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    • 8. 发明授权
    • Method of producing a high-melting powder of
2,2-bis�4'-(2
    • 制备2,2-双[4' - (2“,3” - 二溴丙氧基)-3',5'-二溴苯基]丙烷的高熔点粉末的方法
    • US5710347A
    • 1998-01-20
    • US533822
    • 1995-09-26
    • Setsuo NishiboriHideaki OhnishiTsuyoshi Furukawa
    • Setsuo NishiboriHideaki OhnishiTsuyoshi Furukawa
    • C07C41/40C07C43/225C07C37/24
    • C07C41/40
    • This invention relates to a method of producing a high-melting powder of 2,2-bis�4'-(2",3"-dibromopropoxy)-3',5'-dibromophenyl!propane characterized by comprising a step of adding water to a solution of 2,2-bis�4'-(2",3"-dibromopropoxy)-3',5'-dibromophenyl!-propane in an organic solvent in the presence of a surfactant to give a water-in-oil emulsion and a step of removing the organic solvent from the emulsion in the presence of a crystal nucleus to induce crystallization to give an aqueous dispersion of 2,2-bis�4'-(2",3"-dibromopropoxy)-3',5'-dibromophenyl!propane. In accordance with this invention, crystallization is carried out in the state of an emulsion under assistance of a surfactant so that an ordinary stirrer can be used in production without resort to any special high-shear stirring equipment. Moreover, since a high-melting grade of 2,2-bis�4'-(2",3"-dibromopropoxy)-3',5'-dibromophenyl!propane is obtained as an aqueous dispersion, workability and safety in the subsequent processing are improved.
    • 本发明涉及2,2-双[4' - (2“,3” - 二溴丙氧基)-3',5'-二溴苯基]丙烷的高熔点粉末的制造方法,其特征在于, 在有机溶剂中,在表面活性剂存在下,向2,2-双[4' - (2“,3” - 二溴丙氧基)-3',5'-二溴苯基] - 丙烷的溶液中加入水,得到 油包水乳液和在晶核存在下从乳液中除去有机溶剂以诱导结晶以得到2,2-双[4' - (2“,”3“)的水分散体的步骤 - 二溴丙氧基)-3',5'-二溴苯基]丙烷。 根据本发明,在表面活性剂的辅助下,在乳液状态下进行结晶,使得普通搅拌器可以用于生产而不用任何特殊的高剪切搅拌设备。 此外,由于获得作为水分散体的2,2-双[4' - (2“,3” - 二溴丙氧基)-3',5'-二溴苯基]丙烷的高熔点等级,可加工性和安全性 后续处理得到改善。