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    • 10. 发明授权
    • Electrolytic capacitor having a conducting polymer layer without
containing an organic acid-type dopant
    • 具有不含有机酸型掺杂剂的导电聚合物层的电解电容器
    • US6134099A
    • 2000-10-17
    • US89264
    • 1998-06-03
    • Emiko IgakiMasakazu TanahashiChiharu Hayashi
    • Emiko IgakiMasakazu TanahashiChiharu Hayashi
    • C08G61/10C08G61/12C08G73/00H01G9/00H01G9/02H01G9/025H01G9/028H01G9/042H01G9/04
    • H01G9/042H01G11/48H01G11/56H01G9/0036H01G9/025H01G9/028H01G9/0425Y02E60/13Y10T29/417
    • An electrolytic capacitor in which an conducting polymer as a cathode of the electrolytic capacitor is formed as a homogeneous and densified film on the dielectric layer even extending to the inside of pores of a valvular metal porous body and which obtains a high rate of inducing the capacitance, and have low impedance and high responsiveness at high frequencies. A chemical oxidation polymerization method is utilized to form an conducting polymer layer even extending to the inside of pores of the capacitor element. First, a polymerization reaction is performed in a solution excluding an organic acid-type dopant to form an conducting polymer layer as a densified film on a dielectric layer extending from the surface of the porous body to every inside portions of pores in the pretreatment. Then a polymerization reaction is performed in a solution containing an organic acid-type dopant to grow an conducting polymer layer containing an organic acid-type dopant over the conducting polymer layer without including an organic acid-type dopant in the primary treatment.
    • 一种电解电容器,其中作为电解电容器的阴极的导电聚合物在电介质层上形成为均匀且致密的膜,甚至延伸到阀瓣金属多孔体的孔的内部,并且获得高的电容率 并且在高频下具有低阻抗和高响应性。 使用化学氧化聚合法形成甚至延伸到电容器元件的孔的内部的导电聚合物层。 首先,在除了有机酸型掺杂剂之外的溶液中进行聚合反应,以在预处理中从多孔体的表面延伸到孔的每个内部的电介质层上形成作为致密化膜的导电聚合物层。 然后在包含有机酸型掺杂剂的溶液中进行聚合反应,以在一次处理中在不包含有机酸型掺杂剂的情况下,在导电聚合物层上生长含有有机酸型掺杂剂的导电聚合物层。