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1. 发明授权

US08404877B2 Metal oxide coatings 有权
标题翻译：金属氧化物涂层
公开(公告)号：US08404877B2
公开(公告)日：2013-03-26
申请号：US11930991
申请日：2007-10-31
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： C08G77/06
CPC分类号： G02B1/10 , C07F7/0836 , C07F7/0874 , C07F7/0889 , C07F9/005 , C09D1/00 , C09D5/24 , G02B1/105 , G02B27/0006 , Y10T428/31663
摘要： Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14, and R15 are independently C1-C10 alkyl or phenyl; n is equal to the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
摘要翻译：式I化合物可以水解生成金属氧化物，其中M是Mg，Al，Ca，Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ga，Ge，As，Y， Nb，Mo，Tc，Ru，Rh，Pd，Cd，In，Sn，Sb，La，Hf，Ta，W，Re，Os，Ir，Pt，Hg，Tl，Pb，Bi，Ce，Pr， Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Th，U或Pu; X为O1 / 2或OR; R是烷基; R1，R2，R3，R4，R5，R6和R7独立地为H，烷氧基，C1-C10烷基，苯基或R10，R11，R12，R13，R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时，X为OR; 当q为2时，X为O1 / 2，M为V，Cr，Mn，Fe，As，Nb，Mo，Tc，Ru，Sb，Ta，W，Re，Os，Ir，Pt，Bi，Th ，U或Pu; 当q为4时，X为O1 / 2，M为Cr，Mo，W，Ru，Re，Os，U或Pu。包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物，然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。

2. 发明授权

US08624050B2 Solution process for transparent conductive oxide coatings 有权
标题翻译：透明导电氧化物涂层的溶液工艺
公开(公告)号：US08624050B2
公开(公告)日：2014-01-07
申请号：US12512152
申请日：2009-07-30
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： C07F7/0836 , C07F9/005 , C08G77/58 , C09D5/24 , C09D183/14
摘要： A process according to the present invention comprises combining in a reaction mixture at least one metal alkyl compound of formula MRx with at least one silanol compound of formula; forming a film from the reaction mixture; and treating the film with heat and moisture; wherein an amount of the at least one silanol compound present ranges from about one quarter to about three quarters of an amount required to replace all alkyl groups of the at least one metal alkyl compounds with groups derived from the at least one silanol compound; M is, independently at each occurrence, Zn, Cd, Al, Ga, In, Tl, Hg, Pb, Bi or a combination thereof; x is, independently at each occurrence, an integer equal to 2 or 3; z is 0, 1 or 2; R is, independently at each occurrence, alkyl; and R1-R5 is independently H, alkyl, or hydroxyl.
摘要翻译：根据本发明的方法包括在反应混合物中将至少一种式MRx的金属烷基化合物与至少一种式的硅烷醇化合物混合; 从反应混合物中形成膜; 并用热和水分处理薄膜; 其中存在的所述至少一种硅烷醇化合物的量为所述至少一种金属烷基化合物的所有烷基用衍生自所述至少一种硅烷醇化合物的基团所需的量的约四分之一至约四分之三; M在每次出现时独立地是Zn，Cd，Al，Ga，In，Tl，Hg，Pb，Bi或它们的组合; x在每次出现时独立地为等于2或3的整数; z为0,1或2; R在每次出现时独立地为烷基; 且R 1 -R 5独立地为H，烷基或羟基。

3. 发明申请

US20090289235A1 SOLUTION PROCESS FOR TRANSPARENT CONDUCTIVE OXIDE COATINGS 有权
标题翻译：透明导电氧化物涂层的解决方法
公开(公告)号：US20090289235A1
公开(公告)日：2009-11-26
申请号：US12512152
申请日：2009-07-30
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： H01B1/02 , B05D5/12
CPC分类号： C07F7/0836 , C07F9/005 , C08G77/58 , C09D5/24 , C09D183/14
摘要： A process according to the present invention comprises combining in a reaction mixture at least one metal alkyl compound of formula MRx with at least one silanol compound of formula; forming a film from the reaction mixture; and treating the film with heat and moisture; wherein an amount of the at least one silanol compound present ranges from about one quarter to about three quarters of an amount required to replace all alkyl groups of the at least one metal alkyl compounds with groups derived from the at least one silanol compound; M is, independently at each occurrence, Zn, Cd, Al, Ga, In, Tl, Hg, Pb, Bi or a combination thereof; x is, independently at each occurrence, an integer equal to 2 or 3; z is 0, 1 or 2; R is, independently at each occurrence, alkyl; and R1-R5 is independently H, alkyl, or hydroxyl.
摘要翻译：根据本发明的方法包括在反应混合物中将至少一种式MRx的金属烷基化合物与至少一种式的硅烷醇化合物混合; 从反应混合物中形成膜; 并用热和水分处理薄膜; 其中存在的所述至少一种硅烷醇化合物的量为所述至少一种金属烷基化合物的所有烷基用衍生自所述至少一种硅烷醇化合物的基团所需的量的约四分之一至约四分之三; M在每次出现时独立地是Zn，Cd，Al，Ga，In，Tl，Hg，Pb，Bi或它们的组合; x在每次出现时独立地为等于2或3的整数; z为0,1或2; R在每次出现时独立地为烷基; 且R 1 -R 5独立地为H，烷基或羟基。

4. 发明申请

US20080319143A1 METAL OXIDE COATINGS 有权
标题翻译：金属氧化物涂层
公开(公告)号：US20080319143A1
公开(公告)日：2008-12-25
申请号：US11930991
申请日：2007-10-31
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： C08F283/12
CPC分类号： G02B1/10 , C07F7/0836 , C07F7/0874 , C07F7/0889 , C07F9/005 , C09D1/00 , C09D5/24 , G02B1/105 , G02B27/0006 , Y10T428/31663
摘要： Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14, and R15 are independently C1-C10 alkyl or phenyl; n is equal to the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
摘要翻译：式I化合物可以水解生成金属氧化物，其中M是Mg，Al，Ca，Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ga，Ge，As，Y， Nb，Mo，Tc，Ru，Rh，Pd，Cd，In，Sn，Sb，La，Hf，Ta，W，Re，Os，Ir，Pt，Hg，Tl，Pb，Bi，Ce，Pr， Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Th，U或Pu; X为O1 / 2或OR; R是烷基; R1，R2，R3，R4，R5，R6和R7独立地为H，烷氧基，C1-C10烷基，苯基或R10，R11，R12，R13，R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时，X为OR; 当q为2时，X为O1 / 2，M为V，Cr，Mn，Fe，As，Nb，Mo，Tc，Ru，Sb，Ta，W，Re，Os，Ir，Pt，Bi，Th ，U或Pu; 当q为4时，X为O1 / 2，M为Cr，Mo，W，Ru，Re，Os，U或Pu。包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物，然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。

5. 发明授权

US07169483B2 Opto-electroactive device comprising a metallocene and method 有权
标题翻译：包含茂金属的光电活性器件和方法
公开(公告)号：US07169483B2
公开(公告)日：2007-01-30
申请号：US10822446
申请日：2004-04-12
申请人： Larry Neil Lewis , Joseph John Shiang , Aharon Yakimov , Gautam Parthasarathy , Jie Liu , Sergei Kniajanski
发明人： Larry Neil Lewis , Joseph John Shiang , Aharon Yakimov , Gautam Parthasarathy , Jie Liu , Sergei Kniajanski
IPC分类号： H05B33/14 , H01L31/00
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1007 , C09K2211/183 , H01L51/0094 , H01L51/5012 , Y10S428/917
摘要： Disclosed is an opto-electroactive device comprising a metallocene of the formula wherein M is zirconium or hafnium; X is halogen and R1–R5 are each independently hydrogen, aryl, alkyl, halogen or —Si(R6)3; or wherein at least two adjacent R substituents on at least one ring are joined to form a fused ring, which may be unsubstituted or substituted with aryl, alkyl, halogen or —Si(R6)3; or wherein the R1 substituents on each ring are joined to link the rings in an ansa bridge, and wherein R6 is an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group. Also disclosed is a method for making an opto-electroactive device comprising a metallocene.
摘要翻译：公开了一种光电活性器件，其包含下式的金属茂，其中M为锆或铪; X是卤素，R 1 -R 5各自独立地为氢，芳基，烷基，卤素或-Si（R 6） 3 或其中在至少一个环上的至少两个相邻的R取代基连接以形成稠环，其可以是未取代的或被芳基，烷基，卤素或-Si（R 6） 3 或其中每个环上的R 1取代基被连接以连接安桥中的环，并且其中R 6是烷基，取代的烷基，芳基基团或取代的芳基。还公开了一种制造包含茂金属的光电活性器件的方法。

6. 发明申请

US20050227108A1 Opto-electroactive device comprising a metallocene and method 有权
标题翻译：包含茂金属的光电活性器件和方法
公开(公告)号：US20050227108A1
公开(公告)日：2005-10-13
申请号：US10822446
申请日：2004-04-12
申请人： Larry Lewis , Joseph Shiang , Aharon Yakimov , Gautam Parthasarathy , Jie Liu , Sergei Kniajanski
发明人： Larry Lewis , Joseph Shiang , Aharon Yakimov , Gautam Parthasarathy , Jie Liu , Sergei Kniajanski
IPC分类号： H01L51/50 , C07F7/00 , C07F7/08 , C07F17/00 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/42 , H05B33/14 , H01L31/00
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1007 , C09K2211/183 , H01L51/0094 , H01L51/5012 , Y10S428/917
摘要： Disclosed is an opto-electroactive device comprising a metallocene of the formula wherein M is zirconium or hafnium; X is halogen and R1-R5 are each independently hydrogen, aryl, alkyl, halogen or —Si(R6)3; or wherein at least two adjacent R substituents on at least one ring are joined to form a fused ring, which may be unsubstituted or substituted with aryl, alkyl, halogen or —Si(R6)3; or wherein the R1 substituents on each ring are joined to link the rings in an ansa bridge, and wherein R6 is an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group. Also disclosed is a method for making an opto-electroactive device comprising a metallocene.
摘要翻译：公开了一种光电活性器件，其包含下式的金属茂，其中M为锆或铪; X是卤素，R 1 -R 5各自独立地为氢，芳基，烷基，卤素或-Si（R 6） 3 或其中在至少一个环上的至少两个相邻的R取代基连接以形成稠环，其可以是未取代的或被芳基，烷基，卤素或-Si（R 6） 3 或其中每个环上的R 1取代基被连接以连接安桥中的环，并且其中R 6是烷基，取代的烷基，芳基基团或取代的芳基。还公开了一种制造包含茂金属的光电活性器件的方法。

7. 发明授权

US07652157B2 Metal oxide coatings 有权
标题翻译：金属氧化物涂层
公开(公告)号：US07652157B2
公开(公告)日：2010-01-26
申请号：US11931039
申请日：2007-10-31
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： C07F7/26
CPC分类号： C07F7/0836 , C07F9/005
摘要： Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14 and R15 are independently C1-C10 alkyl or phenyl; n is equal to the the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
摘要翻译：式I化合物可以水解生成金属氧化物，其中M是Mg，Al，Ca，Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ga，Ge，As，Y， Nb，Mo，Tc，Ru，Rh，Pd，Cd，In，Sn，Sb，La，Hf，Ta，W，Re，Os，Ir，Pt，Hg，Tl，Pb，Bi，Ce，Pr， Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Th，U或Pu; X为O1 / 2或OR; R是烷基; R1，R2，R3，R4，R5，R6和R7独立地为H，烷氧基，C1-C10烷基，苯基或R10，R11，R12，R13，R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q值; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时，X为OR; 当q为2时，X为O1 / 2，M为V，Cr，Mn，Fe，As，Nb，Mo，Tc，Ru，Sb，Ta，W，Re，Os，Ir，Pt，Bi，Th ，U或Pu; 当q为4时，X为O1 / 2，M为Cr，Mo，W，Ru，Re，Os，U或Pu。包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物，然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。

8. 发明申请

US20080319212A1 METAL OXIDE COATINGS 有权
标题翻译：金属氧化物涂层
公开(公告)号：US20080319212A1
公开(公告)日：2008-12-25
申请号：US11931039
申请日：2007-10-31
申请人： Sergei Kniajanski , Aharon Yakimov
发明人： Sergei Kniajanski , Aharon Yakimov
IPC分类号： C07F7/02
CPC分类号： C07F7/0836 , C07F9/005
摘要： Compounds of formula I may be hydrolyzed to produce metal oxides whereinM is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu;X is O1/2 or OR;R is alkyl;R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14 and R15 are independently C1-C10 alkyl or phenyl;n is equal to the the value of the oxidation state of M minus q;m and p are independently 0 or an integer from 1 to 5; andq is 0, 1, 2, or 4;with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu. Articles comprising at least one metal oxide are fabricated by coating a substrate with at least one compounds of formula I before hydrolyzing, and/or heating the compound at a temperature ranging from about 50° C. to about 450° C.
摘要翻译：式I化合物可以水解生成金属氧化物，其中M是Mg，Al，Ca，Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ga，Ge，As，Y， Nb，Mo，Tc，Ru，Rh，Pd，Cd，In，Sn，Sb，La，Hf，Ta，W，Re，Os，Ir，Pt，Hg，Tl，Pb，Bi，Ce，Pr， Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Th，U或Pu; X为O1 / 2或OR; R是烷基; R1，R2，R3，R4，R5，R6和R7独立地为H，烷氧基，C1-C10烷基，苯基或R10，R11，R12，R13，R14和R15独立地为C1-C10烷基或苯基; n等于M的氧化态减去q值; m和p独立地为0或1至5的整数; q为0,1,2或4; 条件是当q为1时，X为OR; 当q为2时，X为O1 / 2，M为V，Cr，Mn，Fe，As，Nb，Mo，Tc，Ru，Sb，Ta，W，Re，Os，Ir，Pt，Bi，Th ，U或Pu; 当q为4时，X为O1 / 2，M为Cr，Mo，W，Ru，Re，Os，U或Pu。包含至少一种金属氧化物的制品通过在至少一种式I化合物之前涂覆底物，然后在约50℃至约450℃的温度下水解和/或加热该化合物来制备。

9. 发明授权

US09649055B2 System and methods for physiological monitoring 有权
公开(公告)号：US09649055B2
公开(公告)日：2017-05-16
申请号：US13435966
申请日：2012-03-30
申请人： Jeffrey Michael Ashe , Aharon Yakimov , Siavash Yazdanfar , Milos Todorovic
发明人： Jeffrey Michael Ashe , Aharon Yakimov , Siavash Yazdanfar , Milos Todorovic
IPC分类号： A61B5/1455 , A61B5/029 , A61B5/08 , A61B5/024
CPC分类号： A61B5/14552 , A61B5/02427 , A61B5/029 , A61B5/08
摘要： Embodiments of devices, methods, and non-transitory computer readable media for monitoring a subject are presented. The monitoring device includes at least one sensor configured to monitor one or more physiological parameters of a subject and a processing unit operatively coupled to the sensor. The sensor comprises a plurality of radiation sources and detectors disposed on a flexible substrate in a designated physical arrangement. The processing unit is configured to dynamically configure an operational geometry of the sensor by controlling the intensity of one or more of the radiation sources and the gain of one or more of the detectors so as to satisfy at least one quality metric associated with one or more physiological parameters of the subject.

10. 发明申请

US20130192667A1 PHOTOVOLTAIC DEVICES AND METHOD OF MAKING 有权
标题翻译：光伏器件及其制造方法
公开(公告)号：US20130192667A1
公开(公告)日：2013-08-01
申请号：US13362813
申请日：2012-01-31
申请人： Jinbo Cao , Bastiaan Arie Korevaar , Dalong Zhong , Juan Carlos Rojo , Qianqian Xin , Aharon Yakimov
发明人： Jinbo Cao , Bastiaan Arie Korevaar , Dalong Zhong , Juan Carlos Rojo , Qianqian Xin , Aharon Yakimov
IPC分类号： H01L31/0352 , H01L31/18
CPC分类号： H01L31/073 , H01L31/0749 , Y02E10/541 , Y02E10/543 , Y02P70/521
摘要： A photovoltaic device is presented. The photovoltaic device includes a transparent conductive layer; a window layer disposed on the transparent conductive layer; and an absorber layer disposed on the window layer. The window layer includes a low-diffusivity layer disposed adjacent to the transparent conductive layer and a high-diffusivity layer interposed between the low-diffusivity layer and the absorber layer. Method of making a photovoltaic device is also presented.
摘要翻译：介绍了光伏器件。光电器件包括透明导电层; 设置在所述透明导电层上的窗口层; 以及设置在窗口层上的吸收层。窗口层包括邻近透明导电层设置的低扩散层和介于低扩散层和吸收层之间的高扩散性层。还提出了制造光伏器件的方法。

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