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1. 发明授权

US09660241B2 NASICON-polymer electrolyte structure 有权
公开(公告)号：US09660241B2
公开(公告)日：2017-05-23
申请号：US14198755
申请日：2014-03-06
申请人： Sharp Laboratories of America, Inc.
发明人： Long Wang , Yuhao Lu , Jong-Jan Lee , Sean Vail
IPC分类号： H01M4/58 , H01M2/16 , C01C3/12 , H01M4/136 , H01M4/04 , H01M4/62 , H02J7/00 , H01M4/134 , H01M4/1395 , C01B17/02 , C01B19/02 , C01B25/00 , C01B31/00 , C01B33/021 , C01D1/02 , C01D15/02 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/38 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/587 , H01M10/054 , H01M10/0525 , H01M10/0565 , H01M4/1397 , H01M2/14 , H01M10/056 , H01M10/052
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a sodium-containing particle electrolyte structure. The method provides sodium-containing particles (e.g., NASICON), dispersed in a liquid phase polymer, to form a polymer film with sodium-containing particles distributed in the polymer film. The liquid phase polymer is a result of dissolving the polymer in a solvent or melting the polymer in an extrusion process. In one aspect, the method forms a plurality of polymer film layers, where each polymer film layer includes sodium-containing particles. For example, the plurality of polymer film layers may form a stack having a top layer and a bottom layer, where with percentage of sodium-containing particles in the polymer film layers increasing from the bottom layer to the top layer. In another aspect, the sodium-containing particles are coated with a dopant. A sodium-containing particle electrolyte structure and a battery made using the sodium-containing particle electrolyte structure are also presented.

2. 发明授权

US09531002B2 Transition metal cyanometallate cathode battery with metal plating anode 有权
标题翻译：过渡金属氰金属阴极电池与金属电镀阳极
公开(公告)号：US09531002B2
公开(公告)日：2016-12-27
申请号：US14668788
申请日：2015-03-25
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/136 , C01C3/12 , H01M4/04 , H01M4/1397 , H01M4/58 , H01M4/66 , H01M10/054
CPC分类号： H01M4/136 , C01C3/12 , H01M4/0404 , H01M4/0452 , H01M4/1397 , H01M4/58 , H01M4/661 , H01M4/663 , H01M4/667 , H01M4/668 , H01M10/054 , Y02E60/122
摘要： A method is provided for cycling power in a transition metal cyanometallate (TMCM) cathode battery. The method provides a battery with a TMCM cathode, an anode, and an electrolyte, where TMCM corresponds to the chemical formula of AXM1NM2M(CN)Y-d(H2O), where “A” is an alkali or alkaline earth metal, and where M1 and M2 are transition metals. The method charges the battery using a first charging current, or greater. In response to the charging current, a plating of “A” metal is formed overlying a plating surface of the anode. In response to discharging the battery, the “A” metal plating is removed from the anode plating surface. In one aspect, in an initial charging of the battery, a permanent solid electrolyte interphase (SEI) layer is formed overlying the anode plating surface. In subsequent charging and discharging cycles, the permanent SEI layer is maintained overlying the anode plating surface.
摘要翻译：提供了一种在过渡金属氰金属（TMCM）阴极电池中循环功率的方法。该方法提供具有TMCM阴极，阳极和电解质的电池，其中TMCM对应于AXM1NM2M（CN）Yd（H2O）的化学式，其中“A”是碱金属或碱土金属，并且其中M1和 M2是过渡金属。该方法使用第一充电电流或更高的电池充电。响应于充电电流，在阳极的电镀表面上形成覆盖“A”金属的电镀。响应于电池的放电，从阳极电镀表面去除“A”金属电镀。一方面，在电池的初始充电中，在阳极电镀表面上形成永久的固体电解质相（SEI）层。在随后的充放电循环中，永久性SEI层保持覆盖阳极电镀表面。

3. 发明授权

US09419278B2 Rechargeable metal-ion battery with non-aqueous hybrid ion electrolyte 有权
标题翻译：具有非水混合离子电解质的可充电金属离子电池
公开(公告)号：US09419278B2
公开(公告)日：2016-08-16
申请号：US14271498
申请日：2014-05-07
申请人： Sharp Laboratories of America, Inc.
发明人： Long Wang , Yuhao Lu , David Evans
IPC分类号： H01M2/00 , H01M4/58 , H01M10/058 , H01M10/44 , H01M10/0525 , H01M10/054 , H01M10/04 , H01M4/136 , H02J7/00
CPC分类号： H01M4/58 , H01M4/136 , H01M10/049 , H01M10/0525 , H01M10/054 , H01M10/058 , H01M10/44 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a rechargeable metal-ion battery with a non-aqueous hybrid ion electrolyte. The method provides a transition metal hexacyanometallate (TMHCM) cathode (AXM1YM2Z(CN)N.MH2O), where “A” is from a first group of metals, and M1 and M2 are transition metals. The electrolyte includes a first type of cation from the first group of metals, different than “A”. The method connects the cathode and anode to external circuitry to perform initial charge/discharge operations. As a result, a hybrid ion electrolyte is formed including the first type of cation and “A” cations. Subsequently, cations are inserted into the anode during charging, which alternatively may be only “A” cations, only the first type of cation, or both the “A” cations and the first type of cation. Only “A” cations, only the first type, or both “A” and the first type of cation are inserted into the TMHCM during discharge.
摘要翻译：提供了一种用非水混合离子电解质形成可再充电金属离子电池的方法。该方法提供了过渡金属六金属金属酸盐（TMHCM）阴极（AXM1YM2Z（CN）N.MH2O），其中“A”来自第一组金属，M1和M2是过渡金属。电解质包含不同于“A”的第一类金属的第一类型的阳离子。该方法将阴极和阳极连接到外部电路以执行初始充电/放电操作。结果，形成包含第一种阳离子和“A”阳离子的混合离子电解质。随后，在充电期间将阳离子插入阳极中，或者可以仅仅是“A”阳离子，仅第一类型的阳离子，或者“A”阳离子和第一类型的阳离子。在放电期间，只有“A”阳离子，只有第一种类型，或“A”型和第一种类型的阳离子被插入到TMHCM中。

4. 发明授权

US09406919B2 Metal cyanometallate electrode with shield structure 有权
标题翻译：具有屏蔽结构的金属氰基金属电极
公开(公告)号：US09406919B2
公开(公告)日：2016-08-02
申请号：US14193501
申请日：2014-02-28
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/62 , H01M2/16 , H01M4/58 , C01C3/12 , H01M4/136 , H01M4/04 , H02J7/00 , H01M4/134 , H01M4/1395 , C01B17/02 , C01B19/02 , C01B25/00 , C01B31/00 , C01B33/021 , C01D1/02 , C01D15/02 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/38 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/587 , H01M10/054 , H01M10/0525 , H01M10/0565 , H01M4/1397 , H01M10/052
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A mechanism is presented for shielding a cathode in a metal cyanometallate battery. A battery is provided with an anode, a cathode, an electrolyte, and an ion-permeable membrane separating the anode from the cathode. The cathode is made up of a plurality of metal cyanometallate layers overlying the current collector. At least one of the metal cyanometallate layers is an active layer formed from an active material AXM1YM2Z(CN)N·MH2O, where “A” is an alkali metal, alkaline earth metal, or combination thereof. At least one of the metal cyanometallate layers is a shield layer comprising less than 50 percent by weight (wt %) active material. In response to applying an external voltage potential between the cathode and the anode, the method charges the battery. Upon discharge, the shield layer blocks metal particles from contacting active layers. Simultaneously, the shield layer transports metal ions from the electrolyte to the active layers.
摘要翻译：提出了一种用于屏蔽金属氰酸金属电池中的阴极的机理。电池设置有将阳极与阴极分离的阳极，阴极，电解质和离子透过膜。阴极由覆盖在集电器上的多个金属金属氧化物层构成。至少一种金属氰酸金属盐层是由活性物质AXM1YM2Z（CN）N·MH2O形成的活性层，其中“A”是碱金属，碱土金属或其组合。至少一种金属氰酸金属盐层是包含小于50重量％（wt％）活性物质的屏蔽层。响应于在阴极和阳极之间施加外部电压电位，该方法对电池充电。在放电时，屏蔽层阻挡金属颗粒接触活性层。同时，屏蔽层将金属离子从电解质输送到活性层。

5. 发明申请

US20140239907A1 Rechargeable Metal-Ion Battery with Non-Aqueous Hybrid Ion Electrolyte 有权
标题翻译：具有非水混合离子电解质的可充电金属离子电池
公开(公告)号：US20140239907A1
公开(公告)日：2014-08-28
申请号：US14271498
申请日：2014-05-07
申请人： Sharp Laboratories of America, Inc.
发明人： Long Wang , Yuhao Lu , David Evans
IPC分类号： H01M4/58 , H01M10/44 , H01M10/058 , H01M4/136 , H01M10/056
CPC分类号： H01M4/58 , H01M4/136 , H01M10/049 , H01M10/0525 , H01M10/054 , H01M10/058 , H01M10/44 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a rechargeable metal-ion battery with a non-aqueous hybrid ion electrolyte. The method provides a transition metal hexacyanometallate (TMHCM) cathode (AXM1YM2Z(CN)N.MH2O), where “A” is from a first group of metals, and M1 and M2 are transition metals. The electrolyte includes a first type of cation from the first group of metals, different than “A”. The method connects the cathode and anode to external circuitry to perform initial charge/discharge operations. As a result, a hybrid ion electrolyte is formed including the first type of cation and “A” cations. Subsequently, cations are inserted into the anode during charging, which alternatively may be only “A” cations, only the first type of cation, or both the “A” cations and the first type of cation. Only “A” cations, only the first type, or both “A” and the first type of cation are inserted into the TMHCM during discharge.
摘要翻译：提供了一种用非水混合离子电解质形成可再充电金属离子电池的方法。该方法提供了过渡金属六金属金属酸盐（TMHCM）阴极（AXM1YM2Z（CN）N.MH2O），其中“A”来自第一组金属，M1和M2是过渡金属。电解质包含不同于“A”的第一类金属的第一类型的阳离子。该方法将阴极和阳极连接到外部电路以执行初始充电/放电操作。结果，形成包含第一种阳离子和“A”阳离子的混合离子电解质。随后，在充电期间将阳离子插入阳极中，或者可以仅仅是“A”阳离子，仅第一类型的阳离子，或者“A”阳离子和第一类型的阳离子。在放电期间，只有“A”阳离子，只有第一种类型，或“A”型和第一种类型的阳离子被插入到TMHCM中。

6. 发明申请

US20140154575A1 CYANOMETALLATE CATHODE BATTERY AND METHOD FOR FABRICATION 有权
标题翻译：电池阴极电池和制造方法
公开(公告)号：US20140154575A1
公开(公告)日：2014-06-05
申请号：US14174171
申请日：2014-02-06
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/58 , H01M4/04
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for fabricating a cyanometallate cathode battery. The method provides a cathode of AXM1YM2Z(CN)N.MH2O, where “A” is selected from a first group of metals, and where M1 and M2 are transition metals. The method provides an anode and a metal ion-permeable membrane separating the anode from the cathode. A third electrode is also provided including “B” metal ions selected from the first group of metals. Typically, the first group of metals includes alkali and alkaline metals. The method intercalates “B” metal ions from the third electrode to the anode, the cathode, or both the anode and cathode to form a completely fabricated battery. In one aspect, a solid electrolyte interface (SEI) layer including the “B” metal ions overlies a surface of the anode, the cathode, or both the anode and cathode. A cyanometallate cathode battery is also provided.
摘要翻译：提供了制造氰金属阴极电池的方法。该方法提供了AXM1YM2Z（CN）N.MH2O的阴极，其中“A”选自第一组金属，并且其中M1和M2是过渡金属。该方法提供将阳极和阴极分开的阳极和金属离子可渗透膜。还提供了第三电极，其包括选自第一组金属的“B”族金属离子。通常，第一组金属包括碱金属和碱金属。该方法将“B”金属离子从第三电极插入阳极，阴极或阳极和阴极，以形成完全制造的电池。在一个方面，包括“B”金属离子的固体电解质界面（SEI）层覆盖阳极，阴极或阳极和阴极两者的表面。还提供了一种氰金属阴极电池。

7. 发明申请

US20170149053A1 BATTERY ELECTRODE WITH METAL PARTICLES AND PYROLYZED COATING 有权
公开(公告)号：US20170149053A1
公开(公告)日：2017-05-25
申请号：US15424549
申请日：2017-02-03
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/134 , H01M4/36 , H01M4/38 , H01M4/04 , H01M4/60 , H01M4/62 , H01M10/054 , B01J6/00 , H01M4/136 , H01M4/58
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a metal battery electrode with a pyrolyzed coating. The method provides a metallorganic compound of metal (Me) and materials such as carbon (C), sulfur (S), nitrogen (N), oxygen (O), and combinations of the above-listed materials, expressed as MeXCYNZSXXOYY, where Me is a metal such as tin (Sn), antimony (Sb), or lead (Pb), or a metal alloy. The method heats the metallorganic compound, and as a result of the heating, decomposes materials in the metallorganic compound. In one aspect, decomposing the materials in the metallorganic compound includes forming a chemical reaction between the Me particles and the materials. An electrode is formed of Me particles coated by the materials. In another aspect, the Me particles coated with a material such as a carbide, a nitride, a sulfide, or combinations of the above-listed materials.

8. 发明授权

US09627671B2 Fabrication method for metal battery electrode with pyrolyzed coating 有权
公开(公告)号：US09627671B2
公开(公告)日：2017-04-18
申请号：US14193782
申请日：2014-02-28
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Jong-Jan Lee
IPC分类号： H01M4/04 , H01M2/16 , H01M4/58 , C01C3/12 , H01M4/136 , H01M4/62 , H02J7/00 , H01M4/134 , H01M4/1395 , C01B17/02 , C01B19/02 , C01B25/00 , C01B31/00 , C01B33/021 , C01D1/02 , C01D15/02 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/38 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/587 , H01M10/054 , H01M10/0525 , H01M10/0565 , H01M4/1397 , H01M10/052
CPC分类号： H01M4/134 , B01J6/008 , C01B17/02 , C01B19/02 , C01B25/003 , C01B32/00 , C01B33/021 , C01C3/12 , C01D1/02 , C01D15/02 , C01P2002/72 , C01P2002/77 , C01P2002/88 , H01M2/14 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/0404 , H01M4/0416 , H01M4/0452 , H01M4/0471 , H01M4/049 , H01M4/0495 , H01M4/0497 , H01M4/131 , H01M4/133 , H01M4/136 , H01M4/1391 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/38 , H01M4/381 , H01M4/382 , H01M4/387 , H01M4/485 , H01M4/505 , H01M4/56 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/623 , H01M4/628 , H01M10/052 , H01M10/0525 , H01M10/054 , H01M10/056 , H01M10/0565 , H01M2004/027 , H02J7/0042 , Y02E60/122 , Y10T29/49108
摘要： A method is provided for forming a metal battery electrode with a pyrolyzed coating. The method provides a metallorganic compound of metal (Me) and materials such as carbon (C), sulfur (S), nitrogen (N), oxygen (O), and combinations of the above-listed materials, expressed as MeXCYNZSXXOYY, where Me is a metal such as tin (Sn), antimony (Sb), or lead (Pb), or a metal alloy. The method heats the metallorganic compound, and as a result of the heating, decomposes materials in the metallorganic compound. In one aspect, decomposing the materials in the metallorganic compound includes forming a chemical reaction between the Me particles and the materials. An electrode is formed of Me particles coated by the materials. In another aspect, the Me particles coated with a material such as a carbide, a nitride, a sulfide, or combinations of the above-listed materials.

9. 发明申请

US20160028086A1 Anode for Sodium-ion and Potassium-ion Batteries 有权
标题翻译：钠离子和钾离子电池阳极
公开(公告)号：US20160028086A1
公开(公告)日：2016-01-28
申请号：US14656808
申请日：2015-03-13
申请人： Sharp Laboratories of America, Inc.
发明人： Sean Vail , Yuhao Lu , Long Wang , Motoaki Nishijima , Jong-Jan Lee
IPC分类号： H01M4/583 , H01M10/054 , H01M4/62 , H01M4/58 , H01M4/04 , H01M4/1393
CPC分类号： H01M10/054 , C01C3/11 , H01M4/0404 , H01M4/0471 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/366 , H01M4/38 , H01M4/483 , H01M4/58 , H01M4/587 , H01M4/622 , H01M4/625 , H01M2004/021
摘要： A first method for fabricating an anode for use in sodium-ion and potassium-ion batteries includes mixing a conductive carbon material having a low surface area, a hard carbon material, and a binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A second method for fabricating an anode for use in sodium-ion and potassium-ion batteries mixes a metal-containing material, a hard carbon material, and binder material. A carbon-composite material is thus formed and coated on a conductive substrate. A third method for fabricating an anode for use in sodium-ion and potassium-ion batteries provides a hard carbon material having a pyrolyzed polymer coating that is mixed with a binder material to form a carbon-composite material, which is coated on a conductive substrate. Descriptions of the anodes and batteries formed by the above-described methods are also provided.
摘要翻译：用于制造用于钠离子和钾离子电池的阳极的第一种方法包括混合具有低表面积的导电碳材料，硬质碳材料和粘合剂材料。由此形成碳复合材料并将其涂覆在导电基板上。用于制造用于钠离子和钾离子电池的阳极的第二种方法将含金属的材料，硬质碳材料和粘合剂材料混合。由此形成碳复合材料并将其涂覆在导电基板上。用于制造用于钠离子和钾离子电池的阳极的第三种方法提供了具有热解聚合物涂层的硬碳材料，其与粘合剂材料混合以形成碳复合材料，其涂覆在导电基材上。还提供了通过上述方法形成的阳极和电池的描述。

10. 发明申请

US20140264160A1 Method for the Synthesis of Metal Cyanometallates 有权
标题翻译：金属金属酸盐的合成方法
公开(公告)号：US20140264160A1
公开(公告)日：2014-09-18
申请号：US14289746
申请日：2014-05-29
申请人： Sharp Laboratories of America, Inc.
发明人： Yuhao Lu , Long Wang , Sean Vail , Jong-Jan Lee
IPC分类号： H01M4/58 , C01C3/12 , C01C3/11
CPC分类号： H01M4/58 , C01C3/11 , C01C3/12 , C01P2002/50 , C01P2006/40
摘要： Methods are presented for synthesizing metal cyanometallate (MCM). A first method provides a first solution of AXM2Y(CN)Z, to which a second solution including M1 is dropwise added. As a result, a precipitate is formed of ANM1PM2Q(CN)R·FH2O, where N is in the range of 1 to 4. A second method for synthesizing MCM provides a first solution of M2C(CN)B, which is dropwise added to a second solution including M1. As a result, a precipitate is formed of M1[M2S(CN)G]1/T·DH2O, where S/T is greater than or equal to 0.8. Low vacancy MCM materials are also presented.
摘要翻译：提出了合成金属氰金属（MCM）的方法。第一种方法提供AXM2Y（CN）Z的第一溶液，向其中滴加包含M1的第二溶液。结果，由ANM1PM2Q（CN）R·FH2O形成沉淀物，其中N在1〜4的范围内。合成MCM的第二种方法是提供M2C（CN）B的第一溶液，将其逐滴加入包括M1的第二个解决方案。结果，由M1 [M2S（CN）G] 1 / T·DH2O形成沉淀物，其中S / T大于或等于0.8。还提出了低空缺MCM材料。

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