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    • 1. 发明授权
    • Solid acid catalyst containing tin and method for preparation thereof
    • 含锡的固体酸催化剂及其制备方法
    • US07442668B2
    • 2008-10-28
    • US10550716
    • 2004-04-21
    • Satoshi Furuta
    • Satoshi Furuta
    • B01J27/02C01G17/02C01G19/02C01G21/02
    • B01J27/053B01J23/14
    • An object is to provide a sulfated tin oxide catalyst with strong catalytic activity, and a method for preparation thereof. It was discovered that in the preparation of a solid acid catalyst containing tin, stronger solid acid properties than before could be achieved by preparing a support comprising a crystalline tin oxide, preferably metastannic acid, bringing this support into contact with organic acid ions, then bringing it into contact with a sulfate group-containing compound, and then calcining it. The solid acid catalyst of the present invention has a tin content of 30% or more by weight as metal in the catalyst, a sulfate group supported thereon and an argon adsorption heat of more than 30 kJ/mol, and is used in acid-catalytic reactions.
    • 目的是提供具有强催化活性的硫酸化氧化锡催化剂及其制备方法。 已经发现,在制备含锡的固体酸催化剂时,可以通过制备包含结晶锡氧化物(优选偏亚氨酸)的载体来实现比以前更强的固体酸性质,使得该载体与有机酸离子接触,然后将 与含硫酸基的化合物接触,然后煅烧。 本发明的固体酸催化剂的锡含量为催化剂中的金属的30重量%以上,负载硫酸盐基,锡吸附热为30kJ / mol以上,并用于酸催化 反应。
    • 2. 发明授权
    • Water shower apparatus
    • 水淋浴设备
    • US06920654B2
    • 2005-07-26
    • US09894704
    • 2001-06-28
    • Masao NoguchiAkihiko NakashimaShigeru ShiraiMasaaki KawaguriSatoshi Furuta
    • Masao NoguchiAkihiko NakashimaShigeru ShiraiMasaaki KawaguriSatoshi Furuta
    • A47K3/28A61H33/00B05B1/18E03C1/04
    • E03C1/0408A47K3/28
    • The water shower apparatus according to the present invention is constructed in a way to produce cold air intercepting screen having warming effects around the bather. In this water shower apparatus, the shower sprayed from the wide-angle spray nozzle of the shower system forms a shower curtain. That water shower of thin cold air intercepting screen is sprayed toward about the neck and the shoulders to the flanks of the bather. And, the shower curtain formed this way wraps about the horizontal face under the neck of the bather, the vertical face about in the vertical direction on the left and the right sides of the bather's body, and the front face centering on the lower half portion of the bather's body. This enables to intercept cold air from outside and enclose the hot air inside. Production of “cold feeling” at the time of entry of the bather into the chilled bathroom can be prevented. The entire body of the bather can be warmed with bathing.
    • 根据本发明的水淋浴装置构造成产生具有围绕着沐浴者的变暖效果的冷风拦截屏。 在该淋浴装置中,从淋浴系统的广角喷嘴喷出的淋浴器形成淋浴帘。 将冷水冷空气屏幕的水淋浴朝向脖子和肩膀喷洒到沐浴者的侧面。 而且,以这种方式形成的浴帘围绕着沐浴者的颈部下方的水平面,垂直面围绕着泳客的身体的左侧和右侧沿垂直方向,并且正面以下半部分为中心 的沐浴者的身体。 这样可以从外部拦截冷空气,并将热空气封闭。 可以防止在沐浴者进入冷藏浴室时产生“冷感”。 沐浴的整个身体可以加热。
    • 5. 发明授权
    • Clock matching apparatus for a data reproduction system
    • 用于数据再现系统的时钟匹配装置
    • US6151282A
    • 2000-11-21
    • US409538
    • 1999-09-30
    • Kenichi HamadaSatoshi FurutaMasakazu TaguchiToru Fujiwara
    • Kenichi HamadaSatoshi FurutaMasakazu TaguchiToru Fujiwara
    • G11B20/14G11B5/09G11B7/00G11B7/005G11B11/10G11B20/10
    • G11B20/10009G11B20/10296
    • A clock matching apparatus for a data reproduction system includes a phase error detection unit which detects a phase error of a clock signal based on samples of a readout signal output by a sampler of the data reconstruction system. A phase-locked loop supplies a phase-matched clock signal to the sampler by compensating for the phase error detected by the phase error detection unit. The phase error detection unit includes an edge detection unit which detects a sampling instant for an edge sample among the samples of the readout signal. A difference unit generates a difference in timing phase between the edge sample and a sync level, the sync level being a reference signal level corresponding to a level of the readout signal at the sampling instants thereof and defined based on a partial-response waveform, the difference in the timing phase being output to the phase-locked loop as the detected phase error.
    • 用于数据再现系统的时钟匹配装置包括相位误差检测单元,其基于由数据重建系统的采样器输出的读出信号的样本来检测时钟信号的相位误差。 锁相环通过补偿由相位误差检测单元检测到的相位误差向采样器提供相位匹配的时钟信号。 相位误差检测单元包括边缘检测单元,其检测读出信号的样本中的边缘样本的采样时刻。 差分单元产生边缘样本和同步电平之间的定时相位差,同步电平是与其采样时刻的读出信号的电平相对应的参考信号电平,并且基于部分响应波形定义 作为检测到的相位误差,定时相位的差异被输出到锁相环。
    • 8. 发明授权
    • Method for manufacture of esters by transesterification
    • 通过酯交换制造酯的方法
    • US07696376B2
    • 2010-04-13
    • US10558935
    • 2004-06-23
    • Satoshi Furuta
    • Satoshi Furuta
    • C07C67/02
    • B01J21/063B01J21/066B01J23/002B01J27/16B01J35/1014B01J35/1019B01J2523/00C07C67/03C07C69/52C07C69/24B01J2523/31B01J2523/48B01J2523/51B01J2523/47B01J2523/41
    • A method for the manufacture of an ester by transesterification allows the transesterification reaction to proceed within a short reaction time and under a pressure of the order of normal pressure. It was found that transesterification proceeds when a starting material ester and an alcohol are brought into contact with a catalyst comprising (A) an amorphous zirconium oxide and (B) an oxide of a Group II element, an oxide of a Group V element, and/or an oxide of a Group IV element other than zirconium and hafnium. In this method, it is preferred that the starting material ester in a liquid-phase state and the alcohol in a vapor-phase state be brought into contact with a solid acid catalyst comprising the above components (A) and (B), the starting material ester be an oil or fat, and the alcohol be methanol or ethanol. An oxide of titanium, silicon, germanium, or tin is the preferred oxide of the Group IV element other than zirconium and hafnium.
    • 通过酯交换法制造酯的方法允许酯交换反应在短的反应时间内和在正常压力的压力下进行。 已经发现,当使原料酯和醇与包含(A)无定形氧化锆和(B)II族元素的氧化物,V族元素的氧化物和 /或除了锆和铪之外的IV族元素的氧化物。 在该方法中,优选使液相状态的原料酯和气相状态的醇与包含上述成分(A)和(B)的固体酸催化剂接触,起始 原料酯为油或脂肪,醇为甲醇或乙醇。 钛,硅,锗或锡的氧化物是除了锆和铪之外的第IV族元素的优选氧化物。
    • 9. 发明授权
    • Ester production method by transesterification reaction using solid acid catalyst
    • 酯类生产方法采用酯交换反应使用固体酸催化剂
    • US07211681B2
    • 2007-05-01
    • US10544822
    • 2004-03-19
    • Satoshi Furuta
    • Satoshi Furuta
    • C07C51/43C07C67/02
    • C11C3/10B01J23/30B01J27/053C07C67/03C11C3/003C07C69/24C07C69/52
    • It is an object of this invention to provide a method for producing an ester by a transesterification reaction in which the reaction can be stably performed in a short time at a pressure approximately equal to normal pressure. The ester is produced by a transesterification reaction in which a starting material ester and an alcohol are brought into contact with a solid acid catalyst that displays the characteristics of a very strong acid in terms of the absolute value of argon adsorption heat ranging from 15 to 22 kJ/mol. In particular, it is preferable that the starting material ester in a liquid phase and alcohol in a vapor phase be brought into contact with the solid acid catalyst, and that the starting material ester be oil or fat, and the alcohol be methanol or ethanol.
    • 本发明的目的是提供一种通过酯交换反应制备酯的方法,其中反应可在短时间内以大约等于常压的压力稳定地进行。 该酯通过酯交换反应制备,其中原料酯和醇与固体酸催化剂接触,该固体酸催化剂以从15至22的氩吸附热的绝对值显示出非常强的酸的特性 kJ / mol。 特别优选使液相中的原料酯和汽相的醇与固体酸催化剂接触,原料酯为油脂,醇为甲醇或乙醇。