% to the whole peak area.
    • 为了提供不仅不包括产品和吹塑产品以及注塑产品的形式的透明性,耐冲击性等的平衡优异的嵌段共聚物组合物。 具有至少三种具有不同分子量的聚合物嵌段的线性嵌段共聚物组合物,其各自包含乙烯基芳族烃作为单体单元,其中聚合物嵌段的混合物的分子量分布在特定范围内,并且在GPC 混合物中,M1 / M2在特定范围内,其中M1是峰顶分子量,峰顶分子量对应于峰顶分子量峰值之间的峰值,其形成与整个峰面积至少30%的面积比例 ,M2是峰顶分子量对应于峰顶分子量峰值在峰顶分子量为50,000以下的峰中峰值的峰值,并且其峰面积的比例至少为20% 全峰面积。
    • 7. 发明申请
    • Linear block copolymer composition
    • 线性嵌段共聚物组成
    • US20060211823A1
    • 2006-09-21
    • US10549574
    • 2004-03-19
    • Hiroyuki KurimuraJun WatanabeTakeshi OdaNorihiro Shimizu
    • Hiroyuki KurimuraJun WatanabeTakeshi OdaNorihiro Shimizu
    • C08F297/02
    • C08L53/02C08F297/04C08L53/00
    • To provide a block copolymer composition excellent in balance of transparency, impact resistance, etc. in the form of not only an excluded product and a blow molded product but also an injection molded product. A linear block copolymer composition having at least three types of polymer blocks with different molecular weights each comprising a vinyl aromatic hydrocarbon as monomer units, wherein the molecular weight distribution of a mixture of the polymer blocks is within a specific range, and in GPC of the mixture, M1/M2 is within a specific range, where M1 is the peak top molecular weight corresponding to a peak at which the peak top molecular weight becomes maximum among peaks forming a proportion of the area of at least 30% to the whole peak area, and M2 is the peak top molecular weight corresponding to a peak at which the peak top molecular weight becomes minimum among peaks at which the peak top molecular weight is at most 50,000 and which form a proportion of the area of at least 20% to the whole peak area.
    • 为了提供不仅不包括产品和吹塑产品以及注塑产品的形式的透明性,耐冲击性等的平衡优异的嵌段共聚物组合物。 具有至少三种具有不同分子量的聚合物嵌段的线性嵌段共聚物组合物,其各自包含乙烯基芳族烃作为单体单元,其中聚合物嵌段的混合物的分子量分布在特定范围内,并且在GPC 混合物中,M1 / M2在特定范围内,其中M1是峰顶分子量,峰顶分子量对应于峰顶分子量峰值之间的峰值,其形成与整个峰面积至少30%的面积比例 ,M2是峰顶分子量对应于峰顶分子量峰值在峰顶分子量为50,000以下的峰中峰值的峰值,并且其峰面积的比例至少为20% 全峰面积。
    • 10. 发明授权
    • Mouth cleaning device
    • 口清洁装置
    • US4365376A
    • 1982-12-28
    • US217002
    • 1980-11-14
    • Takeshi OdaToshio TanabeYoshimasa Tanaka
    • Takeshi OdaToshio TanabeYoshimasa Tanaka
    • F16L11/127A61C17/02A61C17/22A61C17/36A46B13/06
    • A61C17/36A61C17/02A61C17/22
    • A mouth cleaning device of this invention comprises a hand held gripping part with brush and nozzle members selectively mounted thereto. The gripping part is provided with a driving rod for transmitting to the selectively mounted brush member a reciprocal turning force and for providing to the selectively mounted nozzle member a water feeding path to lead water to the nozzle member from an external water feeding means. A driving means provides a reciprocal turning force to the driving rod. A change-over switch drives the driving means only when the brush member is mounted so that, when the brush member is mounted to the gripping part, the brush member will be reciprocally turned to perform tooth brushing. When the nozzle member is mounted to the gripping part, water will be jetted out of the nozzle member to perform gum cleaning and massaging.
    • PCT No.PCT / JP80 / 00043 Sec。 371日期1980年11月14日 102(e)1980年11月14日PCT PCT Fils 3月13日,PCT PCT。 出版物WO80 / 01873 日本1980年9月18日。本发明的清洗器具包括具有刷子的手持夹持部件和选择性地安装在其上的喷嘴部件。 夹持部设置有驱动杆,用于向选择性地安装的刷构件传递往复转动力,并且向选择性地安装的喷嘴构件提供从外部给水装置将水引导到喷嘴构件的供水路径。 驱动装置向驱动杆提供往复转动力。 转换开关仅在刷子安装时驱动驱动装置,使得当刷子安装到抓握部分时,刷子部件将往复转动以进行牙刷。 当喷嘴构件安装到夹持部分时,水将从喷嘴构件喷出,以进行牙龈清洁和按摩。