会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明授权
    • Organometallic catalysts containing hydrotris(pyrazolyl) borate and
cyclopentadienyl groups, and processes of employing the same
    • 含有氢三(吡唑基)硼酸酯和环戊二烯基的有机金属催化剂及其应用方法
    • US5519099A
    • 1996-05-21
    • US481113
    • 1995-06-07
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiYu-Hwa E. Sheu
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiYu-Hwa E. Sheu
    • C08F4/619C08F4/6192C08F4/62C08F4/622C08F4/64C08F4/642C08F10/00C08F10/02
    • C08F10/00C08F10/02C08F4/61908C08F4/61912C08F4/6192Y10S526/943
    • A catalyst composition is disclosed for catalyzing the polymerization and copolymerization reactions of ethylene monomers, with or without another olefin monomer. The catalyst composition comprises a metallocene compound represented by the the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY or the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopendadienyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrotrispyrazolyl borate or hydrotris-3,5-dimethyl; (c) M is Group IIIB, Group IVB, or Group VB transitional metal; (d) X is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; (e) Y, which can the same as or different from X, is a C.sub.1 to C.sub.4 alkyl or alkenyl group, an aromatic group, an alkylaryl, a halogen, a hydrogen, or a silane group; and (f) A.sup.- is non-coordinated or loosely coordinated bulky anion. Examples of the (C.sub.5 R.sub.n H.sub.5-n)(L)MXY and (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sup.+ A.sup.- metallocene compounds are represented by the following formulas: ##STR1## respectively.
    • 公开了用于催化乙烯单体与或不与其它烯烃单体的聚合和共聚反应的催化剂组合物。 催化剂组合物包含由式(C5RnH5-n)(L)MXY或式(C5RnH5-n)(L)MX + A-表示的茂金属化合物; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢四吡啶基硼酸盐或氢化三-3,5-二甲基; (c)M为IIIB族,IVB族或VB族过渡金属; (d)X是C1-C4烷基或烯基,芳基,烷基芳基,卤素,氢或硅烷基; (e)与X相同或不同的Y为C1-C4烷基或烯基,芳基,烷基芳基,卤素,氢或硅烷基; 和(f)A-是非协调或松散配位的大体积阴离子。 (C5RnH5-n)(L)MXY和(C5RnH5-n)(L)MX + A-茂金属化合物的实例分别由下式表示:
    • 2. 发明授权
    • Single site catalyst with methyl aluminoxane or borate free and their
applications for the preparation of polyolefins
    • 具有甲基铝氧烷或无硼酸盐的单中心催化剂及其在制备聚烯烃中的应用
    • US6150529A
    • 2000-11-21
    • US249511
    • 1999-02-12
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiChing Ting
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiChing Ting
    • C07F5/02C07F7/00C07F17/00C07F19/00C08F4/64
    • C08F10/00C08F110/02C08F4/65912Y10S526/943
    • A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Grcup IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1 or ER.sup.1 R.sup.2, where E is a Group VA or VIA element, and R.sup.1 and R.sup.2, which can be the same or different from each other, are C.sub.1 to C.sub.6 alkyl group or substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
    • 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(C5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,Grcup IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1或ER1R2表示的卤素原子或配体,其中E是VA族或VIA族,R1和R2可以 彼此相同或不同,为C1至C6烷基或取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
    • 3. 发明授权
    • Single site catalysts with MAO or borate free and their application for
polyolefins
    • 具有MAO或无硼酸盐的单中心催化剂及其在聚烯烃中的应用
    • US5891816A
    • 1999-04-06
    • US897862
    • 1997-07-21
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiChing Ting
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cherng TsaiChing Ting
    • C07F5/02C07F7/00C07F17/00C07F19/00C08F4/64
    • C08F10/00C08F110/02C08F4/65912Y10S526/943
    • A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (CR.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
    • 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(CR5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1表示的卤素原子或配体,其中E是VA族或VIA族,R1是C1-C6烷基, 芳基或卤素取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
    • 5. 发明授权
    • Process for the polymerization or copolymerization of ethylene using
mao-  or borate-free single site catalysts
    • 使用无硼酸盐或无硼酸盐的单中心催化剂聚合或共聚乙烯的方法
    • US5684098A
    • 1997-11-04
    • US602206
    • 1996-02-15
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cheing TsaiChing Ting
    • Shian-Jy WangYi-Chun ChenShu-Hua ChanJing-Cheing TsaiChing Ting
    • C08F4/619C08F4/6192C08F4/62C08F4/622C08F4/64C08F4/642C08F10/00C08F10/02
    • C08F10/00C08F10/02C08F4/61908C08F4/61912C08F4/6192Y10S526/943
    • A novel organometallic compound is disclosed which can be used, in conjunction with a trialkyl or bialkyl aluminum cocatalyst, for catalyzing the polymerization and copolymerization of ethylene without requiring the use of either methyl aluminoxane or borate as cocatalyst. The organometallic compound is represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MX.sub.a Y.sub.b ; wherein: (a) C.sub.5 R.sub.n H.sub.5-n is a substituted or unsubstituted cyclopentadienyl group, in which n is an integer between 0 and 5, and R is C.sub.1 to C.sub.6 alkyl group; (b) L is tetrapyrazolyl borate, hydrotrispyrazolyl borate, dihydrobispyrazolyl borate or hydrotris(3,5-dimethylpyrazolyl) borate; (c) M is a Group IIIB, Group IVB, or Group VB transitional metal; (d) a and b are integers such that a+b=m-2, where m is the valance of M; and (e) X and Y, which can be the same of different from each other, are halogen atoms or ligands represented by the formula of ER.sup.1, where E is a Group VA or VIA element, and R.sup.1 is C.sub.1 to C.sub.6 alkyl group, aryl group or halogen-substituted aryl group. Preferably, M is a Group IVB transitional metal and a=b=1, and the organometallic compound is then represented by the formula of (C.sub.5 R.sub.n H.sub.5-n)(L)MXY.
    • 公开了一种可与三烷基或双烷基铝助催化剂结合使用的用于催化乙烯的聚合和共聚而不需要使用甲基铝氧烷或硼酸盐作为助催化剂的新型有机金属化合物。 有机金属化合物由式(C5RnH5-n)(L)MXaYb表示; 其中:(a)C5RnH5-n是取代或未取代的环戊二烯基,其中n是0和5之间的整数,R是C1-C6烷基; (b)L是四吡唑基硼酸盐,氢四唑基硼酸盐,二氢双吡唑基硼酸盐或氢化三(3,5-二甲基吡唑基)硼酸盐; (c)M是IIIB族,IVB族或VB族过渡金属; (d)a和b是整数,使得a + b = m-2,其中m是M的化合价; 和(e)可以彼此不同的X和Y是由式ER1表示的卤素原子或配体,其中E是VA族或VIA族,R1是C1-C6烷基, 芳基或卤素取代的芳基。 优选地,M是IVB族过渡金属,a = b = 1,有机金属化合物由式(C5RnH5-n)(L)MXY表示。
    • 6. 发明授权
    • Catalyst composition for preparing high syndiotacticity polystyrene from
styrene of other arylethylene monomers and processes using the same
    • 用于由其它芳基乙烯单体的苯乙烯制备高间同立构聚苯乙烯的催化剂组合物和使用其的方法
    • US5644009A
    • 1997-07-01
    • US563272
    • 1995-11-27
    • Jing-Cherng TsaiShian-Jy WangShu-Ling PengMickey Sue
    • Jing-Cherng TsaiShian-Jy WangShu-Ling PengMickey Sue
    • C08F4/642C08F4/646C08F4/658C08F4/659C08F10/00C08F12/04C08F12/08
    • C08F10/00C08F12/04C08F4/65904C08F4/65908C08F4/65912
    • An catalyst composition for preparing high-syndiotacticity polystyrene polymers which comprises: (a) a titanium complex represented by the following formula of TiR'.sub.1 R'.sub.2 R'.sub.3 R'.sub.4 or TiR'.sub.1 R'.sub.2 R'.sub.3, wherein R'.sub.1, R'.sub.2, R'.sub.3, and R'.sub.4 are, independently, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrogen atom, or a halogen atom; (b) a cyclopentadienyl complex of silicon (Si), germanium (Ge), or tin (Sn) represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are, independently, an alkyl group, an aryl group, a silyl group, a germanyl group, a stannyl group, or a halogen atom; R is an alkyl group, aryl group, a hydrogen atom, or a halogen element; and X can be one of the Group IVA elements of silicon (Si), germanium (Ge), or tin (Sn); and (c) an activated transitional metal co-catalyst, which can be methyl aluminoxane, or a mixture containing a non-coordinated Lewis add (a Lewis acid is an electron-pair donor) and a trialkyl aluminum, such as triethyl aluminum or tetraisobutyl aluminum.
    • 一种用于制备高间同立构聚苯乙烯聚合物的催化剂组合物,其包含:(a)由下式TiR'1R'2R'3R'4或TiR'1R'2R'3表示的钛络合物,其中R'1,R' 2,R'3和R '4独立地是烷基,芳基,烷氧基,芳氧基,氨基,氢原子或卤素原子; (b)由下式表示的硅(Si),锗(Ge)或锡(Sn)的环戊二烯基络合物:其中R 1,R 2,R 3和R 4独立地为烷基,芳基 基团,甲硅烷基,锗烷基,甲锡烷基或卤素原子; R是烷基,芳基,氢原子或卤素元素; X可以是硅(Si),锗(Ge)或锡(Sn)的IVA族元素之一; 和(c)活化的过渡金属助催化剂,其可以是甲基铝氧烷,或含有不协调的路易斯添加剂(路易斯酸是电子对供体)和三烷基铝的混合物,例如三乙基铝或四异丁基 铝。