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1. 发明授权

US06627714B2 Method for producing an olefin type copolymer having a cyclic structure 有权
标题翻译：具有环状结构的烯烃类共聚物的制造方法
公开(公告)号：US06627714B2
公开(公告)日：2003-09-30
申请号：US09985488
申请日：2001-11-05
申请人： Shigeharu Yamamoto , Sakae Kamiyama , Toshifumi Takemori , Yoji Suzuki , Kazuhiko Mizuno , Yoko Furuyama , Hiroshi Yamazaki
发明人： Shigeharu Yamamoto , Sakae Kamiyama , Toshifumi Takemori , Yoji Suzuki , Kazuhiko Mizuno , Yoko Furuyama , Hiroshi Yamazaki
IPC分类号： C08F444
CPC分类号： C08F232/08 , C08F4/65912 , C08F210/02 , Y10S526/905 , Y10S526/916 , C08F4/65927 , C08F2500/03 , C08F232/04
摘要： An olefinic copolymer having a cyclic structure is prepared by copolymerizing a) ethylene (M1) and b) dicyclopentadiene or tricyclopentadiene (M2), and, optionally c) a cyclic olefin (M3), in the presence of a catalyst which contains a metallocene compound (A) having formula [1]: H2C(R′mCp)(R″nCp)MX2[1], wherein M is zirconium or hafnium, Cp has a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Yp, a thioalkyl group, or a thioaryl group of the formula —S—Ar—Yp; wherein Ar is an aromatic ring, Y is a halogen, a hydrogen, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino group, a cyano group or a nitro group, and p is an integer of from 1 to 5, and each of m and n is an integer of from 0 to 4, provided that m and n are not equal, and m+n is an integer of from 3 to 6, and an aluminoxane (B), is used.
摘要翻译：具有环状结构的烯烃共聚物通过在含有茂金属化合物的催化剂存在下共聚a）乙烯（M1）和b）二环戊二烯或三环戊二烯（M2），和任选地c）环状烯烃（M3）（A）具有式[1]：H2C（R'mCp）（R''nCp）MX2 [1]其中M为锆或铪，Cp为环戊二烯基骨架，R'和R“为烃具有1至10个碳原子的基团可以彼此相同或不同的两个X是卤素，氢，具有1至20个碳原子的烃基，卤代烃基，烷基氨基，烷氧基，式-O-Ar-Yp的芳氧基，式-S-Ar-Yp的硫代烷基或硫代芳基; 其中Ar为芳环，Y为卤素，氢，碳原子数1〜20的烃基，卤代烃基，烷氧基，烷基氨基，氰基或硝基，p为 m和n分别为1〜5，m和n为0〜4的整数，m和n不相等，m + n为3〜6的整数，铝氧烷（B），用来。

2. 发明授权

US06455647B1 Solid catalyst for olefin polymerization and process for producing olefin polymer with the same 失效
标题翻译：用于烯烃聚合的固体催化剂和用于制备烯烃聚合物的方法
公开(公告)号：US06455647B1
公开(公告)日：2002-09-24
申请号：US09581042
申请日：2000-06-08
申请人： Sakae Kamiyama , Toshifumi Takemori , Minoru Iijima , Yukiko Hane , Shigeharu Yamamoto
发明人： Sakae Kamiyama , Toshifumi Takemori , Minoru Iijima , Yukiko Hane , Shigeharu Yamamoto
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , Y10S526/943 , C08F4/65916 , C08F210/16 , C08F210/14 , C08F2500/03
摘要： The present invention relates to a solid catalyst (D) for olefin polymerization comprising a magnesium-containing solid component (A) carrying thereon an organoaluminum-oxy compound (B) and a metallocene compound (C), the magnesium-containing compound (A) being obtained by heat treating a magnesium compound represented by the general formula: MgX2.nH2O where X represents a halogen atom and n is an integer of 1 to 12, and to a method of producing an olefinic polymer using the catalyst. In the case where the above solid catalyst for olefin polymerization is used, catalyst activity, particularly activity per solid catalyst, is high. Therefore, a deashing treatment step such as catalyst removal can be omitted. Further, the olefinic polymer produced has a narrow molecular weight distribution, and in the case of a copolymer, its monomer composition is uniform.
摘要翻译：本发明涉及一种用于烯烃聚合的固体催化剂（D），其包含含有有机铝 - 氧化合物（B）和茂金属化合物（C）的含镁固体组分（A），含镁化合物（A）通过热处理由通式MgX 2·nH 2 O表示的镁化合物得到，其中X表示卤素原子，n表示1〜12的整数，以及使用该催化剂制造烯烃类聚合物的方法。在使用上述用于烯烃聚合的固体催化剂的情况下，催化剂活性，特别是每固体催化剂的活性高。因此，可以省略诸如催化剂去除的脱气处理步骤。此外，所生产的烯烃聚合物具有窄的分子量分布，在共聚物的情况下，其单体组成是均匀的。

3. 发明授权

US06368995B1 Solid catalysts for the polymerization of olefins and process for the production of olefin polymers therewith 失效
标题翻译：用于烯烃聚合的固体催化剂和用于生产烯烃聚合物的方法
公开(公告)号：US06368995B1
公开(公告)日：2002-04-09
申请号：US09530264
申请日：2000-06-08
申请人： Sakae Kamiyama , Toshifumi Takemori , Minoru Iijima , Yukiko Hane , Shigeharu Yamamoto
发明人： Sakae Kamiyama , Toshifumi Takemori , Minoru Iijima , Yukiko Hane , Shigeharu Yamamoto
IPC分类号： B01J3122
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/02 , C08F4/65916 , C08F4/61912 , C08F4/61916 , C08F2500/18 , C08F2500/24 , C08F2500/03 , C08F210/14
摘要： A solid catalyst for olefin polymerization, obtained by reacting a least one of a hydropolysiloxane compound, having the formula R1aHbSiO(4−a−b)/2, a silane compound of formula R2cSi(OH)4−c, and condensates of the silane, with a compound of formula (MgR32)p.(R3MgX)q to form a reaction product. The reaction product is reacted with an alcohol, having 1 to 4 carbon atoms, to obtain an intermediate product. The intermediate product, is then reacted with water to obtain reaction product. An organoaluminum oxy compound and a metallocene compound are carried on the solid reaction product. The solid catalyst may be used for olefin polymerization. The catalyst requires no deashing treatment and produces a polymer having high bulk density and narrow particle size distribution. Thus the solid catalystenables control of particle size of the polymer in a simple easy manner, and shows no adhesion of polymer onto the inner wall of autoclave.
摘要翻译：一种用于烯烃聚合的固体催化剂，其通过使具有式R1aHbSiO（4-ab）/ 2的氢化聚硅氧烷化合物，式R 2 c Si（OH）4-c的硅烷化合物和硅烷的缩合物中的至少一种与硅烷的缩合物与式（MgR32）p。（R3MgX）q的化合物以形成反应产物。使反应产物与具有1至4个碳原子的醇反应以获得中间产物。然后将中间产物与水反应以获得反应产物。有机铝氧化合物和茂金属化合物载于固体反应产物上。固体催化剂可用于烯烃聚合。该催化剂不需要脱屑处理，并且产生具有高堆积密度和窄粒度分布的聚合物。因此，固体催化剂以简单的方式控制聚合物的粒度，并且不显示聚合物对高压釜的内壁的粘附。

4. 发明授权

US4742132A Process for the polymerization or copolymerization of ethylene 失效
标题翻译：乙烯的聚合或共聚方法
公开(公告)号：US4742132A
公开(公告)日：1988-05-03
申请号：US921824
申请日：1986-10-21
申请人： Hiroshi Morinaga , Shigeharu Yamamoto , Sakae Kamiyama , Takeshi Iwabuchi
发明人： Hiroshi Morinaga , Shigeharu Yamamoto , Sakae Kamiyama , Takeshi Iwabuchi
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A process for polymerizing or copolymerizing ethylene, characterized in that ethylene or a mixture of ethylene with other .alpha.-olefin is polymerized in the presence of a catalyst comprising:[I] a solid catalyst component (B) obtained by reacting the following three components:(a) a reaction product (A) of an organomagnesium compound with a hydropolysiloxane or a silicon compound in which organic groups and hydroxyl groups are bonded to silicon atoms,(b) a silicon compound of the formula R.sub.l.sup.1 Si(OR.sup.2).sub.m X.sub.4-(l+m), wherein R.sup.1 is a hydrogen atom or a hydrocarbon group having from 1 to 8 carbon atoms, R.sup.2 is a hydrocarbon group having from 1 to 12 carbon atoms, X is a halogen atom, l is 0, 1 or 2, and m is a number of from 0 to 4, and(c) a titanium compound of the formula Ti(OR.sup.3).sub.n X.sub.4-n, wherein R.sup.3 is a hydrocarbon group having from 1 to 12 carbon atoms, X is a halogen atom, and n is a number of 0 to 4, provided that m and n are not simultaneously 0, and when m is 0, n is 4, and[II] an organoaluminum compound.
摘要翻译：一种聚合或共聚乙烯的方法，其特征在于乙烯或乙烯与其它α-烯烃的混合物在催化剂存在下聚合，所述催化剂包括：[I]通过使以下三种组分反应得到的固体催化剂组分（B）（a）有机镁化合物与有机基团和羟基与硅原子键合的氢化聚硅氧烷或硅化合物的反应产物（A），（b）式R 1 Si（OR 2）m X 4 - （l + m），其中R 1是氢原子或具有1至8个碳原子的烃基，R 2是具有1至12个碳原子的烃基，X是卤素原子，l是0,1或2，以及 m为0〜4的数，（c）式Ti（OR 3）n X 4-n的钛化合物，其中，R 3为碳原子数1〜12的烃基，X为卤素原子，n为是0〜4的数，条件是m和n不同时为0，当m为0时，n为4，[II]为器官铝化合物。

5. 发明授权

US4464518A Process for the polymerization or copolymerization of ethylene 失效
标题翻译：乙烯的聚合或共聚方法
公开(公告)号：US4464518A
公开(公告)日：1984-08-07
申请号：US385314
申请日：1982-06-04
申请人： Takeshi Iwabuchi , Hiroshi Morinaga , Masao Kawahara , Sakae Kamiyama , Terumi Sato , Muneto Yokota
发明人： Takeshi Iwabuchi , Hiroshi Morinaga , Masao Kawahara , Sakae Kamiyama , Terumi Sato , Muneto Yokota
IPC分类号： C08F4/62 , C08F10/00 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00 , Y10S526/909
摘要： Polymerization of ethylene or copolymerization of ethylene with other .alpha.-olefin is carried out in the presence of a specific catalyst system. The catalyst system is obtained by preparing a reaction product (A) of an organic aluminum compound (I) represented by the formula AlR.sub.n.sup.1 X.sub.3-n where R.sup.1 is hydrogen or an alkyl group having from 1 to 10 carbon atoms, X is Cl or Br and n is a number satisfying 0
摘要翻译：乙烯的聚合或乙烯与其它α-烯烃的共聚在特定催化剂体系的存在下进行。催化剂体系是通过制备由式AlRn1X3-n表示的有机铝化合物（I）的反应产物（A）得到的，其中R 1是氢或具有1至10个碳原子的烷基，X是Cl或Br，和 n是满足0

6. 发明授权

US4657996A Process for producing polyethylene 失效
标题翻译：生产聚乙烯的方法
公开(公告)号：US4657996A
公开(公告)日：1987-04-14
申请号：US833670
申请日：1986-02-27
申请人： Takeshi Iwabuchi , Masao Kawahara , Sakae Kamiyama , Terumi Sato
发明人： Takeshi Iwabuchi , Masao Kawahara , Sakae Kamiyama , Terumi Sato
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/62 , C08F10/02
CPC分类号： C08F10/02 , Y02P20/52
摘要： A process for producing polyethylene comprises polymerizing ethylene or copolymerizing ethylene with other .alpha.-olefin in the presence of a catalyst system obtained by bringing the following components (I) to (III) in contact with one another:(I) a reaction product (B) obtained by reacting an intermediate reaction product (A) obtained by a reaction of a hydropolysiloxane with a Grignard reagent, with at least one nucleophilic reagent selected from an aldehyde, a ketone and an alcohol,(II) a transition metal compound, and(III) at least one organic aluminum compound.
摘要翻译：一种生产聚乙烯的方法包括在催化剂体系存在下聚合乙烯或将乙烯与其它α-烯烃共聚，所述催化剂体系通过使以下组分（I）至（III）彼此接触而获得：（I）反应产物（B ）通过使通过氢化聚硅氧烷与格利雅试剂的反应获得的中间反应产物（A）与至少一种选自醛，酮和醇的亲核试剂反应获得，（II）过渡金属化合物和（ III）至少一种有机铝化合物。

7. 发明授权

US5422400A Method for producing an ethylenic polymer composition 失效
标题翻译：烯属聚合物组合物的制造方法
公开(公告)号：US5422400A
公开(公告)日：1995-06-06
申请号：US285762
申请日：1994-08-03
申请人： Sakae Kamiyama , Masao Kawahara , Kunihiro Inamatsu , Keizo Kase , Kouji Mizokami , Tsuyoshi Matsumoto
发明人： Sakae Kamiyama , Masao Kawahara , Kunihiro Inamatsu , Keizo Kase , Kouji Mizokami , Tsuyoshi Matsumoto
IPC分类号： C08F4/638 , C08F4/60 , C08F4/685 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/06 , C08L23/08
CPC分类号： C08F10/00 , C08F10/02 , C08L23/04 , C08F110/02 , C08F210/16
摘要： The invention relates to a method for producing an ethylenic polymer composition, suitable for molding, at high catalytic efficiency. The ethylenic polymer composition produced has as a high melt tension when melted, and a high melt modulus (die swell ratio). The process comprises a three step polymerization of an olefin employing a transition metal catalyst, the catalyst being produced in a specific manner.
摘要翻译：本发明涉及一种适用于以高催化效率成型的乙烯聚合物组合物的制备方法。所生成的乙烯类聚合物组合物在熔融时具有高熔体张力，并具有高熔体模量（模头膨胀比）。该方法包括使用过渡金属催化剂的烯烃三步聚合，催化剂以特定的方式制备。

8. 发明授权

US4643986A Process for preparing a catalyst for polymerization or copolymerization of ethylene 失效
标题翻译：制备乙烯聚合或共聚催化剂的方法
公开(公告)号：US4643986A
公开(公告)日：1987-02-17
申请号：US847473
申请日：1986-04-03
申请人： Hiroshi Morinaga , Sakae Kamiyama , Yuzo Sato
发明人： Hiroshi Morinaga , Sakae Kamiyama , Yuzo Sato
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F4/658 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F10/02
摘要： A process for preparing a catalyst for polymerization or copolymerization of ethylene, which comprises reacting a silicone compound (I) of the formula R.sup.4.sub.a H.sub.b SiO.sub.(4-a-b)/2 or R.sup.5.sub.n Si(OH).sub.4-n or a condensate thereof and an organomagnesium compound (II) of the formula (MgR.sup.6.sub.2).sub.p.(R.sup.6 MgX).sub.q to obtain a product (A), reacting the product (A) with a titanium compound (III) of the formula Ti(OR.sup.2).sub.m X.sub.4-m and a silicone halide compound (IV) of the formula R.sup.1.sub.L SiX.sub.4-L to obtain a product (B), reacting the product (B) with an organoaluminum halide compound (V) of the formula R.sup.3.sub.c AlX.sub.3-c to obtain a solid component (C), and bringing the solid component (C) in contact with an organoaluminum compound (VI) of the formula R.sub.d AlY.sub.3-d.
摘要翻译：一种制备用于乙烯聚合或共聚的催化剂的方法，其包括将式R4aHbSiO（4-ab）/ 2或R5nSi（OH）4-n的硅氧烷化合物（I）或其缩合物与有机镁化合物 II）式（MgR 62）p（R6MgX）q，得到产物（A），使产物（A）与式Ti（OR 2）m X 4-m的钛化合物（III）和硅氧烷化合物（Ⅳ），得到产物（B），使产物（B）与式R3cAlX3-c的有机铝卤化物（Ⅴ）反应得到固体成分（C），并使固体组分（C）与式RDAlY3-d的有机铝化合物（VI）接触。

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