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    • 4. 发明授权
    • Preparation of polyamide-imide filaments
    • 聚酰亚胺纤维的制备
    • US3839529A
    • 1974-10-01
    • US20936571
    • 1971-12-17
    • STANDARD OIL CO
    • SERRES CSTEPHENS J
    • D01F6/60D01F6/76D01F7/00
    • D01F6/74
    • 1. A PROCESS FOR PREPARING ABRASION-RESISTANT, THERMALLY STABLE POLYAMIDE-IMIDE FILAMENTS FROM THE WATER PRECIPITATED AND WASHED POLYMER PREPARED BY REACTING ESSENTIALLY EQUIMOLAR QUANTITIES OF AN ACYL HALIDE DERIVATIVE OF TRIMELLITIC ACID ANHYDRIDE WHICH CONTAINS AT LEAST ONE ACYL HALIDE GROUP WITH THAT IN THE 4-RING POSITION AND AN AROMATIC PRIMARY DIAMINE, IN A POLAR ORGANIC SOLVENT, FOR A PERIOD OF TIME AND AT A TEMPERATURE BELOW 150*C. SUFFICIENT TO PRODUCE A POLYMER SUBSTANTIALLY IN THE POLYAMIC ACID FORM, WHICH PROCESS COMPRISES: (1) HEATING THE PRECIPITATED POLYMER AT A TEMPERATURE BETWEEN ABOUT 300*F. TO 600*F.; (2) DISSOLVING THE HEATED POLYMER INTO A POLAR ORGANIC SOLVENT AT SUCH A CONCENTRATION THAT THE SOLUTION VISCOSITY OF THE RESULTING SOLUTION IS AT LEAST ABOUT 1500 POISES WHEN MEASURED AT 25*C.; (3) SPINNING THE POLYMER SOLUTION INTO A GASEOUS ATMOSPHERE WHICH IS MAINTAINED AT A TEMPERATURE OF AT LEAST 450*F.; AND (4) CURING THE SPUN FILAMENTS FOR A TIME AND AT A TEMPERATURE ABOVE 300*F. SUFFICIENT TO CONVERT SUBSTANTIALLY ALL THE CARBOXYL AND AMIDE GROUPS AVAILABLE FOR FURTHER REACTION TO IMIDE GROUPS.