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    • 3. 发明申请
    • METHOD OF PRODUCING LIQUID CRYSTAL POLYESTER
    • 生产液晶聚酯的方法
    • US20130197165A1
    • 2013-08-01
    • US13750349
    • 2013-01-25
    • Sumitomo Chemical Company, Limited
    • Shinji OHTOMOHidehiro KOTAKA
    • C09K19/38
    • C09K19/38C09K19/3809
    • A method is provided of producing a liquid crystal polyester, including: preparing a liquid crystal polyester prepolymer containing a repeating unit represented by general formula (1) and a repeating unit represented by general formula (2) by melt polymerization, cooling and solidifying the prepolymer to obtain a solidified prepolymer, pulverizing the solidified prepolymer to obtain a prepolymer powder, and heating the prepolymer powder to conduct solid-phase polymerization. A liquid crystal polyester is thereby prepared having a polymerization degree higher than the prepolymer. Preparing a liquid crystal polyester is performed with a rate of temperature rise within a temperature range of from a temperature 10° C. lower than a final end-point temperature of the solid-phase polymerization to the final end-point temperature of from 0.01° C./min to 0.03° C./min.
    • 提供一种制造液晶聚酯的方法,包括:通过熔融聚合,冷却和固化预聚物制备含有由通式(1)表示的重复单元和由通式(2)表示的重复单元的液晶聚酯预聚物 得到固化预聚物,粉碎固化预聚物以获得预聚物粉末,加热预聚物粉末进行固相聚合。 由此制备聚合度高于预聚物的液晶聚酯。 以比固相聚合的最终终点温度低至最终终点温度0.01℃的温度10℃的温度范围内的温度升高速度进行液晶聚酯的制备 C. / min至0.03℃/ min。