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1. 发明授权

US07235612B2 Polymer alloy and method for manufacturing polymer alloy 有权
标题翻译：聚合物合金及其制造方法
公开(公告)号：US07235612B2
公开(公告)日：2007-06-26
申请号：US10766487
申请日：2004-01-29
申请人： Sadayuki Kobayashi , Jiro Kumaki , Akira Hirai , Toru Nishimura
发明人： Sadayuki Kobayashi , Jiro Kumaki , Akira Hirai , Toru Nishimura
IPC分类号： C08J3/00 , C08L69/00 , C08L67/02
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of 0.001 to 1 μm. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译：本发明是一种制造聚合物合金的方法，通过使至少两种树脂用作可混溶的组分，并引起旋节分解引起相分离，形成波长为0.001至1μm的共连续结构或具有0.001至1μm的颗粒之间的距离的分散结构。本发明也是通过该方法制造的聚合物合金。本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。

2. 发明申请

US20070225450A1 Polymer alloy 失效
标题翻译：聚合物合金
公开(公告)号：US20070225450A1
公开(公告)日：2007-09-27
申请号：US11802762
申请日：2007-05-24
申请人： Sadayuki Kobayashi , Jiro Kumaki
发明人： Sadayuki Kobayashi , Jiro Kumaki
IPC分类号： C08L67/00
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of 0.001 to 1 μm. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译：本发明是一种制造聚合物合金的方法，通过使至少两种树脂用作可混溶的组分，并引起旋节分解以引起相分离，形成波长为0.001至1μm的共连续结构或具有0.001至1μm的颗粒之间的距离的分散结构。本发明也是通过该方法制造的聚合物合金。本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。

3. 发明申请

US20070032577A1 Polylactic acid resin composition, process for producing the same, biaxially stretched polylactic acid film, and molded articles thereof 有权
标题翻译：聚乳酸树脂组合物，其制造方法，双轴拉伸聚乳酸薄膜及其成型体
公开(公告)号：US20070032577A1
公开(公告)日：2007-02-08
申请号：US10550666
申请日：2004-02-10
申请人： Takeshi Kanzawa , Sadayuki Kobayashi , Minoru Yoshida , Fumie Sakida , Jiro Kumaki
发明人： Takeshi Kanzawa , Sadayuki Kobayashi , Minoru Yoshida , Fumie Sakida , Jiro Kumaki
IPC分类号： C09D101/18
CPC分类号： C08L67/04 , C08J5/18 , C08J2367/04 , C08L1/10 , C08L25/18 , C08L33/08 , C08L33/10 , C08L2666/26 , C08L2666/06 , C08L2666/04
摘要： The invention provides a resin composition containing poly(lactic acid) and a cellulosic ester, which are biomass type materials; a resin composition excellent in transparency, mechanical properties, and thermostability; a biaxially drawn film containing poly(lactic acid) and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; and a biaxially drawn film excellent in transparency, mechanical properties, and thermostability. The aims of the invention can be achieved by a resin composition obtained by melt-kneading a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and a cellulosic ester; a resin composition excellent in transparency and having luminous transmittance of 40% or higher for visible light with 400 nm; its production method; a molded article and a film made of the resin composition; a poly(lactic acid) biaxially drawn film containing a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60° C. or higher; a poly(lactic acid) biaxially drawn film excellent in transparency and having film haze of 10% or lower; and a molded article made of the film.
摘要翻译：本发明提供含有聚（乳酸）和纤维素酯的树脂组合物，其为生物质型材料; 透明性，机械性能和热稳定性优异的树脂组合物; 含有聚（乳酸）和至少一种选自纤维素酯，聚（甲基）丙烯酸酯和玻璃化转变温度为60℃以上的聚乙烯基化合物的化合物的双轴拉伸膜; 以及透明性，机械性能和热稳定性优异的双轴拉伸膜。本发明的目的可以通过将重均分子量为50,000以上的聚（乳酸）聚合物和纤维素酯熔融捏合得到的树脂组合物实现，对于400nm的可见光，透明性优异，透光率为40％以上的树脂组合物; 其生产方式; 模塑制品和由该树脂组合物制成的薄膜; 含有重均分子量为50,000以上的聚（乳酸）聚合物的聚（乳酸）双轴拉伸膜和至少一种选自纤维素酯，聚（甲基）丙烯酸酯和具有玻璃化转变的聚乙烯基化合物的化合物温度为60℃以上; 具有透明性优异且膜雾度为10％以下的聚（乳酸）双轴拉伸膜; 和由该膜制成的模制品。

4. 发明授权

US07462672B2 Polymer alloy 失效
标题翻译：聚合物合金
公开(公告)号：US07462672B2
公开(公告)日：2008-12-09
申请号：US11802762
申请日：2007-05-24
申请人： Sadayuki Kobayashi , Jiro Kumaki
发明人： Sadayuki Kobayashi , Jiro Kumaki
IPC分类号： C08L67/02 , C08L81/04
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： A polymer alloy of polyphenylene sulfide resin and a polyester resin with polyethylene terephthalate as a main component, and forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of to 1 μm. The co-continuous structure or dispersed structure of the polymer alloy is formed by the phase separation caused by spinodal decomposition. The polymer alloy is miscible when the shear rate is kept in a range from 100 to 10000 sec−1, and is separated into phases under no shear flow. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译：聚苯硫醚树脂和聚对苯二甲酸乙二醇酯作为主要成分的聚酯树脂的聚合物合金，形成浓度波动为0.001〜1μm的共连续结构体或粒径为1μm的分散结构体。聚合物合金的共连续结构或分散结构通过由旋节分解引起的相分离形成。当剪切速率保持在100至10000秒-1的范围内时，聚合物合金是可混溶的，并且在无剪切流动下分离成相。本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。

5. 发明授权

US08383717B2 Synthetic polymers controlled in spiral structure, host-guest compounds prepared by using the same, and processes for production of both 有权
标题翻译：以螺旋结构控制的合成聚合物，通过使用它们制备的主体 - 客体化合物和两者的生产方法
公开(公告)号：US08383717B2
公开(公告)日：2013-02-26
申请号：US12599455
申请日：2008-03-18
申请人： Takehiro Kawauchi , Jiro Kumaki , Eiji Yashima
发明人： Takehiro Kawauchi , Jiro Kumaki , Eiji Yashima
IPC分类号： C08K3/04 , C08L33/00
CPC分类号： C08F220/14
摘要： The invention provides a process for producing spiral polymers controlled in the direction of spiral winding easily from inexpensive general-purpose polymers; and spiral polymers controlled in the direction of spiral winding. The invention relates to a process for the production of syndiotactic polymethacrylate- or polyacrylate-type spiral polymers controlled in the direction of spiral winding which comprises dissolving a syndiotactic polymethacrylate- or polyacrylate-type polymer and a chiral compound in a solvent preferably under heating, subjecting the obtained solution to cooling or concentration to form a solid matter, and separating the solid matter; and so on.
摘要翻译：本发明提供了一种从便宜的通用聚合物制备螺旋形聚合物的方法，该方法容易地从螺旋缠绕方向控制; 螺旋聚合物控制在螺旋缠绕的方向。本发明涉及一种在螺旋缠绕方向上制备间同立构聚甲基丙烯酸酯或聚丙烯酸酯型螺旋聚合物的方法，该方法包括将间同立构聚甲基丙烯酸酯或聚丙烯酸酯类聚合物和手性化合物溶解在溶剂中，优选在加热下，将得到的溶液冷却或浓缩形成固体物质，分离固体物质; 等等。

6. 发明授权

US07550541B2 Resin composition and molded article, film and fiber each comprising the same 失效
标题翻译：树脂组合物和模制品，各自包括它们的膜和纤维
公开(公告)号：US07550541B2
公开(公告)日：2009-06-23
申请号：US11826011
申请日：2007-07-11
申请人： Hiroyuki Ohme , Sadanori Kumazawa , Jiro Kumaki
发明人： Hiroyuki Ohme , Sadanori Kumazawa , Jiro Kumaki
IPC分类号： C08J3/00 , C08J5/00 , C08L59/00 , C08L67/04
CPC分类号： C08L59/00 , C08K3/013 , C08K3/014 , C08K5/005 , C08L33/04 , C08L67/00 , C08L67/025 , C08L67/04 , C08L77/00 , C08L2201/00 , C08L2666/18 , C08L2666/02 , C08L2666/16
摘要： Disclosed are a resin composition comprising a polylactic acid resin and a polyacetal resin, and such a resin composition in which the polylactic acid resin and the polyacetal resin are kept miscible with each other. The resin composition has good moldability, workability, mechanical properties, heat resistance and transparency, and may be worked into moldings, films and fibers for practical use.
摘要翻译：公开了包含聚乳酸树脂和聚缩醛树脂的树脂组合物和其中聚乳酸树脂和聚缩醛树脂彼此保持混溶的树脂组合物。树脂组合物具有良好的成型性，可加工性，机械性能，耐热性和透明性，并且可以加工成用于实际使用的模制品，薄膜和纤维。

7. 发明申请

US20070260019A1 Resin composition and molded article, film and fiber each comprising the same 失效
标题翻译：树脂组合物和模制品，各自包括它们的膜和纤维
公开(公告)号：US20070260019A1
公开(公告)日：2007-11-08
申请号：US11826011
申请日：2007-07-11
申请人： Hiroyuki Ohme , Sadanori Kumazawa , Jiro Kumaki
发明人： Hiroyuki Ohme , Sadanori Kumazawa , Jiro Kumaki
IPC分类号： C08L61/02
CPC分类号： C08L59/00 , C08K3/013 , C08K3/014 , C08K5/005 , C08L33/04 , C08L67/00 , C08L67/025 , C08L67/04 , C08L77/00 , C08L2201/00 , C08L2666/18 , C08L2666/02 , C08L2666/16
摘要： Disclosed are a resin composition comprising a polylactic acid resin and a polyacetal resin, and such a resin composition in which the polylactic acid resin and the polyacetal resin are kept miscible with each other. The resin composition has good moldability, workability, mechanical properties, heat resistance and transparency, and may be worked into moldings, films and fibers for practical use.
摘要翻译：公开了包含聚乳酸树脂和聚缩醛树脂的树脂组合物和其中聚乳酸树脂和聚缩醛树脂彼此保持混溶的树脂组合物。树脂组合物具有良好的成型性，可加工性，机械性能，耐热性和透明性，并且可以加工成用于实际使用的模制品，薄膜和纤维。

8. 发明授权

US06838529B2 Polyester composition and connector 有权
标题翻译：涤纶组合物和连接器
公开(公告)号：US06838529B2
公开(公告)日：2005-01-04
申请号：US09988776
申请日：2001-11-20
申请人： Sadanori Kumazawa , Hiroyuki Ohme , Kenichi Utazaki , Jiro Kumaki
发明人： Sadanori Kumazawa , Hiroyuki Ohme , Kenichi Utazaki , Jiro Kumaki
IPC分类号： C08G59/22 , C08G59/38 , C08L63/00 , C08L67/00 , C08G59/68
CPC分类号： C08G59/38 , C08G59/226 , C08L63/00 , C08L2666/18
摘要： A polyester composition prepared by melting and blending a polyester with a glycidyl ester compound, a glycidyl ether compound and a catalyst has good hydrolysis resistance and, when melted, gives little gas generation and undergoes little viscosity change. It is most favorable for parts of automobile, electric and electronic appliances such as connectors.

9. 发明申请

US20110144262A1 SYNTHETIC POLYMERS CONTROLLED IN SPIRAL STRUCTURE, HOST-GUEST COMPOUNDS PREPARED BY USING THE SAME, AND PROCESSES FOR PRODUCTION OF BOTH 有权
标题翻译：在螺旋结构中控制的合成聚合物，使用它们制备的主体化合物和用于生产二氧化碳的方法
公开(公告)号：US20110144262A1
公开(公告)日：2011-06-16
申请号：US12599455
申请日：2008-03-18
申请人： Takehiro Kawauchi , Jiro Kumaki , Eiji Yashima
发明人： Takehiro Kawauchi , Jiro Kumaki , Eiji Yashima
IPC分类号： C08F8/48 , C08K3/04 , C08F20/18 , C08L33/06 , B82Y99/00
CPC分类号： C08F220/14
摘要： The invention provides a process for producing spiral polymers controlled in the direction of spiral winding easily from inexpensive general-purpose polymers; and spiral polymers controlled in the direction of spiral winding. The invention relates to a process for the production of syndiotactic polymethacrylate- or polyacrylate-type spiral polymers controlled in the direction of spiral winding which comprises dissolving a syndiotactic polymethacrylate- or polyacrylate-type polymer and a chiral compound in a solvent preferably under heating, subjecting the obtained solution to cooling or concentration to form a solid matter, and separating the solid matter; and so on.
摘要翻译：本发明提供了一种从便宜的通用聚合物制备螺旋形聚合物的方法，该方法容易地从螺旋缠绕方向控制; 螺旋聚合物控制在螺旋缠绕的方向。本发明涉及一种在螺旋缠绕方向上制备间同立构聚甲基丙烯酸酯或聚丙烯酸酯型螺旋聚合物的方法，该方法包括将间同立构聚甲基丙烯酸酯或聚丙烯酸酯类聚合物和手性化合物溶解在溶剂中，优选在加热下，将得到的溶液冷却或浓缩形成固体物质，分离固体物质; 等等。

10. 发明授权

US4839463A Ultra fine polymer particle and composite material of preparation for methods 失效
标题翻译：超细聚合物颗粒和复合材料的制备方法
公开(公告)号：US4839463A
公开(公告)日：1989-06-13
申请号：US841189
申请日：1986-03-19
申请人： Jiro Kumaki
发明人： Jiro Kumaki
IPC分类号： B32B5/16 , A61L29/00 , A61L33/00 , A61L33/06 , B01D69/00 , B05D1/20 , C08J3/14 , C08J5/18
CPC分类号： C08J3/14 , A61L33/0005 , A61L33/06 , A61L33/064 , B05D1/20 , B05D2401/32
摘要： A cumulatable ultrafine polymer particle consisting of one molecular chain of the polymer is prepared by spreading a dilute solution of the polymer at the interface between the atmosphere and a subphase solution having a weak affinity for the polymer, and evaporating the spreading solvent or dissolving it into the subphase. A composite material comprising the polymer particles is produced by contacting the particles formed on the subphase solution with the surface of a substrate. The particles are cumulated on the substrate in a ratio of area occupied by the particles of at least 10%. The particles may be cumulated in multiple layers on the substrate.
摘要翻译：由聚合物的一个分子链组成的可累积的超细聚合物颗粒通过在聚合物的界面处扩散聚合物的稀溶液和对聚合物具有弱亲和力的亚相溶液，并蒸发扩散溶剂或将其溶解成子阶段。包含聚合物颗粒的复合材料通过使形成在副相溶液上的颗粒与基材的表面接触来制备。颗粒以基质占据的面积比例至少为10％而累积在基材上。颗粒可以在基底上以多层累积。

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