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    • 1. 发明授权
    • Liquid developer for electrostatic photography
    • 静电摄影用液体显影剂
    • US5344694A
    • 1994-09-06
    • US885353
    • 1992-05-19
    • Seiji HorieKenji SanoNobuo SuzukiSyu Watarai
    • Seiji HorieKenji SanoNobuo SuzukiSyu Watarai
    • G03G5/05G03G9/13B32B9/00
    • G03G5/0521G03G9/131G03G9/133Y10T428/24802
    • A liquid developer for electrostatic photography, said liquid developer comprising resin particles dispersed in a non-aqueous solvent having a volume resistivity of at least 10.sup.9 .OMEGA.cm, said dispersed resin particles being obtained by polymerizing(a) at least one member of methyl methacrylate and ethyl methacrylate soluble in said non-aqueous solvent and(b) at least one member selected from the group consisting of acrylic esters and methacrylic esters having an alkyl group having not more than 4 carbon atoms, said esters being soluble in said non-aqueous solvent, but being made insoluble by polymerization,said components (a) and (b) being polymerized in the presence of a dispersion stabilizing resin which is soluble in said non-aqueous solvent, and said dispersion stabilizing resin comprising a graft copolymer formed by polymerizing(i) at least one member of macromonomers (M) having a weight-average molecular weight of 1.times.10.sup.3 to 4.times.10.sup.4, said macromonomers (M) having a polymerizable double bond containing group represented by the formula (I) defined in the specification bonded to one terminal of the main polymer chain, said macromonomers (M) containing at least one member of polymer components represented by formula (II) defined in the specification in the main chain thereof, and(ii) at least one member of monomers represented by formula (III) as defined in the specification,said monomers (a) and (b) being made insoluble by polymerization.
    • 一种用于静电摄影的液体显影剂,所述液体显影剂包括分散在体积电阻率为至少10 9欧米亚厘米的非水溶剂中的树脂颗粒,所述分散的树脂颗粒通过聚合(a)至少一种甲基丙烯酸甲酯和 可溶于所述非水溶剂的甲基丙烯酸乙酯和(b)选自具有不超过4个碳原子的烷基的丙烯酸酯和甲基丙烯酸酯的至少一种,所述酯可溶于所述非水溶剂 但是通过聚合使其不溶,所述组分(a)和(b)在可溶于所述非水溶剂的分散体稳定树脂的存在下聚合,所述分散体稳定树脂包含通过聚合形成的接枝共聚物 i)至少一种重均分子量为1×10 3至4×10 4的大分子单体(M)的成员,所述大分子单体(M)具有可聚合的 所述大分子单体(M)含有在本说明书中定义的至少一种由式(II)表示的聚合物组分的组分中的至少一种聚合物组分, 其主链,和(ii)说明书中定义的至少一种由式(III)表示的单体,所述单体(a)和(b)通过聚合而不溶解。
    • 2. 发明授权
    • Electrophotographic photoreceptor and electrophotographic printing plate
precursor comprising phthalocyanine pigment and thiobarbituric acid
derivative
    • 电子显微照相机和电泳印刷机前体包含羟基苯甲酸颜料和硫代酸衍生物
    • US5102760A
    • 1992-04-07
    • US584027
    • 1990-09-18
    • Hiroaki YokoyaHiromichi TachikawaSyu WataraiSyunichi KondoSeiji Horie
    • Hiroaki YokoyaHiromichi TachikawaSyu WataraiSyunichi KondoSeiji Horie
    • C07D239/60C07D405/06C07D409/06G03G5/06
    • C07D405/06C07D239/60C07D409/06G03G5/0638G03G5/0661G03G5/0696
    • A novel electrophotographic photoreceptor for copiers or photoprinters is provided comprising a photoconducting layer provided on an electrically conductive support, wherein said photoconducting layer comprises a phthalocyanine pigment and at least one compound represented by the general formula (I) or (II): ##STR1## wherein Z represents a sulfur atom or oxygen atom; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, alkyl group, aryl group or aralkyl group; A represents an alkyl group, aryl group, aralkyl group or monovalent heterocyclic group; and B represents an alkylene group, arylene group, polymethylene group or aralkylene group.A novel electrophotographic printing plate precursor is also provided which comprises a photoconducting layer containing at least a photoconducting pigment and a binder resin on an electrically conductive support and is adapted to form a printing plate in an electrophotographic process comprising forming a toner image, and then removing said photoconducting layer from the non-image portions except said toner image portions, characterized in that said photoconducting pigment is a phthalocyanine pigment and said photoconducting layer further comprises a compound represented by the general formula [I] or [II]: ##STR2## wherein Z represents a sulfur atom or oxygen atom; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, alkyl group, aryl group or aralkyl group; A represents an alkyl group, aryl group, aralkyl group or monovalent heterocyclic group; and B represents an alkylene group, arylene group, polymethylene group or aralkylene group.
    • 提供了一种用于复印机或照相印刷机的新型电子照相感光体,其包括设置在导电载体上的光导层,其中所述光导层包含酞菁颜料和至少一种由通式(I)或(II)表示的化合物: (I)其中Z表示硫原子或氧原子; R1和R2可以相同或不同,各自表示氢原子,烷基,芳基或芳烷基; A表示烷基,芳基,芳烷基或1价杂环基; B表示亚烷基,亚芳基,多亚甲基或亚芳烷基。 还提供了一种新颖的电子照相印版前体,其包括在导电载体上至少含有光导颜料和粘合剂树脂的光导层,并且适于在电子照相方法中形成印版,包括形成调色剂图像,然后除去 所述光导体层除了所述调色剂图像部分之外的非图像部分,其特征在于所述光导颜料是酞菁颜料,并且所述光导层还包含由通式[I]或[II]表示的化合物:( I)其中Z表示硫原子或氧原子;(II)其中Z表示硫原子或氧原子; R1和R2可以相同或不同,各自表示氢原子,烷基,芳基或芳烷基; A表示烷基,芳基,芳烷基或1价杂环基; B表示亚烷基,亚芳基,多亚甲基或亚芳烷基。
    • 5. 发明授权
    • Electrophotographic printing plate precursor
    • 电子照相印版前体
    • US5063129A
    • 1991-11-05
    • US449161
    • 1989-12-13
    • Hiroaki YokoyaHiromichi TachikawaSyu Watarai
    • Hiroaki YokoyaHiromichi TachikawaSyu Watarai
    • G03G5/06
    • G03G5/0618G03G5/062G03G5/0638G03G5/0661
    • A electrophotographic printing plate precursor comprising an electrically-conductive support having thereon a photoconductive layer containing at least photoconductive pigments and a binder resin, wherein said photoconductive pigments are phthalocyanine pigments and said photoconductive layer further comprises a compound represented by the general formula (I), (II) or (III): ##STR1## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R.sub.3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R.sub.3 may together form a ring; and R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group, aryl group or aralkyl group, with the proviso that the aromatic hydrocarbon group and heterocyclic group represented by Ar and the alkyl, aryl and aralkyl group represented by R.sub.1, R.sub.2 and R.sub.3 may be further substituted by substituents, ##STR2## wherein Z represents a sulfur or oxygen atom; R.sub.4 to R.sub.9, which may be the same or different, each represents a hydrogen atom, alkyl group, aryl group or monovalent group derived from heterocyclic group; R.sub.4 and R.sub.5 or R.sub.6 and R.sub.7 may be connected to each other; R.sub.4 to R.sub.7 may be connected to each other to form a crosslinkable ring as a whole in the general formula (II); and R.sub.10 represents a divalent arylene, aralkylene, polymethylene or alkylene group.
    • 一种电子照相平版印刷版原版,其特征在于,具有导电性支持体,其上具有至少含有光电导性颜料的光电导层和粘合剂树脂,其中,所述感光颜料为酞菁颜料,所述感光层还含有通式(I)表示的化合物, (II)或(III):其中Z表示硫或氧原子; Ar表示一价芳香族烃基或1价杂环基; R3表示氢原子,烷基,芳基或芳烷基; Ar和R3可以一起形成环; 并且可以相同或不同的R 1和R 2各自表示烷基,芳基或芳烷基,条件是由Ar表示的芳族烃基和杂环基以及由R 1表示的烷基,芳基和芳烷基 (II)其中Z表示硫或氧原子; R 3和R 3可以进一步被取代基取代。 R 4〜R 9可以相同或不同,表示氢原子,烷基,芳基或衍生自杂环基的一价基团; R4和R5或R6和R7可以彼此连接; R4至R7可以彼此连接,从而在通式(II)中整体形成可交联的环; R 10表示二价亚芳基,亚芳基,多亚甲基或亚烷基。
    • 8. 发明授权
    • Electrophotographic printing plate precursor
    • 电子照相印版前体
    • US5426012A
    • 1995-06-20
    • US466905
    • 1990-01-18
    • Hiroaki YokoyaHiromichi TachikawaSyu Watarai
    • Hiroaki YokoyaHiromichi TachikawaSyu Watarai
    • C09B47/04G03G5/05G03G5/06G03G5/09G03G13/26G03G13/28G03G15/09
    • G03G5/0521G03G5/0514G03G5/0517G03G5/0696G03G13/28
    • An electrophotographic printing plate precursor is disclosed, which comprises an electrically conductive support having thereon a photoconductive layer containing a photoconductive pigment and binder resin which is designated to undergo an electrophotographic process wherein a toner image is formed and the photoconductive layer in the non-image portion other than the toner image portion is then removed to form a printing plate, wherein said photoconductive pigment is a phthalocyanine pigment and said photoconductive layer further comprises at least one compound selected from the compounds represented by the formulae (I), (II) and (III): ##STR1## wherein Z represents a sulfur atom or an oxygen atom, R.sup.1 represents an alkyl group, an alkoxy group, a single ring or double condensed ring aryl group, a single ring or a double condensed ring aryloxy group, or a univalent group derived from a heterocyclic ring, and the two R.sup.1 groups in general formula (III) may be the same or different;R.sup.2 and R.sup.3 each represent a hydrogen atom, an alkyl group, a single ring or double condensed ring aryl group, or a univalent group derived from a heterocyclic ring, and R.sup.2 and R.sup.3 may be the same or different;R.sup.4 represents a methylene group, a polymethylene group, a branched alkanediyl group or an arylene group, and R.sup.1 and R.sup.2, or R.sup.2 and R.sup.3 may be bonded together.
    • 公开了一种电子照相印版前体,其包括导电载体,其上具有含有光电导颜料和粘合剂树脂的光电导层,其被指定经历电子照相方法,其中形成调色剂图像,并且非图像部分中的光电导层 然后除去调色剂图像部分以形成印版,其中所述光导颜料是酞菁颜料,并且所述光电导层还包含选自由式(I),(II)和(II)表示的化合物中的至少一种化合物, (III)其中Z表示硫原子或氧原子,R1表示烷基,烷氧基,单环或双稠环芳基 基团,单环或双稠环芳氧基或衍生自杂环的一价基团,通式(III)中的两个R 1基团可以是 相同或不同; R2和R3各自表示氢原子,烷基,单环或双稠环芳基或衍生自杂环的一价基团,R2和R3可以相同或不同; R4表示亚甲基,多亚甲基,支链烷二基或亚芳基,R 1和R 2,或R 2和R 3可以结合在一起。