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    • 1. 发明申请
    • SEMICONDUCTOR DEVICE MANUFACTURING METHOD
    • 半导体器件制造方法
    • US20100203704A1
    • 2010-08-12
    • US12704315
    • 2010-02-11
    • Seiji INUMIYATomonori Aoyama
    • Seiji INUMIYATomonori Aoyama
    • H01L21/762H01L21/28
    • H01L21/28167H01L21/02057H01L21/28088H01L21/28194H01L21/28202H01L21/7624H01L21/823857H01L29/4966H01L29/513H01L29/517H01L29/518H01L29/66795H01L29/785
    • A semiconductor device manufacturing method includes: removing an insulating film on a semiconductor substrate by etching and subsequently oxidizing a surface of the semiconductor substrate by using a liquid oxidation agent without exposing this surface to an atmosphere, thereby forming a first insulating film containing an oxide of a constituent element of the semiconductor substrate on the surface of the semiconductor substrate; forming a second insulating film containing an aluminum oxide on the first insulating film; forming a third insulating film containing a rare earth oxide on the second insulating film; forming a high-k insulating film on the third insulating film; introducing nitrogen into the high-k insulating film to thereby make it a fourth insulating film; and conducting heat treatment to change the first through third insulating films into a insulating film made of a mixture containing aluminum, a rare earth element, the constituent element of the semiconductor substrate, and oxygen.
    • 半导体器件制造方法包括:通过使用液体氧化剂蚀刻并随后氧化半导体衬底的表面而在半导体衬底上去除绝缘膜而不将该表面暴露在大气中,从而形成含有氧化物的第一绝缘膜 半导体衬底的表面上的构成元件; 在所述第一绝缘膜上形成含有氧化铝的第二绝缘膜; 在所述第二绝缘膜上形成含有稀土类氧化物的第三绝缘膜; 在第三绝缘膜上形成高k绝缘膜; 将氮引入高k绝缘膜,从而使其成为第四绝缘膜; 并且进行热处理以将第一至第三绝缘膜改变为由含有铝,稀土元素,半导体衬底的构成元素和氧的混合物制成的绝缘膜。
    • 2. 发明申请
    • SEMICONDUCTOR DEVICE AND METHOD FOR MANUFACTURING SAME
    • 半导体器件及其制造方法
    • US20100133623A1
    • 2010-06-03
    • US12626216
    • 2009-11-25
    • Seiji INUMIYATomonori Aoyama
    • Seiji INUMIYATomonori Aoyama
    • H01L27/092H01L21/8238
    • H01L21/823857H01L29/513H01L29/517
    • A silicon oxynitride film is formed on entire surface of a semiconductor substrate, a lanthanum oxide film is formed on the silicon oxynitride film and the lanthanum oxide film is removed from a pMOS region. Then, a nitrided hafnium silicate film serving as a highly dielectric film is formed on the entire surface, an aluminum-containing titanium nitride film is formed, a polysilicon film is formed, and the stacked films are patterned into a gate electrode configuration. Next, impurities are introduced into a source/drain region, and an annealing for activating the impurities is utilized to diffuse the aluminum included in the aluminum-containing titanium nitride film to the interface between the silicon oxynitride film and the nitrided hafnium aluminum silicate film in the pMOS region.
    • 在半导体衬底的整个表面上形成氧氮化硅膜,在氧氮化硅膜上形成氧化镧膜,并从pMOS区域除去氧化镧膜。 然后,在整个表面上形成用作高电介质膜的氮化铪硅酸盐膜,形成含铝的氮化钛膜,形成多晶硅膜,并将层叠的膜图案化为栅电极构造。 接下来,将杂质引入源极/漏极区域,并且利用用于激活杂质的退火将包含在含铝氮化钛膜中的铝扩散到氮氧化硅膜和氮化铪硅酸铝膜之间的界面 pMOS区域。