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    • 10. 发明授权
    • Process for removal and recovery of an arylamine compound
    • 芳胺化合物的除去和回收方法
    • US06096927A
    • 2000-08-01
    • US365486
    • 1999-08-02
    • Satish R. ParikhEdward J. Radigan, Jr.Anthony M. HorganJohn A. Bergfjord, Sr.
    • Satish R. ParikhEdward J. Radigan, Jr.Anthony M. HorganJohn A. Bergfjord, Sr.
    • C07C209/86C07C211/50C07C211/00
    • C07C209/86
    • A process for recovery of N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine from an electrophotographic imaging member, the process includingproviding an electrophotographic imaging member including at least one imaging layer, the imaging layer including a film forming binder and N,N'-bis(alkylphenyl)[1,1'-biphenyl]-4,4'-diamine,contacting the at least one imaging layer with warm toluene to dissolve toluene soluble materials including the film forming binder and N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine to form a mixture containing undissolved material and a solution of toluene and the toluene soluble materials,isolating the solution from the undissolved material,concentrating the solution in a partial vacuum and with applied heat,cooling the concentrate,mixing the concentrate with acetone to precipitate the N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine,separating the N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine precipitate from the concentrate,washing the N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine precipitate with acetone,drying the N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine precipitate,and purifying the N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine precipitate.
    • 一种从电子照相成像部件回收N,N'-双(烷基苯基) - [1,1'-联苯] -4,4'-二胺的方法,该方法包括提供电子照相成像部件,其包括至少一个成像层 ,成像层包括成膜粘合剂和N,N'-双(烷基苯基)[1,1'-联苯] -4,4'-二胺,使至少一个成像层与热甲苯接触以溶解甲苯可溶物 包括成膜粘合剂和N,N'-双(烷基苯基) - [1,1'-联苯] -4,4'-二胺以形成含有未溶解材料的混合物和甲苯和甲苯可溶物质的溶液, 来自未溶解材料的溶液,将溶液浓缩在部分真空中并加热,冷却浓缩物,将浓缩物与丙酮混合以沉淀N,N'-双(烷基苯基) - [1,1'-联苯] - 4,4'-二胺,从浓缩物中分离出N,N'-双(烷基苯基) - [1,1'-联苯] -4,4'-二胺沉淀物,洗涤 N,N'-双(烷基苯基) - [1,1'-联苯] -4,4'-二胺与丙酮沉淀,干燥N,N'-双(烷基苯基) - [1,1'-联苯基] - 4,4'-二胺沉淀,纯化N,N'-双(烷基苯基) - [1,1'-联苯] -4,4'-二胺沉淀。