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1. 发明授权

US06887557B2 Anti-static hard coat film and method of manufacturing the same 有权
标题翻译：防静电硬涂膜及其制造方法
公开(公告)号：US06887557B2
公开(公告)日：2005-05-03
申请号：US10197475
申请日：2002-07-18
申请人： Yutaka Onozawa , Satoru Shoshi , Shigenobu Maruoka
发明人： Yutaka Onozawa , Satoru Shoshi , Shigenobu Maruoka
IPC分类号： C08J7/04 , B05D5/12 , B29D7/01 , B32B3/00 , B32B5/16 , B32B7/02 , B32B27/08 , B32B27/16 , B32B27/18 , C08J7/18 , C09D5/00 , H05F1/02
CPC分类号： B05D7/536 , B05D1/32 , B05D3/067 , B05D5/00 , C08J7/042 , C08J2367/02 , C09D5/24 , G02B1/105 , G02B1/14 , G02B1/16 , Y10T428/24802 , Y10T428/24893 , Y10T428/24909 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/264 , Y10T428/31 , Y10T428/31536
摘要： An anti-static hard coat film is easy to manufacture, has a high total light transmission, achieves favorable viewability for displayed images, and has a superior balance between an anti-static effect and a resistance to scratch. A hard coat layer made of an ionizing radiation-curable resin and an anti-static layer, which is about 0.03 to 2 μm thick and is made of ionizing radiation-curable resin that includes anti-static particles with an average particle diameter of about 0.01 to 2 μm, are formed in order on a base film, and the Taber abrasion resistance is set at 25 or below as measured in accordance with JIS K5400.
摘要翻译：防静电硬涂膜容易制造，总透光率高，对于显示图像实现良好的可视性，并且在防静电效果和耐擦伤性之间具有优异的平衡。由电离辐射固化树脂制成的硬涂层和抗静电层，其厚度为约0.03至2μm，由电离辐射固化树脂制成，其包含平均粒径为约0.01的抗静电颗粒至2μm，在基膜上依次形成，并且泰伯的耐磨性根据JIS K5400测定为25或更低。

2. 发明授权

US06613426B2 Very fine anti-glare hard coat film 有权
标题翻译：非常好的抗眩光硬涂膜
公开(公告)号：US06613426B2
公开(公告)日：2003-09-02
申请号：US09873865
申请日：2001-06-04
申请人： Yutaka Onozawa , Shigenobu Maruoka , Satoru Shoshi
发明人： Yutaka Onozawa , Shigenobu Maruoka , Satoru Shoshi
IPC分类号： B32B516
CPC分类号： C08J7/047 , B32B5/16 , C08F2/44 , C08J2433/00 , C08K3/36 , C09D4/00 , C09J7/29 , C09J2205/106 , C09J2433/006 , Y10T428/25 , Y10T428/256 , Y10T428/259 , Y10T428/28 , Y10T428/2848 , Y10T428/31797 , Y10T428/31855 , C08F222/1006
摘要： A very fine anti-glare hard coat film which comprises a base film and a hard coat layer disposed on the base film and has a haze of 3% or greater, wherein the hard coat layer comprises (A) a resin cured by an ionizing radiation and, per 100 parts by weight of the resin, 2 to 25 parts by weight of (B) silica particles having an average diameter of 0.5 to 5 &mgr;m and 10 to 200 parts by weight of (C) fine particles having an average diameter of 1 to 60 nm. The very fine anti-glare hard coat film provides excellent visibility when the film is used for various types of displays since the film provides an excellent anti-glare property to the displays such as very fine liquid crystal displays without deterioration in the quality of displayed images.
摘要翻译：一种非常细的防眩硬涂膜，其包含基膜和设置在基膜上的雾涂层为3％以上的硬涂层，其中硬涂层包含（A）通过电离辐射固化的树脂相对于树脂100重量份，平均粒径为0.5〜5μm的（B）二氧化硅粒子2〜25重量份，平均粒径为10〜200重量份的（C） 1〜60nm。非常好的抗眩光硬涂膜在将膜用于各种显示器时提供优异的可视性，因为该膜对诸如非常精细的液晶显示器的显示器提供优异的抗眩光性能，而不会劣化显示图像的质量。

3. 发明授权

US06773835B2 Film for optical applications 有权
标题翻译：光学应用薄膜
公开(公告)号：US06773835B2
公开(公告)日：2004-08-10
申请号：US10134779
申请日：2002-04-29
申请人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka
发明人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka
IPC分类号： B32B900
CPC分类号： G02B1/14 , G02B1/105 , G02B1/111 , G02B1/16 , G02B1/18 , H01J2211/44 , Y10S428/913 , Y10T428/24975 , Y10T428/256 , Y10T428/26 , Y10T428/263 , Y10T428/264 , Y10T428/265 , Y10T428/31663
摘要： A film for optical applications comprising (A) a hard coat layer which comprises a resin cured by an ionizing radiation, (B) a high refractivity layer which comprises a resin cured by an ionizing radiation and at least two metal oxides comprising tin oxide doped with antimony and has a refractive index in a range of 1.65 to 1.80 and (C) a low refractivity layer which comprises a siloxane-based polymer and has a refractive index in a range of 1.37 to 1.47, layers (A) to (D) each having a specific thickness and being successively laminated at least on one face of a substrate film. The film exhibits an excellent property for preventing reflection of light and excellent scratch resistance and can be produced at a low cost.
摘要翻译：一种用于光学应用的膜，包括（A）硬涂层，其包含通过电离辐射固化的树脂，（B）高折射率层，其包含通过电离辐射固化的树脂和至少两种金属氧化物，所述金属氧化物包含掺杂有锑，折射率为1.65〜1.80，（C）低折射率层，其包含硅氧烷类聚合物，折射率为1.37〜1.47，各层（A）〜（D）各自为具有特定厚度并且至少在基底膜的一个面上依次层叠。该膜具有优异的防止光反射和耐擦伤性的特性，可以低成本地制造。

4. 发明授权

US06859322B2 Film for optical applications 有权
标题翻译：光学应用薄膜
公开(公告)号：US06859322B2
公开(公告)日：2005-02-22
申请号：US10085570
申请日：2002-02-27
申请人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka
发明人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka
IPC分类号： G02B1/10 , B32B7/02 , B32B27/00 , G02B1/11 , G02B1/111 , G02B1/14 , G02B1/16 , G02B1/18
CPC分类号： G02B1/111
摘要： A film for optical applications comprising (A) a hard coat layer which comprises a resin cured by an ionizing radiation, (B) a high refractivity layer I which comprises a resin cured by an ionizing radiation and a metal oxide and has a refractive index in a range of 1.70 to 1.95, (C) a high refractivity layer II which comprises a resin cured by an ionizing radiation and a metal oxide and has a refractive index in a range of 1.60 to 1.70 and (D) a low refractivity layer which comprises a siloxane-based polymer and has a refractive index in a range of 1.37 to 1.47, layers (A) to (D) having specific thicknesses and being successively laminated at least on one face of a substrate film. The film exhibits an excellent property for preventing reflection of light and excellent scratch resistance and can be produced at a low cost.
摘要翻译：一种用于光学应用的膜，包括（A）硬涂层，其包含通过电离辐射固化的树脂，（B）高折射率层I，其包含通过电离辐射固化的树脂和金属氧化物，并且折射率在范围为1.70至1.95，（C）高折射率层II，其包括通过电离辐射固化的树脂和金属氧化物，并且折射率在1.60至1.70的范围内，（D）低折射率层，其包含硅氧烷类聚合物，其折射率在1.37〜1.47的范围内，具有特定厚度的层（A）至（D），并且至少在基材膜的一个面上依次层叠。该膜具有优异的防止光反射和耐擦伤性的特性，可以低成本地制造。

5. 发明授权

US06841272B2 Film for optical applications 失效
标题翻译：光学应用薄膜
公开(公告)号：US06841272B2
公开(公告)日：2005-01-11
申请号：US10278273
申请日：2002-10-23
申请人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka , Yoshitaka Takesako
发明人： Satoru Shoshi , Yutaka Onozawa , Shigenobu Maruoka , Yoshitaka Takesako
IPC分类号： G02B5/02 , B32B7/02 , C08J7/04 , G02B1/10 , G02B1/11 , G02B1/111 , G02B1/14 , G02B1/16 , G02B1/18 , B32B3/12 , B32B19/00 , G02B5/08
CPC分类号： C08J7/045 , G02B1/105 , G02B1/111 , G02B1/14 , G02B1/16 , G02B1/18 , Y10T428/24504 , Y10T428/24802 , Y10T428/24942 , Y10T428/2495 , Y10T428/26
摘要： A film for optical applications comprising (A) a hard coat layer which comprises a metal oxide and a substance cured by heat or by an ionizing radiation and has a thickness in a range of 2 to 20 μm and (B) a low refractivity layer which comprises porous silica and a polysiloxane-based polymer and has a refractive index in a range of 1.30 to 1.45 and a thickness in a range of 40 to 200 nm, layers (A) and (B) being successively laminated at least on one face of a substrate film. The film exhibits an excellent property for preventing reflection of light and excellent scratch resistance and can be produced at a low cost.
摘要翻译：一种用于光学应用的膜，其包含（A）硬涂层，其包含金属氧化物和通过热或通过电离辐射固化并具有2至20μm的厚度的物质和（B）低折射率层，包括多孔二氧化硅和聚硅氧烷类聚合物，其折射率在1.30〜1.45的范围内，厚度在40〜200nm的范围内，层（A）和（B）的至少一面基底膜。该膜具有优异的防止光反射和耐擦伤性的特性，可以低成本地制造。

6. 发明申请

US20060171034A1 OPTICAL FILM 有权
标题翻译：光学胶片
公开(公告)号：US20060171034A1
公开(公告)日：2006-08-03
申请号：US10549044
申请日：2004-03-28
申请人： Satoru Shoshi , Yutaka Onozawa
发明人： Satoru Shoshi , Yutaka Onozawa
IPC分类号： G02B1/10
CPC分类号： G02B1/111 , G02B1/116 , G02B1/14 , G02B1/16 , G02F1/133502 , H01J29/896
摘要： A film for optical applications which effectively prevents reflection of light on the surface of image display devices such as PDP, CRT and LCD, exhibits excellent scratch resistance and transmission of light, provides excellent adhesion between layers and can be produced at a low cost is disclosed. The film comprises (A) a high refractivity hard coat layer (the refractive index: 1.60 to 1.75, the thickness: 2 to 20 μm) comprising (a) an antimony-doped tin oxide having a needle shape (the average particle diameter along the major axis: 0.05 to 10 μm, the average aspect ratio: 3 to 100), (b) at least one other metal oxide and (c) a material cured with an ionizing radiation and (B) a low refractivity layer (the refractive index: 1.30 to 1.45, the thickness: 40 to 200 nm), which are successively laminated at least on one face of a substrate film.
摘要翻译：用于光学应用的薄膜，其有效地防止了诸如PDP，CRT和LCD等图像显示装置的表面上的光的反射，显示出优异的耐擦伤性和透光性，提供了优异的层之间的粘附性，并且可以以低成本生产。该膜包含（A）高折射率硬涂层（折射率：1.60〜1.75，厚度：2〜20μm），其包含（a）具有针状的锑掺杂氧化锡（沿着长轴：0.05〜10μm，平均纵横比：3〜100），（b）至少一种其他金属氧化物和（c）用电离辐射固化的材料和（B）低折射率层（折射率：1.30〜1.45，厚度：40〜200nm），其依次层叠在基板的至少一个面上。

7. 发明申请

US20100208352A1 GLARE-PROOFING AND LIGHT-TRANSMITTING HARD COAT FILM 有权
标题翻译：防伪和发光硬膜
公开(公告)号：US20100208352A1
公开(公告)日：2010-08-19
申请号：US12602025
申请日：2008-05-27
申请人： Yutaka Onozawa , Satoru Shoshi
发明人： Yutaka Onozawa , Satoru Shoshi
IPC分类号： G02B5/02 , G02B1/10
CPC分类号： G02B1/111 , C09D5/24 , C09D7/61 , C09D7/68 , C09D7/69
摘要： The present invention provides a which comprises a cured resin layer (A) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein and a cured resin layer (B) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein, and the layer (A) and the layer (B) being laminated in order on at least one surface of a light-transmitting substrate film, wherein a total film thickness of the layer (A) and the layer (B) is 1 to 10 μm, a microparticle A having an average particle size of 0.5 to 10 μm is compounded in the layer (A) in an amount of 0.5 to 60 parts by mass to 100 parts by mass of an active energy ray curable compound, and a microparticle B having an average particle size which is less than an average particle size of the microparticle A is compounded in the layer (B). The glare-proofing and light-transmitting hard coat film of the present invention can have a satisfactory level of a glare-proofing property and display a black color on an image more intensely.
摘要翻译：本发明提供一种包含含有活性能量射线固化性化合物和分散在其中的微粒的固化性组合物的固化树脂层（A）和含有活性能量射线固化性化合物的固化性组合物的固化树脂层（B）分散在其中的微粒，并且层（A）和层（B）依次层叠在透光性基材膜的至少一个表面上，其中层（A）和层（B）的总膜厚度）为1〜10μm，相对于100质量份的活性能量射线固化性化合物，在层（A）中将平均粒径为0.5〜10μm的微粒A配合0.5〜60质量份，并且在层（B）中配合平均粒径小于微粒A的平均粒径的微粒B. 本发明的防眩光透光性硬涂膜可以具有令人满意的防眩光性能，更强烈地在图像上显示黑色。

8. 发明申请

US20060099385A1 Material for forming antiglare hard coat layer and antiglare hard coat film 审中-公开
标题翻译：用于形成防眩硬涂层和防眩涂硬涂层的材料
公开(公告)号：US20060099385A1
公开(公告)日：2006-05-11
申请号：US11256265
申请日：2005-10-20
申请人： Yutaka Onozawa , Satoru Shoshi
发明人： Yutaka Onozawa , Satoru Shoshi
IPC分类号： B32B27/40 , B32B27/36 , B32B27/30 , B32B27/00
CPC分类号： C08J7/047 , Y10T428/24355 , Y10T428/265 , Y10T428/31504 , Y10T428/31551 , Y10T428/31786 , Y10T428/31935
摘要： A material for forming an antiglare hard coat layer which comprises (A) a polymerizable compound of an active energy beam curing type, (B) a thermoplastic resin, (C) a good solvent for (A) and (B), and (D) a poor solvent for (B), wherein the ratio of amounts by weight of (A) to (B) is 100:0.3 to 100:50 and the ratio of amounts by weight of (C) to (D) is 99:1 to 30:70; and an antiglare hard coat film which comprises an antiglare hard coat layer comprising a layer of an active energy beam-cured resin formed by using the above material and disposed on a substrate film. The hard coat film contains no fine particles or a decreased amount of fine particles for providing the antiglare property and exhibits highly fine antiglare property, stable optical properties and excellent scratch resistance.
摘要翻译：用于形成防眩光硬涂层的材料，其包含（A）活性能量束固化型的可聚合化合物，（B）热塑性树脂，（C）（A）和（B）的良溶剂和（D ）（B）的不良溶剂，其中（A）与（B）的重量比为100:0.3至100:50，（C）与（D）的重量比为99： 1到30:70; 以及防眩硬涂膜，其包括防眩硬涂层，其包含通过使用上述材料形成并设置在基底膜上的活性能量束固化树脂层。硬涂膜不含细颗粒或减少用于提供防眩光性能的细颗粒，并且具有高度的防眩光性能，稳定的光学性能和优异的耐刮擦性。

9. 发明授权

US08333478B2 Glare-proofing and light-transmitting hard coat film 有权
标题翻译：防眩透光硬涂膜
公开(公告)号：US08333478B2
公开(公告)日：2012-12-18
申请号：US12602025
申请日：2008-05-27
申请人： Yutaka Onozawa , Satoru Shoshi
发明人： Yutaka Onozawa , Satoru Shoshi
IPC分类号： G02B27/00
CPC分类号： G02B1/111 , C09D5/24 , C09D7/61 , C09D7/68 , C09D7/69
摘要： A film includes a cured resin layer (A) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein and a cured resin layer (B) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein laminated in order on at least one surface of a light-transmitting substrate film, wherein the total film thickness of layer (A) and layer (B) is 1 to 10 μm, a microparticle (a) having an average particle size of 0.5 to 10 μm is compounded in layer (A) in an amount of 0.5 to 60 parts by mass to 100 parts by mass of an active energy ray curable compound, and a microparticle (b) having an average particle size which is less than an average particle size of the microparticle (a) is compounded in layer (B).
摘要翻译：膜包括含有活性能量射线固化性化合物和分散在其中的微粒的固化性组合物的固化树脂层（A）和含有活性能量射线固化性化合物和分散在其中的微粒的固化性组合物的固化树脂层（B）层叠在透光性基板膜的至少一个面上，其中，层（A）和层（B）的总膜厚为1〜10μm，平均粒径为0.5〜相对于100质量份的活性能量射线固化性化合物和平均粒径小于平均粒子的微粒（b），在层（A）中以10μm〜60质量份的量配合10μm 微粒（a）的尺寸在层（B）中复合。

10. 发明申请

US20100178469A1 GLARE-PROOFING AND LIGHT-TRANSMITTING HARD COAT FILM 审中-公开
标题翻译：防伪和发光硬膜
公开(公告)号：US20100178469A1
公开(公告)日：2010-07-15
申请号：US12601941
申请日：2008-05-27
申请人： Yutaka Onozawa , Satoru Shoshi
发明人： Yutaka Onozawa , Satoru Shoshi
IPC分类号： G02B1/10 , B32B7/02 , B32B5/22 , B32B27/04
CPC分类号： G02B1/14 , G02B1/105 , G02B5/02 , Y10T428/24612 , Y10T428/24942 , Y10T428/2495
摘要： The present invention provides a glare-proofing and light-transmitting hard coat film, which comprises a cured resin layer (A) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein and a cured resin layer (B) of a curable composition containing an active energy ray curable compound and a microparticle dispersed therein, and the layer (A) and the layer (B) being laminated in order on at least one surface of a light-transmitting substrate film, wherein a center line average roughness (Ra(B)) of a surface of the layer (B) after the layer (B) is laminated, is smaller by 1 μm or more than a center line average roughness (Ra(A)) of a surface of the layer (A) before the layer (B) is laminated, and a haze value (Hz(B)) of a film after the layer (B) is laminated, is smaller by 1.5% or more than a haze value (Hz(A)) of a film after only the layer (A) is laminated and before the layer (B) is laminated. The glare-proofing and light-transmitting hard coat film of the present invention can have a satisfactory level of a glare-proofing property and display a black color on an image more intensely.
摘要翻译：本发明提供一种防眩光透光性硬涂膜，其包含含有活性能量射线固化性化合物和分散在其中的微粒的固化性组合物的固化树脂层（A）和固化树脂层（B）含有活性能量射线固化性化合物和分散在其中的微粒的固化性组合物，并且所述层（A）和所述层（B）依次层叠在透光性基板膜的至少一个面上，其中中心线平均层（B）之后的层（B）的表面的粗糙度（Ra（B））比层的表面的中心线平均粗糙度（Ra（A））小1μm以上层叠上层（B）之前的层（A）和层（B）之后的膜的雾度值（Hz（B））小于雾度值的1.5％以上（Hz（A））仅在层（A）层压之后并且层（B）层压之前的膜。本发明的防眩光透光性硬涂膜可以具有令人满意的防眩光性能，更强烈地在图像上显示黑色。

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