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    • 4. 发明授权
    • Process for preparing developer materials for electrostatic images
    • 制备静电图像显影剂材料的方法
    • US4455361A
    • 1984-06-19
    • US232805
    • 1981-02-09
    • Toshiaki NarusawaSeiji OkadaKiyohide MuramatsuTeruo YagishitaHirofumi Okuyama
    • Toshiaki NarusawaSeiji OkadaKiyohide MuramatsuTeruo YagishitaHirofumi Okuyama
    • G03G9/087G03G9/09G03G9/097G03G9/113G03G9/10G03G11/00
    • G03G9/08753G03G9/08708G03G9/08711G03G9/08768G03G9/0904G03G9/0914G03G9/097G03G9/09741G03G9/1133Y10S430/105
    • A process for preparing a developer material for electrostatic images comprising a mixture of (1) a coated carrier and (2) a toner by a rotary drying method.(a) The carrier consists of core beads coated with a coating resin comprising a butadiene homopolymer of a molecular weight of from 10,000 to 100,000, for the butadiene homopolymer is linear 1,2-polybutadiene and/or cyclized as-1,4-polybutadiene or a mixture of at least one these homopolymers and a styrene/butadiene copolymer of a molecular weight of from 10,000 to 100,000, the mixture containing from 7.5 to 100% by weight, based on the weight of the mixture, of butadiene in polymerized form.(2) The toner comprises, based on the weight of the toner, (A) from 85 to 95% by weight of a binder resin comprising, based on the weight of the binder resin, from 50 to 100% by weight of an epoxy resin of a molecular weight of from 900 to 8,000 and from 0 to 50% by weight of a styrene/alkyl methacrylate copolymer, the alkyl group having from 1 to 4 carbon atoms, of a molecular weight of from 10,000 to 100,000; (B) a colorant comprising, based on the weight of the toner, from 0 to 10% by weight of fine carbon and from about 0.5 to 8% by weight of a nigrosine dye, and; (C) from 0 to 8% by weight of a charge controlling agent, based on the weight of the toner, comprising a quaternary ammonium alkyl sulfonate, the alkyl group having from 4 to 20 carbon atoms, or di-(p-hydroxy ethoxy ethyl)octadecyl amine or a polyamine.The ratio of the total surface area of the coated carrier to the total projection area of the toner particles is in the range of from 1:0.5 to 1:2.0.
    • 一种制备用于静电图像的显影剂材料的方法,包括(1)涂覆载体和(2)通过旋转干燥方法的调色剂的混合物。 (a)载体由涂覆有包含分子量为10,000至100,000的丁二烯均聚物的涂层树脂的芯珠组成,丁二烯均聚物为线性1,2-聚丁二烯和/或环化的1,4-聚丁二烯 或至少一种这些均聚物和分子量为10,000至100,000的苯乙烯/丁二烯共聚物的混合物,该混合物含有基于混合物重量的7.5至100重量%的聚合形式的丁二烯。 (2)调色剂基于调色剂的重量,包含(A)85至95重量%的粘合剂树脂,其包含基于粘合剂树脂的重量的50至100重量%的环氧树脂 树脂,分子量为900至8,000和0至50重量%的苯乙烯/甲基丙烯酸烷基酯共聚物,具有1至4个碳原子的烷基,分子量为10,000至100,000; (B)着色剂,其包含基于调色剂重量的0至10重量%的细碳和约0.5至8重量%的苯胺黑染料,和 (C)0至8重量%的电荷控制剂,基于调色剂的重量,其包含季铵烷基磺酸盐,具有4至20个碳原子的烷基或二(对羟基乙氧基) 乙基)十八烷基胺或多胺。 涂覆载体的总表面积与调色剂颗粒的总投影面积的比率在1:0.5至1:2.0的范围内。
    • 5. 发明授权
    • Developer materials for electrostatic images
    • 静电图像显影材料
    • US4513075A
    • 1985-04-23
    • US320609
    • 1981-11-12
    • Toshiaki NarusawaSeiji OkadaKiyohide MuramatsuTeruo YagishitaHirofumi Okuyama
    • Toshiaki NarusawaSeiji OkadaKiyohide MuramatsuTeruo YagishitaHirofumi Okuyama
    • G03G9/087G03G9/09G03G9/097G03G9/113G03G9/10
    • G03G9/08753G03G9/08708G03G9/08711G03G9/08768G03G9/0904G03G9/0914G03G9/097G03G9/09741G03G9/1133Y10S430/105
    • A developer material for electrostatic images comprising a mixture of (1) a coated carrier and (2) a toner.(1) The carrier consists of core beads coated with a coating resin comprising a butadiene homopolymer of a molecular weight of from 10,000 to 100,000, for the butadiene homopolymer is 1,2-polybutadiene and/or cyclized cis-1,4-polybutadiene or a mixture of at least one of these homopolymers and a styrene/butadiene copolymer of a molecular weight of from 10,000 to 100,000, the mixture containing from 7.5 to 100% by weight, based on the weight of the mixture, of butadiene in polymerized form.(2) The toner comprises, based on the weight of the toner, (A) from 85 to 95% by weight of a binder resin comprising, based on the weight of the binder resin, from 50 to 100% by weight of an epoxy resin of a molecular weight of from 900 to 8,000 and from 0 to 50% by weight of a styrene/alkyl methacrylate copolymer, the alkyl group having from 1 to 4 carbon atoms, of a molecular weight of from 10,000 to 100,000; (B) a colorant comprising, based on the weight of the toner, from 0 to 10% by weight of fine carbon and from 0.5 to 8% by weight of a nigrosine dye, and; (C) from 0 to 8% by weight of a charge controlling agent, based on the weight of the toner, comprising a quaternary ammonium alkyl sulfonate, the alkyl group having from 4 to 20 carbon atoms, or di-(polyhydroxyethoxy ethyl) octadecyl amine, or a polyamine.The ratio of the total surface area of the coated carrier to the total projection area of the toner particles is in the range of from 1:0.5 to 1:2.0.
    • 一种用于静电图像的显影剂材料,其包含(1)涂覆载体和(2)调色剂的混合物。 (1)载体由涂布有包含分子量为10,000至100,000的丁二烯均聚物的涂层树脂的芯珠粒组成,丁二烯均聚物为1,2-聚丁二烯和/或环化顺式-1,4-聚丁二烯或 这些均聚物中的至少一种和分子量为10,000至100,000的苯乙烯/丁二烯共聚物的混合物,基于混合物重量的7.5至100重量%的混合物的聚合形式的丁二烯的混合物。 (2)调色剂基于调色剂的重量,包含(A)85至95重量%的粘合剂树脂,其包含基于粘合剂树脂的重量的50至100重量%的环氧树脂 树脂,分子量为900至8,000和0至50重量%的苯乙烯/甲基丙烯酸烷基酯共聚物,具有1至4个碳原子的烷基,分子量为10,000至100,000; (B)着色剂,其包含基于调色剂重量的0至10重量%的细碳和0.5至8重量%的苯胺黑染料,和 (C)0至8重量%的电荷控制剂,基于调色剂的重量,其包含季铵烷基磺酸盐,具有4至20个碳原子的烷基或二(多羟基乙氧基乙基)十八烷基 胺或多胺。 涂覆载体的总表面积与调色剂颗粒的总投影面积的比率在1:0.5至1:2.0的范围内。