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    • 1. 发明申请
    • ALKYLENE OXIDE PRODUCTION
    • 烷基氧化铝生产
    • US20150191440A1
    • 2015-07-09
    • US14580683
    • 2014-12-23
    • SHELL OIL COMPANY
    • Arian VAN MOURIKIngmar Hubertus Josephina PLOEMEN
    • C07D301/04C07C407/00
    • C07D301/04B01D17/045C07C7/11C07C29/132C07C45/53C07C407/00C07D301/19C07C409/08C07C15/073C07C33/22C07C49/78
    • A process for preparing an alkylene oxide comprising contacting an alkyl phenyl hydroperoxide with an alkene in an epoxidation reaction to obtain an alkylene oxide and an alkyl phenyl alcohol, wherein the alkyl phenyl hydroperoxide is prepared by a process comprising reacting an alkyl aryl compound and oxygen to produce a reaction mixture comprising alkyl phenyl hydroperoxide, alkyl aryl compound and oxygen; separating at least a part of the reaction mixture into a product stream comprising alkyl phenyl hydroperoxide and an alkyl aryl compound stream; mixing at least a part of the alkyl aryl compound stream with a basic aqueous solution; separating at least a part of the mixture of alkyl aryl compound and basic aqueous solution with the help of a coalescer to obtain an organic phase containing alkyl aryl compound, and an aqueous phase; and recycling at least a part of the organic phase to the reacting step.
    • 一种制备烯化氧的方法,包括在环氧化反应中使烷基苯基氢过氧化物与烯烃接触以获得环氧烷和烷基苯醇,其中烷基苯基过氧化氢通过包括使烷基芳基化合物与氧反应的方法制备 产生包含烷基苯基氢过氧化物,烷基芳基化合物和氧的反应混合物; 将至少一部分反应混合物分离成包含烷基苯基氢过氧化物和烷基芳基化合物流的产物流; 将至少一部分烷基芳基化合物流与碱性水溶液混合; 在聚结器的帮助下分离烷基芳基化合物和碱性水溶液的混合物的至少一部分,得到含有烷基芳基化合物和水相的有机相; 并将至少一部分有机相再循环至反应步骤。