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1. 发明授权

US5276239A Dimerization of long-chain olefins using a silica gel alkylsulfonic acid 失效
标题翻译：使用硅胶烷基磺酸使长链烯烃二聚
公开(公告)号：US5276239A
公开(公告)日：1994-01-04
申请号：US919455
申请日：1992-07-27
申请人： Sanderson John R. , John F. Knifton , Edward T. Marquis
发明人： Sanderson John R. , John F. Knifton , Edward T. Marquis
IPC分类号： C10G50/02 , C07C2/26 , C07C2/34
CPC分类号： C10G50/02
摘要： A process is disclosed for preparing synthetic lubricant base stocks having a high dimer to trimer ratio from long-chain olefins. These synthetic lubricant base stocks are prepared in good yield by dimerizing linear olefins using a catalyst comprising a silica gel alkylsulfonic acid.
摘要翻译：公开了一种从长链烯烃制备具有高二聚体与三聚体比的合成润滑剂基础油料的方法。通过使用包含硅胶烷基磺酸的催化剂使线性烯烃二聚来制备这些合成润滑剂基础油料。

2. 发明授权

US4910349A Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：催化剂由叔丁基过氧化氢生产叔丁醇
公开(公告)号：US4910349A
公开(公告)日：1990-03-20
申请号：US94173
申请日：1987-09-08
申请人： John R. Sanderson , John F. Knifton , Edward T. Marquis
发明人： John R. Sanderson , John F. Knifton , Edward T. Marquis
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).
摘要翻译：通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇，元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。

3. 发明授权

US5488178A Ditertiary butyl peroxide preparation from tertiary butyl hydroperoxide 失效
标题翻译：二叔丁基过氧化物由叔丁基过氧化氢制备
公开(公告)号：US5488178A
公开(公告)日：1996-01-30
申请号：US401107
申请日：1995-03-08
申请人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
发明人： John F. Knifton , Edward T. Marquis , Pei-Shing E. Dai
IPC分类号： C07C409/16
CPC分类号： C07C409/16 , C07C407/00
摘要： Disclosed is a method of selective preparation of ditertiary butyl peroxide from tertiary butyl hydroperoxide and t-butanol which comprises reacting said tertiary butyl hydroperoxide and t-butanol over a solid acid catalyst selected from:a) an acidic montmorillonite clay;b) an acidic zeolite selected from the group consisting of dealuminized Y-zeolite and pentasil zeolite;c) an acidic organic resin; andd) heteropoly acids supported on an oxide selected from Group III or Group IV.
摘要翻译：公开了从叔丁基过氧化氢和叔丁醇中选择性制备二叔丁基过氧化物的方法，其包括使所述叔丁基过氧化氢和叔丁醇在选自以下的固体酸催化剂中反应：a）酸性蒙脱土粘土; b）选自脱铝Y沸石和pentasil沸石的酸性沸石; c）酸性有机树脂; 和d）负载在选自III或IV族的氧化物上的杂多酸。

4. 发明授权

US4978800A Production of detergent range alcohols and ketones using acetylacetonate catalysts 失效
标题翻译：使用乙酰丙酮催化剂生产洗涤剂范围的醇和酮
公开(公告)号：US4978800A
公开(公告)日：1990-12-18
申请号：US428703
申请日：1989-10-30
申请人： John R. Sanderson , Edward T. Marquis , John F. Knifton
发明人： John R. Sanderson , Edward T. Marquis , John F. Knifton
IPC分类号： C07C29/48 , C07C45/28
CPC分类号： C07C29/48 , C07C45/28
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal acetylacetonate catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal itself may be iron, ruthenium, chromium and mixtures thereof. If iron acetylacetonate is used as a catalyst, copper (II) acetate may be usefully employed as a co-catalyst.
摘要翻译：描述了在过渡金属乙酰丙酮化物催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。过渡金属本身可以是铁，钌，铬及其混合物。如果使用乙酰丙酮铁作为催化剂，乙酸铜（II）可用作助催化剂。

5. 发明授权

US4922036A Tertiary butyl hydroperoxide decomposition 失效
标题翻译：叔丁基过氧化氢分解
公开(公告)号：US4922036A
公开(公告)日：1990-05-01
申请号：US94175
申请日：1987-09-08
申请人： John R. Sanderson , Edward T. Marquis , John F. Knifton
发明人： John R. Sanderson , Edward T. Marquis , John F. Knifton
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a borate-promoted metal phthalocyanine catalyst such as a Group IB, VIIB or VIIIB metal phthalocyanine and a Group IA, IIA or IIB metal borate, for example, chloroferric phthalocyanine and lithium borate, barium borate, zinc borate or sodium metaborate.
摘要翻译：在硼酸盐促进的金属酞菁催化剂如IB，VIIB或VIIIB族金属酞菁和IAA IIA族的存在下，通过叔丁基过氧化氢的催化分解，优选在叔丁醇溶液中催化分解叔丁醇。或IIB金属硼酸盐，例如氯代酞菁和硼酸锂，硼酸钡，硼酸锌或偏硼酸钠。

6. 发明授权

US4891437A Olefin epoxidation of olefins in a polar medium 失效
标题翻译：烯烃在极性介质中的烯烃环氧化
公开(公告)号：US4891437A
公开(公告)日：1990-01-02
申请号：US133664
申请日：1987-12-16
申请人： Edward T. Marquis , Kenneth P. Keating , John F. Knifton , William A. Smith , John R. Sanderson , Jonathan Lustri
发明人： Edward T. Marquis , Kenneth P. Keating , John F. Knifton , William A. Smith , John R. Sanderson , Jonathan Lustri
IPC分类号： C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , C07D303/04
摘要： A hydroperoxide charge stock (t-butyl hydroperoxide or t-amyl hydroperoxide) is reacted with a C.sub.3 to C.sub.20 olefin charge stock in liquid phase in a reaction zone in the presence of a catalytically effective amount of a soluble molybdenum catalyst to form a product olefin epoxide corresponding to the olefin charge stock and a product alcohol corresponding to the hydroperoxide charge (t-butyl alcohol or t-amyl alcohol), which process is improved in accordance with the present invention by maintaining a reaction medium composed of more than 60 wt % of polar components (hydroperoxide charge stock, product alcohol and product epoxide) in the reaction zone by charging to the reaction zone at least about a 30 wt % solution of the hydroperoxide charge stock in the corresponding product alcohol and charging said olefin charge stock to said reaction zone in an amount relative to the amount of said charged solution of charged hydroperoxide in product alcohol sufficient to provide a ratio of from about 0.5 to about 2 moles of charged olefin per mole of charged hydroperoxide.The preferred olefin charge stock is propylene and the preferred hydroperoxide charge stock is t-butyl hydroperoxide. The corresponding epoxide in this situation is propylene oxide and the corresponding product alcohol is t-butyl alcohol.
摘要翻译：在催化有效量的可溶性钼催化剂的存在下，将氢过氧化物电荷原料（叔丁基过氧化氢或叔戊基过氧化氢）与液相中的C3至C20烯烃加料原料在反应区中反应以形成产物烯烃对应于烯烃电荷原料的环氧化物和对应于氢过氧化物电荷的产物醇（叔丁醇或叔戊醇），根据本发明，通过保持由60重量％以上的反应介质组成的反应介质，的反应区中的极性组分（氢过氧化物电荷原料，产物醇和产物环氧化物）通过向反应区中加入至少约30重量％的氢过氧化物电荷原料在相应产物醇中的溶液，并将所述烯烃电荷原料装入所述反应区的量相对于产物醇中充入的氢过氧化物的所述带电溶液的量足以提供从ab的比例每摩尔加入的氢过氧化物中含有0.5至约2摩尔的带电烯烃。优选的烯烃电荷原料是丙烯，优选的氢过氧化物电荷原料是叔丁基过氧化氢。在这种情况下相应的环氧化物是环氧丙烷，相应的产物醇是叔丁醇。

7. 发明授权

US5243118A Process for oligomerizing olefins using sulfate-activated molecular sieves 失效
标题翻译：使用硫酸盐活化分子筛使烯烃低聚的方法
公开(公告)号：US5243118A
公开(公告)日：1993-09-07
申请号：US803811
申请日：1991-12-09
申请人： John R. Sanderson , John F. Knifton , Edward T. Marquis
发明人： John R. Sanderson , John F. Knifton , Edward T. Marquis
IPC分类号： B01J21/06 , B01J27/053 , B01J29/06 , B01J37/08 , C07C2/10 , C07C2/12
CPC分类号： C07C2/10 , B01J21/06 , B01J27/053 , B01J29/06 , B01J37/088 , C07C2/12 , C07C2521/06 , C07C2529/06
摘要： An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using sulfate-activated molecular sieves as catalyst.
摘要翻译：公开了用于制备合成润滑剂基础油料的改进方法。通过使用硫酸盐活化分子筛作为催化剂使线性烯烃低聚制备合成润滑剂基础油料。

8. 发明授权

US5159123A Synthesis of hydroxyl-terminated polybutadienes using glycol ether acetate solvents 失效
标题翻译：使用二醇醚乙酸酯溶剂合成羟基封端的聚丁二烯
公开(公告)号：US5159123A
公开(公告)日：1992-10-27
申请号：US694590
申请日：1991-05-02
申请人： John F. Knifton , Edward T. Marquis
发明人： John F. Knifton , Edward T. Marquis
IPC分类号： C07C29/36
CPC分类号： C07C29/36
摘要： Disclosed is an improvement in a process for polymerizing 1,3-butadiene selectively to form relatively low molecular weight hydroxyl-terminated polybutadiene oligomers in the presence of an aqueous solution of hydrogen peroxide which comprises the use of a solvent selected from the group consisting of alkylene glycol monoalkyl ether acetates and aliphatic glycol ether carboxylates to produce butadiene oligomers having a high degree of OH functionality and suppression of formation of solid or gel-type insoluble rubber by-products.
摘要翻译：公开了在过氧化氢水溶液存在下选择性地聚合1,3-丁二烯以形成相对低分子量的羟基封端的聚丁二烯低聚物的方法的改进，该方法包括使用选自以下的溶剂：亚烷基乙二醇单烷基醚乙酸酯和脂肪族二醇醚羧酸酯，以产生具有高OH官能度的丁二烯低聚物并抑制固体或凝胶型不溶性橡胶副产物的形成。

9. 发明授权

US5053569A Process for oligomerizing olefins to prepare base stocks for synthetic lubricants 失效
标题翻译：低聚烯烃以制备合成润滑剂的基础油的方法
公开(公告)号：US5053569A
公开(公告)日：1991-10-01
申请号：US500631
申请日：1990-03-28
申请人： Edward T. Marquis , John R. Sanderson , John F. Knifton
发明人： Edward T. Marquis , John R. Sanderson , John F. Knifton
IPC分类号： B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C10M107/12
CPC分类号： C10M107/12 , B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C07C2521/16 , C07C2527/128 , C07C2527/138 , C07C2527/25 , C10M2205/003 , C10M2205/0285 , C10M2205/043
摘要： A process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When the oligomers are hydrogenated, they provide a synthetic lubricant base stock having excellent properties.
摘要翻译：公开了制备合成润滑剂基础油料的方法。可以通过使用某些酸性钙蒙脱石粘土催化剂使线性烯烃低聚来制备合成润滑剂基础油料。当低聚物被氢化时，它们提供具有优异性能的合成润滑剂基础油料。

10. 发明授权

US5025112A Purification of cumene recycle streams 失效
标题翻译：异丙苯循环物流的净化
公开(公告)号：US5025112A
公开(公告)日：1991-06-18
申请号：US580035
申请日：1990-09-10
申请人： John R. Sanderson , Edward T. Marquis , John F. Knifton
发明人： John R. Sanderson , Edward T. Marquis , John F. Knifton
IPC分类号： B01J21/16 , B01J27/182 , C07B61/00 , C07C7/148 , C07C15/085
CPC分类号： C07C7/148 , Y02P20/52
摘要： A method for purifying a cumene recycle stream by removing 2-phenyl-2-propanol and cumene hydroperoxide before the cumene is distilled and recycled to the peroxidation reactor which comprises reacting the recycle cumene in the presence of an acid treated montmorillonite clay of the formula:M.sub.x/n.sup.n+.sub..y H.sub.2 O(Al.sub.4-x Mg.sub.x) (Si.sub.8)O.sub.20 (OH).sub.4or in the presence of a catalyst comprising phosphoric acid on silica.
摘要翻译：一种在异丙基苯蒸馏并再循环至过氧化反应器之前通过除去2-苯基-2-丙醇和异丙基氢过氧化氢来净化枯烯循环物流的方法，该方法包括在下列通式的酸处理蒙脱石粘土存在下使回收枯烯反应： Mx / nn + .yH2O（Al4-xMgx）（Si8）O20（OH）4或在二氧化硅上含有磷酸的催化剂存在下进行。

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