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    • 1. 发明授权
    • Method for purification of silicon tetrachloride
    • 纯化四氯化硅的方法
    • US08273316B2
    • 2012-09-25
    • US13059961
    • 2009-08-19
    • Satoshi HayashidaHarumichi Semoto
    • Satoshi HayashidaHarumichi Semoto
    • C01B33/107
    • C01B33/10778C01B33/10784
    • An object of the present invention is to provide a method for purification of silicon tetrachloride which solves the problems of separating and removing organic chlorosilanes by distillation or adsorption.The method for purification of silicon tetrachloride comprises the steps of (1) bringing a mixed gas including a silicon tetrachloride gas and an oxygen-containing gas into contact with a catalyst layer which is controlled to a temperature of 200 to 450° C. and which includes at least one selected from the group consisting of activated carbon and metal-supporting activated carbon, and (2) cooling the mixed gas after brought into contact to separate and recover liquid silicon tetrachloride.
    • 本发明的目的是提供四氯化硅的净化方法,其解决了通过蒸馏或吸附分离除去有机氯硅烷的问题。 四氯化硅的净化方法包括以下步骤:(1)使包含四氯化硅气体和含氧气体的混合气体与控制在200-450℃的催化剂层接触,并且其中 包括选自活性炭和金属负载活性炭中的至少一种,和(2)在接触后冷却混合气体以分离和回收液体四氯化硅。
    • 3. 发明授权
    • Apparatus for producing solid product
    • 用于生产固体产品的装置
    • US08657956B2
    • 2014-02-25
    • US12471236
    • 2009-05-22
    • Shuuichi HondaToru TanakaSatoshi Hayashida
    • Shuuichi HondaToru TanakaSatoshi Hayashida
    • C30B25/14B01J19/00C01B33/02
    • C01B33/027C01G9/04C01P2006/80
    • Provided is a production method and a production apparatus using a method for producing a solid product by a reaction of gaseous raw materials with a plurality of components including a step of conducting the reaction using a reactor disposed in a vertical direction; a step of feeding the gaseous raw materials with a plurality of components from the upper part of the reactor; a step of, in the lower part of the reactor, forming a seal gas layer composed of a gas having a high density and fed continuously from the lower part of the reactor; a step of discharging an exhaust gas containing a by-product gas generated by the reaction and unreacted gaseous raw materials from somewhere in the upper part of the formed seal gas layer; and a step of accommodating a solid product in the seal gas layer of the lower part.
    • 本发明提供一种使用气态原料与多种成分的反应生成固体成分的方法的制造方法和制造装置,其包括使用在垂直方向设置的反应器进行反应的工序; 从反应器的上部向气态原料供给多个组分的步骤; 在反应器的下部,形成由高密度气体构成的密封气体层,并从反应器的下部连续进料的工序; 从形成的密封气体层的上部的某处排出含有由反应产生的副产物气体和未反应的气态原料的排气的步骤; 以及在下部的密封气体层中容纳固体产物的步骤。
    • 4. 发明申请
    • METHOD AND APPARATUS FOR PRODUCING SOLID PRODUCT
    • 生产固体产品的方法和装置
    • US20090246102A1
    • 2009-10-01
    • US12471236
    • 2009-05-22
    • Shuuichi HondaToru TanakaSatoshi Hayashida
    • Shuuichi HondaToru TanakaSatoshi Hayashida
    • B01J19/00B01J10/02
    • C01B33/027C01G9/04C01P2006/80
    • Provided is a production method and a production apparatus using a method for producing a solid product by a reaction of gaseous raw materials with a plurality of components including a step of conducting the reaction using a reactor disposed in a vertical direction; a step of feeding the gaseous raw materials with a plurality of components from the upper part of the reactor; a step of, in the lower part of the reactor, forming a seal gas layer composed of a gas having a high density and fed continuously from the lower part of the reactor; a step of discharging an exhaust gas containing a by-product gas generated by the reaction and unreacted gaseous raw materials from somewhere in the upper part of the formed seal gas layer; and a step of accommodating a solid product in the seal gas layer of the lower part.
    • 本发明提供一种使用气态原料与多种成分的反应生成固体成分的方法的制造方法和制造装置,其包括使用在垂直方向设置的反应器进行反应的工序; 从反应器的上部向气态原料供给多个组分的步骤; 在反应器的下部,形成由高密度气体构成的密封气体层,并从反应器的下部连续进料的工序; 从形成的密封气体层的上部的某处排出含有由反应产生的副产物气体和未反应的气态原料的排气的步骤; 以及在下部的密封气体层中容纳固体产物的步骤。
    • 5. 发明申请
    • HIGH PURITY CRYSTALLINE SILICON, HIGH PURITY SILICON TETRACHLORIDE AND PROCESSES FOR PRODUCING THE SAME
    • 高纯度结晶硅,高纯度硅酮四氯乙烯及其制造方法
    • US20110158885A1
    • 2011-06-30
    • US13060669
    • 2009-09-04
    • Satoshi HayashidaWataru Kato
    • Satoshi HayashidaWataru Kato
    • C01B33/02C01B33/033C01B33/107
    • C01B33/033C01B33/1071C30B29/06
    • An object of the present invention is to provide more inexpensive high purity crystalline silicon which can satisfy not only a quality required to a raw material of silicon for a solar cell but also a part of a quality required to silicon for an up-to-date semiconductor and a production process for the same and provide high purity silicon tetrachloride used for production of high purity crystalline silicon and a production process for the same. The high purity crystalline silicon of the present invention has a boron content of 0.015 ppmw or less and a zinc content of 50 to 1000 ppbw. The production process for high purity crystalline silicon according to the present invention is characterized by that a silicon tetrachloride gas and a zinc gas are supplied to a vertical reactor to react them at 800 to 1200° C., whereby crude crystalline silicon is formed at a chip part of a silicon tetrachloride gas-supplying nozzle, and the crude crystalline silicon is grown downward from the chip part of the silicon tetrachloride gas-supplying nozzle; the grown crude crystalline silicon is discharged to an outside of the reactor, and the discharged crude crystalline silicon is subjected to acid treatment.
    • 本发明的目的是提供更便宜的高纯度晶体硅,其不仅可以满足用于太阳能电池的硅原料所需的质量,而且可以满足硅所需的最新的一部分质量 半导体及其制造方法相同,并提供用于生产高纯度晶体硅的高纯度四氯化硅及其制备方法。 本发明的高纯度结晶硅的硼含量为0.015ppmw以下,锌含量为50〜1000ppbw。 根据本发明的高纯度晶体硅的制造方法的特征在于,将四氯化硅气体和锌气体供给至立式反应器,使其在800〜1200℃下反应,由此在 四氯化硅气体供给喷嘴的芯片部分,并且粗晶体硅从四氯化硅气体供应喷嘴的芯片部分向下生长; 将生长的粗晶硅排放到反应器外部,并将排出的粗结晶硅进行酸处理。
    • 6. 发明授权
    • High purity crystalline silicon, high purity silicon tetrachloride for processes for producing the same
    • 高纯度晶体硅,高纯度四氯化硅用于生产相同的方法
    • US08658118B2
    • 2014-02-25
    • US13060669
    • 2009-09-04
    • Satoshi HayashidaWataru Kato
    • Satoshi HayashidaWataru Kato
    • C01B33/08
    • C01B33/033C01B33/1071C30B29/06
    • An object of the present invention is to provide more inexpensive high purity crystalline silicon which can satisfy not only a quality required to a raw material of silicon for a solar cell but also a part of a quality required to silicon for an up-to-date semiconductor and a production process for the same and provide high purity silicon tetrachloride used for production of high purity crystalline silicon and a production process for the same. The high purity crystalline silicon of the present invention has a boron content of 0.015 ppmw or less and a zinc content of 50 to 1000 ppbw. The production process for high purity crystalline silicon according to the present invention is characterized by that a silicon tetrachloride gas and a zinc gas are supplied to a vertical reactor to react them at 800 to 1200° C., whereby crude crystalline silicon is formed at a chip part of a silicon tetrachloride gas-supplying nozzle, and the crude crystalline silicon is grown downward from the chip part of the silicon tetrachloride gas-supplying nozzle; the grown crude crystalline silicon is discharged to an outside of the reactor, and the discharged crude crystalline silicon is subjected to acid treatment.
    • 本发明的目的是提供更便宜的高纯度晶体硅,其不仅可以满足用于太阳能电池的硅原料所需的质量,而且可以满足硅所需的最新的一部分质量 半导体及其制造方法相同,并提供用于生产高纯度晶体硅的高纯度四氯化硅及其制备方法。 本发明的高纯度结晶硅的硼含量为0.015ppmw以下,锌含量为50〜1000ppbw。 根据本发明的高纯度晶体硅的制造方法的特征在于,将四氯化硅气体和锌气体供给至立式反应器,使其在800〜1200℃下反应,由此在 四氯化硅气体供给喷嘴的芯片部分,并且粗晶体硅从四氯化硅气体供应喷嘴的芯片部分向下生长; 将生长的粗晶硅排放到反应器外部,并将排出的粗结晶硅进行酸处理。
    • 10. 发明授权
    • Method for producing polycrystalline silicon
    • 多晶硅的制造方法
    • US07815884B2
    • 2010-10-19
    • US12051536
    • 2008-03-19
    • Satoshi Hayashida
    • Satoshi Hayashida
    • C01B33/03C01B9/02C01B33/033
    • C01B33/033
    • To provide a method for producing polycrystalline silicon at relatively low cost, wherein the amount of waste generated is reduced by decreasing the amount of waste generated in producing polycrystalline silicon from silicon chloride by a method of reduction and increasing the amount of reused auxiliary raw materials. In the production of polycrystalline silicon using a gas phase reaction of a silicon chloride gas and a reducing agent gas, a chlorine gas is blown into an exhaust gas discharged from a reaction device to initiate a reaction, an unreacted reducing agent and silicon particles contained in the exhaust gas are chlorinated, and then a reducing agent chloride contained in the exhaust gas is separated from the other impurities and recovered.
    • 为了提供以较低成本制造多晶硅的方法,通过减少和增加再利用的辅助原料的量,通过减少由氯化硅制造多晶硅而产生的废物的量,从而降低产生的废物的量。 在使用氯化硅气体和还原剂气体的气相反应生产多晶硅时,将氯气吹入从反应装置排出的排气中以引发反应,未反应的还原剂和包含在其中的硅颗粒 排气被氯化,然后将废气中所含的还原剂氯化物与其它杂质分离并回收。