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1. 发明授权

US08329824B2 Propylene polymer compositions and uses thereof 有权
标题翻译：丙烯聚合物组合物及其用途
公开(公告)号：US08329824B2
公开(公告)日：2012-12-11
申请号：US10558076
申请日：2004-05-12
申请人： Ryoji Mori , Takashi Nakagawa , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Akira Todo
IPC分类号： C08L23/00 , C08F8/00
CPC分类号： C08L23/10 , C08L23/14 , C08L2205/02 , C08L2666/06
摘要： The present invention provides a propylene polymer composition having excellent transparency, flexibility, heat resistance, scratch resistance and rubber elasticity with a good balance. The propylene polymer composition comprises 1 to 40 parts by weight of isotactic polypropylene (i) and 60 to 99 parts by weight of a propylene/ethylene/α-olefin copolymer (ii) which contains 45 to 89% by mol of a propylene component, 10 to 25% by mol of an ethylene component, and optionally, 0 to 30% by mol of constituent units (a) derived from an α-olefin of 4 to 20 carbon atoms.
摘要翻译：本发明提供一种丙烯聚合物组合物，其具有优异的透明性，柔软性，耐热性，耐刮擦性和橡胶弹性，并具有良好的平衡性。丙烯聚合物组合物包含1至40重量份的全同立构聚丙烯（i）和60至99重量份的含有45至89摩尔％的丙烯组分的丙烯/乙烯/α-烯烃共聚物（ii） 10〜25摩尔％的乙烯成分，以及0〜30摩尔％的由4-20个碳原子的α-烯烃衍生的构成单元（a）。

2. 发明申请

US20060057321A1 Propylene polymer composition and use thereof 有权
标题翻译：丙烯聚合物组合物及其用途
公开(公告)号：US20060057321A1
公开(公告)日：2006-03-16
申请号：US10543360
申请日：2004-01-16
申请人： Ryoji Mori , Takashi Nakagawa , Mamoru Kagami , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Mamoru Kagami , Akira Todo
IPC分类号： B65D1/02 , C08L23/04
CPC分类号： A61L29/041 , C08L23/10 , C08L23/142 , C08L2205/02 , C08L2207/12 , Y10T428/1397 , C08L2666/06
摘要： The invention provides a propylene polymer composition well balanced and excellent in transparency, flexibility, heat resistance, scratch resistance and rubber elasticity, and a medical tube made from the propylene polymer composition. The propylene polymer composition satisfies all the following properties (A), (B), (C) and (D): (A) the composition shows a loss tangent (tan δ) peak at a temperature in the range of −20 to 25° C. according to dynamic viscoelasticity measurement (10 rad/s) in a torsion mode, and the peak is 0.5 or above; (B) the storage elastic modulus G′ at 20° C. from the dynamic viscoelasticity measurement is in the range of 1.0×107 to 4.9×108 dyn/cm2; (C) the penetration temperature (° C.) determined in accordance with JIS K 7196 is in the range of 60 to 160° C.; and (D) the composition has a permanent set of not more than 30% as determined after the composition fixed between chucks 30 mm apart is 100% strained at a stress rate of 30 mm/min, maintained for 10 minutes and released for 10 minutes. The medical tube is made from the propylene polymer composition.
摘要翻译：本发明提供了一种丙烯聚合物组合物，其透明性，柔韧性，耐热性，耐刮擦性和橡胶弹性优良的平衡性以及由丙烯聚合物组合物制成的医用管。丙烯聚合物组合物满足以下所有性质（A），（B），（C）和（D）：（A）组合物在-20至25℃的温度范围内显示损耗角正切（tanδ）峰根据动态粘弹性测量（10rad / s）在扭转模式下，峰值为0.5或更高; （B）来自动态粘弹性测量的20℃下的储能弹性模量G'在1.0×10 -7至4.9×10 8 dyn / cm 2的范围内 > 2 ; （C）根据JIS K 7196测定的穿透温度（℃）为60〜160℃的范围。和（D）组合物具有不超过30％的永久变形，如在固定在30mm间距的卡盘之间的组合物以30mm / min的应力速率100％应变之后确定的，保持10分钟并释放10分钟。医用管由丙烯聚合物组合物制成。

3. 发明申请

US20060052543A1 Syndiotactic propylene polymer composition 有权
标题翻译：间规丙烯聚合物组合物
公开(公告)号：US20060052543A1
公开(公告)日：2006-03-09
申请号：US10542240
申请日：2004-02-03
申请人： Ryoji Mori , Takashi Nakagawa , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Akira Todo
IPC分类号： C08L23/04
CPC分类号： C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2207/12 , C08L2666/06
摘要： A syndiotactic propylene-based polymer composition which retains the inherent features of the conventional non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer, and also has excellent abrasion resistance and flexibility. The syndiotactic propylene-based polymer composition comprises 1 to 40 parts by weight of the syndiotactic polypropylene (B), and 5 to 60 parts by weight of the syndiotactic structured propylene-α-olefin copolymer (C) comprising 95 to 65 mol % of a syndiotactic structured propylene component and 5 to 35 mol % of an α-olefin (except propylene) component having 2 to 20 carbon atoms, based on 100 parts by weight of the non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer (A).
摘要翻译：保持常规非交联或部分交联的烯烃基热塑性弹性体的固有特征的间同立构丙烯基聚合物组合物，并且还具有优异的耐磨性和柔性。间规丙烯类聚合物组合物包含1〜40重量份的间同立构聚丙烯（B）和5〜60重量份的间同立构结构的丙烯-α-烯烃共聚物（C），其含有95〜65摩尔％间同立构结构丙烯成分和5〜35摩尔％的碳原子数为2〜20的α-烯烃（丙烯除外）成分，相对于100重量份的非交联或部分交联的烯烃类热塑性弹性体（A）。

4. 发明授权

US07253234B2 Syndiotactic propylene polymer composition 有权
标题翻译：间规丙烯聚合物组合物
公开(公告)号：US07253234B2
公开(公告)日：2007-08-07
申请号：US10542240
申请日：2004-02-03
申请人： Ryoji Mori , Takashi Nakagawa , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Akira Todo
IPC分类号： C08L23/10
CPC分类号： C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2207/12 , C08L2666/06
摘要： A syndiotactic propylene-based polymer composition which retains the inherent features of the conventional non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer, and also has excellent abrasion resistance and flexibility.The syndiotactic propylene-based polymer composition comprises 1 to 40 parts by weight of the syndiotactic polypropylene (B), and 5 to 60 parts by weight of the syndiotactic structured propylene-α-olefin copolymer (C) comprising 95 to 65 mol % of a syndiotactic structured propylene component and 5 to 35 mol % of an α-olefin (except propylene) component having 2 to 20 carbon atoms, based on 100 parts by weight of the non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer (A).
摘要翻译：保持常规非交联或部分交联的烯烃基热塑性弹性体的固有特征的间同立构丙烯基聚合物组合物，并且还具有优异的耐磨性和柔软性。间规丙烯类聚合物组合物包含1〜40重量份的间同立构聚丙烯（B）和5〜60重量份的间同立构结构的丙烯-α-烯烃共聚物（C），其含有95〜65摩尔％间同立构结构丙烯成分和5〜35摩尔％的碳原子数为2〜20的α-烯烃（丙烯除外）成分，相对于100重量份的非交联或部分交联的烯烃类热塑性弹性体（A）。

5. 发明授权

US07388051B2 Propylene polymer composition and use thereof 有权
标题翻译：丙烯聚合物组合物及其用途
公开(公告)号：US07388051B2
公开(公告)日：2008-06-17
申请号：US10543360
申请日：2004-01-16
申请人： Ryoji Mori , Takashi Nakagawa , Mamoru Kagami , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Mamoru Kagami , Akira Todo
IPC分类号： C08L23/10 , C08L23/02
CPC分类号： A61L29/041 , C08L23/10 , C08L23/142 , C08L2205/02 , C08L2207/12 , Y10T428/1397 , C08L2666/06
摘要： The invention provides a propylene polymer composition well balanced and excellent in transparency, flexibility, heat resistance, scratch resistance and rubber elasticity, and a medical tube made from the propylene polymer composition. The propylene polymer composition satisfies all the following properties (A), (B), (C) and (D): (A) the composition shows a loss tangent (tan δ) peak at a temperature in the range of −20 to 25° C. according to dynamic viscoelasticity measurement (10 rad/s) in a torsion mode, and the peak is 0.5 or above; (B) the storage elastic modulus G′ at 20° C. from the dynamic viscoelasticity measurement is in the range of 1.0×107 to 4.9×108 dyn/cm2; (C) the penetration temperature (° C.) determined in accordance with JIS K 7196 is in the range of 60 to 160° C.; and (D) the composition has a permanent set of not more than 30% as determined after the composition fixed between chucks 30 mm apart is 100% strained at a stress rate of 30 mm/min, maintained for 10 minutes and released for 10 minutes. The medical tube is made from the propylene polymer composition.
摘要翻译：本发明提供了一种丙烯聚合物组合物，其透明性，柔韧性，耐热性，耐刮擦性和橡胶弹性优良的平衡性以及由丙烯聚合物组合物制成的医用管。丙烯聚合物组合物满足以下所有性质（A），（B），（C）和（D）：（A）组合物在-20至25℃的温度范围内显示损耗角正切（tanδ）峰根据动态粘弹性测量（10rad / s）在扭转模式下，峰值为0.5或更高; （B）来自动态粘弹性测量的20℃下的储能弹性模量G'在1.0×10 -7至4.9×10 8 dyn / cm 2的范围内 > 2 ; （C）根据JIS K 7196测定的穿透温度（℃）为60〜160℃的范围。和（D）组合物具有不超过30％的永久变形，如在固定在30mm间距的卡盘之间的组合物以30mm / min的应力速率100％应变之后确定的，保持10分钟并释放10分钟。医用管由丙烯聚合物组合物制成。

6. 发明申请

US20060247381A1 Propylene polymer compsotions and uses thereof 有权
标题翻译：丙烯聚合物组合物及其用途
公开(公告)号：US20060247381A1
公开(公告)日：2006-11-02
申请号：US10558076
申请日：2004-05-12
申请人： Ryoji Mori , Takashi Nakagawa , Akira Todo
发明人： Ryoji Mori , Takashi Nakagawa , Akira Todo
IPC分类号： C08L23/04
CPC分类号： C08L23/10 , C08L23/14 , C08L2205/02 , C08L2666/06
摘要： The present invention provides a propylene polymer composition having excellent transparency, flexibility, heat resistance, scratch resistance and rubber elasticity with a good balance. The propylene polymer composition comprises 1 to 40 parts by weight of isotactic polypropylene (i) and 60 to 99 parts by weight of a propylene/ethylene/α-olefin copolymer (ii) which contains 45 to 89% by mol of a propylene component, 10 to 25% by mol of an ethylene component, and optionally, 0 to 30% by mol of constituent units (a) derived from an α-olefin of 4 to 20 carbon atoms.
摘要翻译：本发明提供一种丙烯聚合物组合物，其具有优异的透明性，柔软性，耐热性，耐刮擦性和橡胶弹性，并具有良好的平衡性。丙烯聚合物组合物包含1至40重量份的全同立构聚丙烯（i）和60至99重量份的含有45至89摩尔％的丙烯组分的丙烯/乙烯/α-烯烃共聚物（ii） 10〜25摩尔％的乙烯成分，以及任选的0〜30摩尔％的来自碳原子数4〜20的α-烯烃的构成单元（a）。

7. 发明申请

US20070172683A1 Olefinic thermoplastic elastomer laminate 有权
标题翻译：烯烃热塑弹性体层压板
公开(公告)号：US20070172683A1
公开(公告)日：2007-07-26
申请号：US10581344
申请日：2004-10-29
申请人： Yuichi Ito , Ryoji Mori , Takashi Nakagawa , Masakazu Jitsukata
发明人： Yuichi Ito , Ryoji Mori , Takashi Nakagawa , Masakazu Jitsukata
IPC分类号： B32B27/08 , B32B27/32
CPC分类号： C08L23/0815 , B32B1/00 , B32B7/02 , B32B25/08 , B32B27/08 , B32B27/32 , B32B27/327 , B32B2250/242 , B32B2274/00 , B32B2307/306 , B32B2307/554 , B32B2307/558 , B32B2509/00 , B32B2605/08 , C08F10/00 , C08L23/083 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/145 , C08L23/16 , C08L53/00 , C08L2205/02 , C08L2205/03 , C08L2207/12 , C08L2312/00 , C08L2314/06 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938 , C08L2666/06 , C08L2666/02 , C08L2666/08 , C08L2666/04
摘要： The present invention proposes a molded product having excellent moldability and ability to be processed into parts, as well as excellent scratch resistance. The invention provides a multilayered laminate composed of two or more layers, having a structure in which a layer (I) comprising at least one selected from an olefinic thermoplastic elastomer composition (A) and an olefinic resin (B), and a layer (II) comprising an olefinic thermoplastic elastomer composition (C) are laminated. The olefinic thermoplastic elastomer composition (C) is a composition comprising [1] a specific syndiotactic polypropylene copolymer (c), and [2] at least one selected from a polypropylene resin (d) and an olefinic thermoplastic elastomer (e).
摘要翻译：本发明提出了具有优异的成型性和加工成部件的能力以及优异的耐擦伤性的成型体。本发明提供一种由两层或多层组成的多层叠层，其具有其中包含选自烯烃类热塑性弹性体组合物（A）和烯烃树脂（B）中的至少一种的层（I）和层（II））包含烯烃类热塑性弹性体组合物（C）。烯烃类热塑性弹性体组合物（C）是包含[1]特定的间同立构聚丙烯共聚物（c）和[2]选自聚丙烯树脂（d）和烯烃类热塑性弹性体（e）中的至少一种的组合物。

8. 发明授权

US07847040B2 α-olefin-based polymer composition, molded product formed from the composition, and novel polymer 有权
标题翻译：基于α-烯烃的聚合物组合物，由该组合物形成的模塑产品和新型聚合物
公开(公告)号：US07847040B2
公开(公告)日：2010-12-07
申请号：US11578972
申请日：2005-04-08
申请人： Ryoji Mori , Takashi Nakagawa , Shigenobu Ikenaga , Hiromasa Marubayashi , Masahiko Okamoto , Yasushi Tohi , Kouji Nagahashi
发明人： Ryoji Mori , Takashi Nakagawa , Shigenobu Ikenaga , Hiromasa Marubayashi , Masahiko Okamoto , Yasushi Tohi , Kouji Nagahashi
IPC分类号： C08F4/48
CPC分类号： C08F210/06 , C08L23/10 , C08L23/142 , C08L2666/06
摘要： A composition having excellent transparency, flexibility, rubber elasticity, thermal resistance, impact resistance, abrasion resistance and the like, a composition having excellent rigidity and impact resistance as well as excellently balanced in whitening resistance, abrasion resistance and heat sealability, and a composition having excellent rubbery properties, thermal resistance, abrasion resistance and flexibility are provided.A composition comprising a specific propylene•α-olefin copolymer for which, in a signal chart measured by 13C-NMR and predetermined such that the peak present at the highest magnetic field among the signals originating from CH (methine) of the constituent unit derived from an α-olefin having 4 to 20 carbon atoms is to be at 34.4 ppm, an absorption intensity A at about 22.0 to 20.9 ppm and an absorption intensity B at about 19.0 to 20.6 ppm satisfy the following relational expressions (i) and (ii) with respect to an absorption intensity C at about 19.0 to 22.0 ppm, which is assignable to propylene methyl: (A/C)×100≦8 (i), and (B/C)×100≧60 (ii), a molded product thereof, and the α-olefin-based copolymer are provided.
摘要翻译：具有优异的透明性，柔软性，橡胶弹性，耐热性，耐冲击性，耐磨性等的组合物，具有优异的刚性和耐冲击性以及优异的耐白度，耐磨性和热封性均衡的组合物和具有提供优异的橡胶性能，耐热性，耐磨性和柔韧性。一种包含特定丙烯-α-烯烃共聚物的组合物，其以13 C-NMR测量的信号图表示，并且预先确定来自源自该构成单元的CH（次甲基）的CH（次甲基）的信号中的最高磁场存在的峰具有4至20个碳原子的α-烯烃应为34.4ppm，约22.0至20.9ppm的吸收强度A和约19.0至20.6ppm的吸收强度B满足以下关系式（i）和（ii）（A / C）×100＆nlE; 8（i）和（B / C）×100≥60（ii））中的约19.0〜22.0ppm的吸收强度C，其产物和α-烯烃基共聚物。

9. 发明授权

US09382356B2 Catalyst for olefin polymerization, method for producing olefin polymer, method for producing propylene-based copolymer, propylene polymer, propylene-based polymer composition, and use of those 有权
标题翻译：用于烯烃聚合的催化剂，烯烃聚合物的制备方法，丙烯类共聚物的制造方法，丙烯类聚合物，丙烯类聚合物组合物，以及这些
公开(公告)号：US09382356B2
公开(公告)日：2016-07-05
申请号：US11984440
申请日：2007-11-16
申请人： Yasushi Tohi , Masahiko Okamoto , Ryoji Mori , Tatsuya Nakamura , Takashi Yukita , Takashi Nakagawa , Miyuki Konno , Yuichi Yamamura , Shiegenobu Ikenaga , Mayumi Hiwara , Naritoshi Hirota , Hiromasa Marubayashi , Kouji Nagahashi , Shiro Otsuzuki , Tomohiro Yamaguchi , Masashi Higuchi , Yasuo Ichiki , Takayuki Kajihara
发明人： Yasushi Tohi , Masahiko Okamoto , Ryoji Mori , Tatsuya Nakamura , Takashi Yukita , Takashi Nakagawa , Miyuki Konno , Yuichi Yamamura , Shiegenobu Ikenaga , Mayumi Hiwara , Naritoshi Hirota , Hiromasa Marubayashi , Kouji Nagahashi , Shiro Otsuzuki , Tomohiro Yamaguchi , Masashi Higuchi , Yasuo Ichiki , Takayuki Kajihara
IPC分类号： C08F210/06 , C08F10/00 , C08J5/18 , C08L23/14 , C08F4/659
CPC分类号： C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F2420/00 , C08F2500/01 , C08F2500/03 , C08F2500/11 , C08F2500/16 , C08F2500/17 , C08F2800/10 , C08J5/18 , C08J2323/10 , C08L23/14 , C08L23/142 , C08L2203/00 , C08L2203/16 , C08L2205/025 , C08L2205/03 , C08L2207/04 , C08L2207/12 , C08L2314/06 , Y10T428/1397 , C08F4/65927 , C08F210/16 , C08F210/08 , C08F2500/12 , C08F2500/20 , C08F2500/26 , C08L23/0815
摘要： A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R1, R2, R3, R4, R5, R8, R9, and R12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R6, R7, R10, and R11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R13 and R14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1 to 4.
摘要翻译：一种用于烯烃聚合的催化剂，包括：（A-1）由下式[1-1]表示的桥连金属茂化合物和（b）至少一种选自：（b-1）有机铝氧化合物，（ b-2）形成离子对的化合物和（b-3）有机铝化合物：其中在式[1-1]中，各自选择R1，R2，R3，R4，R5，R8，R9和R12 从氢，烃基和含硅基团; R6，R7，R10和R11的四个基团不是氢原子，并且各自选自烃基或含硅基团; R 13和R 14各自为烃基等，不包括氢原子和甲基; M是Ti，Zr等; Y是碳等; Q是卤素等; j为1〜4的整数。

10. 发明授权

US08802779B2 Propylene-based polymer composition, use thereof, and method for producing thermoplastic polymer composition 有权
标题翻译：丙烯系聚合物组合物，其用途，热塑性聚合物组合物的制造方法
公开(公告)号：US08802779B2
公开(公告)日：2014-08-12
申请号：US11643944
申请日：2006-12-22
申请人： Masahiko Okamoto , Ryoji Mori , Takashi Nakagawa , Hiromasa Marubayashi , Shigenobu Ikenaga , Yasushi Tohi , Kouji Nagahashi
发明人： Masahiko Okamoto , Ryoji Mori , Takashi Nakagawa , Hiromasa Marubayashi , Shigenobu Ikenaga , Yasushi Tohi , Kouji Nagahashi
IPC分类号： C08L23/00 , C08L23/04
CPC分类号： C08L23/10 , C08L23/142 , C08L2666/06
摘要： The propylene-based polymer composition of the present invention includes 41 to 95 parts by weight of a propylene-based polymer (A) having a Tm measured by DSC of not less than 120° C. and not more than 170° C., and 59 to 5 parts by weight (provided that the total of (A) and (B) is 100 parts by weight) of a propylene/ethylene/α-olefin copolymer (B) that contains 84.0 to 60.0 mol % of constitutional units derived from propylene, 15.0 to 30.0 mol % of constitutional units derived from ethylene, and 1.0 to 10.0 mol % of constitutional units derived from an α-olefin having 4 to 20 carbon atoms and has a B-value of not less than 0.9 and not more than 1.5. This polymer composition is excellent in transparency, low-temperature impact resistance, and mechanical properties (flexibility or rigidity, etc.) and also excellent in heat resistance.
摘要翻译：本发明的丙烯类聚合物组合物包含41〜95重量份的通过DSC测定的Tm为120℃以上且170℃以下的丙烯系聚合物（A）， 59〜5重量份（式（A）和（B）为100重量份）的丙烯/乙烯/α-烯烃共聚物（B）的含量为84.0〜60.0摩尔％丙烯，来自乙烯的结构单元为15.0〜30.0摩尔％，来自碳原子数4〜20的α-烯烃的结构单元为1.0〜10.0摩尔％，B值为0.9以上且不大于 1.5。该聚合物组合物的透明性，耐低温冲击性，机械特性（柔软性，刚性等）优异，耐热性优异。

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