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1. 发明申请

US20110015062A1 COBALT/ZIRCONIUM-PHOSPHORUS/SILICA CATALYST FOR FISCHER-TROPSCH SYNTHESIS AND METHOD OF PREPARING THE SAME 审中-公开
标题翻译：用于FISCHER-TROPSCH合成的COBALT / ZIRCONIUM-PHOSPHORUS / SILICA催化剂及其制备方法
公开(公告)号：US20110015062A1
公开(公告)日：2011-01-20
申请号：US12933856
申请日：2009-02-16
申请人： Seung-Moon Kim , Jong-Wook Bae , Jong-Hyeok Oh , Yun-Jo Lee , Ki-won Jun
发明人： Seung-Moon Kim , Jong-Wook Bae , Jong-Hyeok Oh , Yun-Jo Lee , Ki-won Jun
IPC分类号： B01J27/185
CPC分类号： B01J27/1856 , B01J23/002 , B01J27/1853 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J37/0201 , B01J37/03 , B01J2523/00 , C10G2/332 , B01J2523/41 , B01J2523/48 , B01J2523/51 , B01J2523/821 , B01J2523/845
摘要： The present invention relates to a cobalt/zirconium-phosphorus/silica catalyst in which cobalt, as an active ingredient, is impregnated on a zirconium-phosphorus/silica support prepared by treating the surface of silica with zirconium and phosphorus, and a method of preparing the catalyst. The catalyst has excellent reactivity since it has excellent heat and mass transfer properties due to a large pore structure of silica and increased reducibility of cobalt; excellent dispersion of cobalt and other activation substances during Fischer-Tropsch (F-T) reaction; and reduced sintering of cobalt particles during the reaction, and thus high CO conversion and stable selectivity for liquid hydrocarbon can be obtained during the F-T reaction.
摘要翻译：本发明涉及一种钴/锆 - 磷/二氧化硅催化剂，其中钴作为活性成分浸渍在用锆和磷处理二氧化硅表面制备的锆 - 磷/二氧化硅载体上，以及制备方法催化剂。催化剂具有优异的反应性，因为由于二氧化硅的大孔结构和钴的还原性，它具有优异的热传质性能; 在费 - 托（F-T）反应中钴和其他活化物质的优异分散性; 并且在反应期间减少了钴颗粒的烧结，因此在F-T反应期间可以获得高CO转化率和对液态烃的稳定选择性。

2. 发明授权

US08084387B2 Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof 有权
标题翻译：钴/磷 - 氧化铝上的费 - 托合成催化剂及其制备方法
公开(公告)号：US08084387B2
公开(公告)日：2011-12-27
申请号：US12594617
申请日：2008-01-30
申请人： Ki-won Jun , Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee
发明人： Ki-won Jun , Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee
IPC分类号： B01J27/185 , B01J23/40 , B01J23/42 , B01J23/00 , B01J23/08 , C01F7/02 , C07C27/00 , C07C27/06
CPC分类号： B01J23/75 , B01J27/16 , B01J27/1853 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/109 , B01J37/0201 , B01J37/0207 , B01J37/033 , B01J37/18 , B01J37/28
摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.
摘要翻译：本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

3. 发明申请

US20100093523A1 CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS ON COBALT/PHOSPHORUS-ALUMINUM OXIDE AND PREPARATION METHODS THEREOF 有权
标题翻译：钴/磷 - 氧化铝合成催化剂及其制备方法
公开(公告)号：US20100093523A1
公开(公告)日：2010-04-15
申请号：US12594617
申请日：2008-01-30
申请人： Ki-won Jun , Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee
发明人： Ki-won Jun , Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee
IPC分类号： B01J27/185
CPC分类号： B01J23/75 , B01J27/16 , B01J27/1853 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/109 , B01J37/0201 , B01J37/0207 , B01J37/033 , B01J37/18 , B01J37/28
摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.
摘要翻译：本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

4. 发明授权

US08598066B2 Preparing phosphorus containing alumina support by sol-gel method for fischer-tropsch synthesis and catalyst preparation thereof 有权
标题翻译：通过溶胶 - 凝胶法制备含磷氧化铝载体，用于费 - 托合成及其催化剂制备
公开(公告)号：US08598066B2
公开(公告)日：2013-12-03
申请号：US12594695
申请日：2008-08-06
申请人： Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee , Ki-won Jun
发明人： Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee , Ki-won Jun
IPC分类号： B01J27/185 , B01J27/18
CPC分类号： B01J27/1853 , B01J21/04 , B01J23/75 , B01J27/16 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/033 , C10G2/33 , C10G2/332
摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.
摘要翻译：本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少由于在FT反应期间钴组分的氧化降低导致的失活速率。当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

5. 发明申请

US20100130349A1 PREPARING PHOSPHORUS CONTAINING ALUMINA SUPPORT BY SOL-GEL METHOD FOR FISCHER-TROPSCH SYNTHESIS AND CATALYST PREPARATION THEREOF 有权
标题翻译：通过溶胶凝胶法制备含有氧化铝的磷化合物，用于FISCHER-TROPSCH合成及其催化剂的制备
公开(公告)号：US20100130349A1
公开(公告)日：2010-05-27
申请号：US12594695
申请日：2008-08-06
申请人： Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee , Ki-won Jun
发明人： Jong-Wook Bae , Seung-Moon Kim , Yun-Jo Lee , Ki-won Jun
IPC分类号： B01J27/185 , B01J27/14 , B01J21/04 , B01J23/75
CPC分类号： B01J27/1853 , B01J21/04 , B01J23/75 , B01J27/16 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/033 , C10G2/33 , C10G2/332
摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.
摘要翻译：本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少由于在FT反应期间钴组分的氧化降低导致的失活速率。当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

6. 发明授权

US08852516B2 Method and apparatus for the continuous separation and discharge of solid catalysts and products for Fischer-Tropsch synthesis reactions 有权
标题翻译：用于费 - 托合成反应的固体催化剂和产物的连续分离和排放的方法和装置
公开(公告)号：US08852516B2
公开(公告)日：2014-10-07
申请号：US12919919
申请日：2008-12-08
申请人： Kwang Jae Woo , Ki-won Jun , Suk-Hwan Kang , Seung-Moon Kim , Jong-Wook Bae
发明人： Kwang Jae Woo , Ki-won Jun , Suk-Hwan Kang , Seung-Moon Kim , Jong-Wook Bae
IPC分类号： B01J8/20 , B01J8/22 , B01J4/00 , C10G2/00 , B01J8/00 , B01J8/18
CPC分类号： B01J8/22 , B01J8/006 , B01J8/1809 , B01J2208/00061 , B01J2208/0007 , B01J2208/0061 , B01J2219/002 , B01J2219/00213 , B01J2219/00236 , C10G2/342 , C10G2300/4056 , C10G2300/4081
摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.
摘要翻译：本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物进料气体的脉冲并将产物排出反应器的下部。提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部通过液位感测装置测量的合成产品的量。

7. 发明申请

US20110028574A1 Method and Apparatus for the Continuous Separation and Discharge of Solid Catalysts and Products for Fischer-Tropsch Synthesis Reactions 有权
标题翻译：用于费 - 托合成反应的固体催化剂和产物的连续分离和排放的方法和装置
公开(公告)号：US20110028574A1
公开(公告)日：2011-02-03
申请号：US12919919
申请日：2008-12-08
申请人： Kwang Jae Woo , Ki-won Jun , Suk-Hwan Kang , Seung-Moon Kim , Jong-Wook Bae
发明人： Kwang Jae Woo , Ki-won Jun , Suk-Hwan Kang , Seung-Moon Kim , Jong-Wook Bae
IPC分类号： C07C1/12 , B01J19/00
CPC分类号： B01J8/22 , B01J8/006 , B01J8/1809 , B01J2208/00061 , B01J2208/0007 , B01J2208/0061 , B01J2219/002 , B01J2219/00213 , B01J2219/00236 , C10G2/342 , C10G2300/4056 , C10G2300/4081
摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.
摘要翻译：本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物进料气体的脉冲并将产物排出反应器的下部。提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部通过液位感测装置测量的合成产品的量。

8. 发明申请

US20090104108A1 Method of Preparing Boehmite and Gamma-Alumina With High Surface Area 审中-公开
标题翻译：制备高表面积的勃姆石和γ-氧化铝的方法
公开(公告)号：US20090104108A1
公开(公告)日：2009-04-23
申请号：US11886367
申请日：2006-01-25
申请人： Ki-Won Jun , Yun-Jo Lee , Seung-Moon Kim , Jeong Yeon Kim
发明人： Ki-Won Jun , Yun-Jo Lee , Seung-Moon Kim , Jeong Yeon Kim
IPC分类号： C01F7/06
CPC分类号： C01F7/36 , B01J20/08 , B01J20/284 , B01J21/04 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/033 , C01P2002/72 , C01P2004/03 , C01P2006/12 , C01P2006/14 , C01P2006/80
摘要： The present invention relates to a method for preparing boehmite and γ-alumina with high surface area, and more particularly, to a method comprising hydrolysis of aluminum alkoxides to produce boehmite and calcination to produce γ-alumina, wherein an alcohol is used as a reaction solvent and a small amount of water and a particular organic carboxylic acid are added so that not only the reaction solvent is easily recovered and energy required for drying is significantly reduced but also it provides boehmite having nano-sized particles, high surface area, and high purity. Further, the prepared γ-alumina may be suitable for high value added industrial applications such as manufacture of adsorbents, catalysts, catalyst supports and chromatography materials.
摘要翻译：本发明涉及一种具有高表面积的勃姆石和γ-氧化铝的制备方法，更具体地涉及一种包括水解醇铝以制备勃姆石并煅烧以产生γ-氧化铝的方法，其中使用醇作为反应溶剂和少量的水和特定的有机羧酸，使得不仅反应溶剂容易回收并且干燥所需的能量显着降低，而且还提供具有纳米尺寸颗粒，高表面积和高的勃姆石纯度。此外，所制备的γ-氧化铝可适用于高附加值工业应用，例如制造吸附剂，催化剂，催化剂载体和色谱材料。

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