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    • 1. 发明授权
    • Thermoplastic polyetherimide ester polymers exhibiting improved flexular
properties
    • 具有改善的挠曲性能的热塑性聚醚酰亚胺酯聚合物
    • US4740565A
    • 1988-04-26
    • US936694
    • 1986-12-02
    • Russell J. McCreadyJohn A. Tyrell
    • Russell J. McCreadyJohn A. Tyrell
    • C08G73/10C08G63/685C08G73/14C08G73/16C08G8/00
    • C08G73/16
    • A thermoplastic polyetherimide ester polymer comprising the reaction products of:(i) a diol component comprised of at least one low molecular weight diol and at least one high molecular weight hydroxy terminated polylactone;(ii) at least one dicarboxylic acid or an ester forming reactive derivative thereof; and(a) (1) at least one high molecular weight poly(oxy alkylene)diamine, and (2) at least one tricarboxylic acid or its derivative, or(b) at least one high molecular weight polyoxyalkylene diimide diacid.These polymers exhibit improved flexibility, i.e., a low flexural modulus. The diol component contains an amount of high molecular weight hydroxy terminated polylactone at least effective to improve the flexibility of the polymer.
    • 包括以下反应产物的热塑性聚醚酰亚胺酯聚合物:(i)由至少一种低分子量二醇和至少一种高分子量羟基封端的聚内酯组成的二醇组分; (ii)至少一种二羧酸或其形成酯的反应性衍生物; 和(a)(1)至少一种高分子量聚(氧亚烷基)二胺,和(2)至少一种三羧酸或其衍生物,或(b)至少一种高分子量聚亚氧烷基二酰亚胺二酸。 这些聚合物表现出改进的柔性,即低弯曲模量。 二醇组分含有一定量的高分子量羟基封端的聚内酯,其至少有效地改善了聚合物的柔韧性。
    • 5. 发明授权
    • Thermoplastic polyetherimide ester elastomers exhibiting improved
hydrolytic stability
    • 表现出改善的水解稳定性的热塑性聚醚酰亚胺酯弹性体
    • US4714753A
    • 1987-12-22
    • US936529
    • 1986-12-01
    • Russell J. McCreadyJohn A. Tyrell
    • Russell J. McCreadyJohn A. Tyrell
    • C08G73/10C08G73/16C08G63/18
    • C08G73/16
    • Polyetherimide ester compositions exhibiting improved hydrolytic stability are provided. These polymers are comprised of the reaction products of:(i) at least one diol;(ii) at least one dicarboxylic acid or an ester forming reactive derivative thereof; and(iii) a set of reactants selected from either(a) (i) an amount at least effective to improve the hydrolytic stability of said composition of at least one high molecular weight bisaminoalkyl polytetrahydrofuran, and (ii) at least one tricarboxylic acid or derivative thereof, or(b) an amount at least effective to improve the hydrolytic stability of said composition of at least one polyoxytetramethylene dialkylenediimide diacid, said polyoxytetramethylene dialkylenediimide diacid being the reaction product of (iii)(a)(i) and (iii)(a)(ii).The polymers of the instant invention are useful for production of extruded and molded parts requiring improved hydrolytic stability.
    • 提供了表现出改进的水解稳定性的聚醚酰亚胺酯组合物。 这些聚合物由以下反应产物组成:(i)至少一种二醇; (ii)至少一种二羧酸或其形成酯的反应性衍生物; (iii)一组反应物,其选自(a)(i)至少有效改善所述组合物至少一种高分子量双氨基烷基聚四氢呋喃的水解稳定性的量,和(ii)至少一种三羧酸或 衍生物,或(b)至少有效提高所述组合物至少一种聚氧四亚甲基二亚乙基二酰亚胺二酸的水解稳定性的量,所述聚氧四亚甲基二亚烷基二酰亚胺二酸是(iii)(a)(i)和(iii)的反应产物, (a)(ii)。 本发明的聚合物可用于生产需要改进的水解稳定性的挤出和模制部件。
    • 6. 发明授权
    • Polyetherimide esters
    • 聚醚酰亚胺酯
    • US4711933A
    • 1987-12-08
    • US928954
    • 1986-11-10
    • Russell J. McCreadyJohn A. Tyrell
    • Russell J. McCreadyJohn A. Tyrell
    • C08G73/16C08G63/76
    • C08G73/16
    • Polyetherimide ester compositions comprising the reaction products of:(i) a mixture of at least one low molecular weight diol and at least one high molecular weight hydroxy terminated polylactone; and(ii) a set of reactants selected from(a) (i) at least one high molecular weight poly(oxy alkylene)diamine, and (ii) at least one tricarboxylic acid or a derivative thereof, or(b) at least one high molecular weight polyoxyalkylene diimide diacid.Also polyetherimide ester compositions comprising the reaction products of:(i) at least one high molecular weight hydroxy terminated polylactone; and(ii) a set of reactants selected from(a) (i) at least one high molecular weight poly(oxy alkylene)diamine, and (ii) at least one tricarboxylic acid or a derivative thereof, or(b) at least one high molecular weight polyoxyalkylene diimide diacid.
    • 包括以下反应产物的聚醚酰亚胺酯组合物:(i)至少一种低分子量二醇和至少一种高分子量羟基封端的聚内酯的混合物; 和(ii)选自(a)(i)至少一种高分子量聚(氧亚烷基)二胺和(ii)至少一种三羧酸或其衍生物的一组反应物,或(b)至少一种 高分子量聚氧化烯二酰亚胺二酸。 还包括以下反应产物的聚醚酰亚胺酯组合物:(i)至少一种高分子量羟基封端的聚内酯; 和(ii)选自(a)(i)至少一种高分子量聚(氧亚烷基)二胺和(ii)至少一种三羧酸或其衍生物的一组反应物,或(b)至少一种 高分子量聚氧化烯二酰亚胺二酸。
    • 8. 发明授权
    • Solid phase polycondensation process for the production of high
molecular weight polyetherimide ester polymers
    • 用于生产高分子量聚醚酰亚胺酯聚合物的固相缩聚方法
    • US4732948A
    • 1988-03-22
    • US936698
    • 1986-12-02
    • Russell J. McCreadyJohn A. Tyrell
    • Russell J. McCreadyJohn A. Tyrell
    • C08G73/16C08G8/00
    • C08G73/16
    • A method for preparing high molecular weight polyetherimide ester polymers comprising:(A) preparing a polyetherimide ester oligomer by coreacting(i) at least one diol,(ii) at least one dicarboxylic acid or an ester forming reactive derivative thereof, and(iii) a set of reactants selected from(a) (1) at least one high molecular weight poly(oxy alkylene)diamine, and (2) at least one tricarboxylic acid or a derivative thereof, or(b) at least one high molecular weight polyoxyalkylene diimide diacid, at elevated temperature and for a period of time effective to form said oligomer; and then(B) further polymerizing said oligomer by a solid phase polycondensation procedure comprising heating said oligomer at a temperature effective to further polymerize said oligomer to a high molecular weight polyetherimide ester polymer but below the melting point of said oligomer.The instant process is useful for forming high molecular weight polyetherimide ester polymers suitable for production of extruded and molded articles.
    • 一种制备高分子量聚醚酰亚胺酯聚合物的方法,包括:(A)通过(i)至少一种二醇,(ii)至少一种二羧酸或其形成酯的反应性衍生物,制备聚醚酰亚胺酯低聚物,和(iii) 一组选自(a)(1)至少一种高分子量聚(氧亚烷基)二胺的反应物,和(2)至少一种三羧酸或其衍生物,或(b)至少一种高分子量聚氧化烯 二酰亚胺二酸在升高的温度下和有效形成所述低聚物的时间段; 然后(B)通过固相缩聚方法进一步聚合所述低聚物,包括在有效使所述低聚物进一步聚合到高分子量聚醚酰亚胺酯聚合物但低于所述低聚物熔点的温度下加热所述低聚物。 该方法可用于形成适于生产挤出和模塑制品的高分子量聚醚酰亚胺酯聚合物。
    • 9. 发明授权
    • Polyetherimide esters
    • 聚醚酰亚胺酯
    • US4714754A
    • 1987-12-22
    • US929041
    • 1986-11-10
    • Russell J. McCreadyJohn A. Tyrell
    • Russell J. McCreadyJohn A. Tyrell
    • C08G73/16C08G63/44C08G69/00C08G69/44
    • C08G73/16
    • A polyetherimide ester composition comprising the reaction products of:(i) a mixture of at least one high molecular weight diol and at least one low molecular weight diol; and(ii) a set of reactants selected from(a) (i) at least one high molecular weight poly(oxy alkylene)diamine, and (ii) at least one tricarboxylic acid or a derivative thereof, or(b) at least one high molecular weight polyoxyalkylene diimide diacid.Also a polyetherimide ester composition comprising the reaction products of:(i) at least one high molecular weight diol; and(ii) a set of reactants selected from(a) (i) at least one high molecular weight poly(oxy alkylene)diamine, and (ii) at least one tricarboxylic acid or a derivative thereof, or(b) at least one high molecular weight polyoxyalkylene diimide diacid.
    • 一种聚醚酰亚胺酯组合物,其包含以下反应产物:(i)至少一种高分子量二醇和至少一种低分子量二醇的混合物; 和(ii)选自(a)(i)至少一种高分子量聚(氧亚烷基)二胺和(ii)至少一种三羧酸或其衍生物的一组反应物,或(b)至少一种 高分子量聚氧化烯二酰亚胺二酸。 还包括聚醚酰亚胺酯组合物,其包含以下反应产物:(i)至少一种高分子量二醇; 和(ii)选自(a)(i)至少一种高分子量聚(氧亚烷基)二胺和(ii)至少一种三羧酸或其衍生物的一组反应物,或(b)至少一种 高分子量聚氧化烯二酰亚胺二酸。