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    • 3. 发明申请
    • Paint Compositions, a Method of Paint Finishing and Painted Objects
    • 油漆组合物,油漆整理和涂漆物体的方法
    • US20090001331A1
    • 2009-01-01
    • US12095369
    • 2006-11-10
    • Tetsu KonishiMachiko OkadaRui Niimi
    • Tetsu KonishiMachiko OkadaRui Niimi
    • F21V9/06
    • C09D133/06C08G59/42C08L33/02C08L33/06C08L63/00C09D163/00C08L2666/04C08L2666/02C08L2666/14
    • Disclosed herein is a paint composition comprising a carboxyl group containing resin comprising two or more carboxyl groups per molecule, having an acid number of from 100 to 300 mgKOH/g and a weight average molecular weight of from 2,000 to 30,000, obtained by the copolymerization of a carboxyl group containing radically polymerizable monomer and another radically polymerizable monomer, wherein the carboxyl group containing resin comprises 5 to 50 weight percent of structural units based on a lactone compound, based on resin solids; an epoxy group containing resin, comprising two or more epoxy groups per molecule; an ultraviolet absorber; and a light stabilizer having a pKb value of at least 9; wherein the molar ratio of the carboxyl groups of the carboxyl group containing resin to the epoxy groups of the epoxy group containing resin is 3:1 to 1:3.
    • 本文公开了一种涂料组合物,其包含每分子含有两个或多个羧基的含羧基的树脂,其酸值为100-300mgKOH / g,重均分子量为2,000至30,000,通过共聚 含有可自由基聚合的单体和另一种可自由基聚合的单体的羧基,其中所述含羧基的树脂基于树脂固体包含5至50重量%的基于内酯化合物的结构单元; 含有环氧基的树脂,每分子含有2个以上的环氧基; 紫外线吸收剂; 和pKb值至少为9的光稳定剂; 其中所述含羧基树脂的羧基与所述含环氧基树脂的环氧基的摩尔比为3:1至1:3。
    • 4. 发明申请
    • Hydroxyl-Containing Resin Composition for Coating Materials, Coating Composition, Coating Finishing Method, and Coated Article
    • 用于涂料的含羟基树脂组合物,涂料组合物,涂料整理方法和涂布制品
    • US20080107904A1
    • 2008-05-08
    • US11576841
    • 2005-10-05
    • Tetsu KonishiRui NiimiYuichi Shinozaki
    • Tetsu KonishiRui NiimiYuichi Shinozaki
    • B32B27/00C08G65/34
    • C08G18/6237C08F220/18C08F220/30C08G18/0823C09D175/04Y10T428/31504
    • The present invention relates to a hydroxyl-containing resin composition for a coating material, characterized in comprising a hydroxyl-containing resin that has a hydroxyl value of 50 to 400 mg KOH/g and a weight-average molecular weight of 2,000 to 100,000, and in being a resin obtained by copolymerizing, in the presence of (a) an acid compound containing one carboxyl group and two or more hydroxyl groups, (b) a radical-polymerizable monomer having an epoxy group and (c) another radical-polymerizable monomer, or a resin obtained by the addition reaction of (a) an acid compound containing one carboxyl group and two or more hydroxyl groups with a copolymer of (b) a radical-polymerizable monomer having an epoxy group and (c) another radical-polymerizable monomer. The invention also relates to a coating composition comprising the resin composition and a crosslinking agent, to a coating finishing method in which the coating composition is used, and to a coated article coated by the method.
    • 本发明涉及一种用于涂料的含羟基树脂组合物,其特征在于包含羟基值为50-400mg KOH / g,重均分子量为2,000至100,000的含羟基树脂,以及 在(a)含有一个羧基和两个或更多个羟基的酸化合物的存在下,(b)具有环氧基的可自由基聚合的单体和(c)另一种可自由基聚合的单体 或通过(a)含有一个羧基和两个或更多个羟基的酸化合物与(b)具有环氧基的可自由基聚合的单体的共聚物和(c)另一种可自由基聚合的 单体。 本发明还涉及包含树脂组合物和交联剂的涂料组合物,其中使用涂料组合物的涂料整理方法以及通过该方法涂覆的涂布制品。
    • 9. 发明申请
    • Paint Composition, a Painting and Finishing Method, and Painted Articles
    • 油漆成分,绘画和表面处理方法以及绘画文章
    • US20080177006A1
    • 2008-07-24
    • US11910671
    • 2006-04-11
    • Tetsu KonishiShinji MitsumuneMasayuki TakemotoTakehito ItoHiroyuki TagkagiRui Niimi
    • Tetsu KonishiShinji MitsumuneMasayuki TakemotoTakehito ItoHiroyuki TagkagiRui Niimi
    • C08G65/26
    • C08G18/6237C08G18/7831C09D4/06C09D175/04
    • The provision of a paint composition that affords a paint film of excellent acid rain resistance, contamination resistance, water resistance, weather resistance and painting workability, with particularly excellent resistance to vehicle wash damage; and a painting and finishing method, and painted articles. [Overcoming means] A paint composition, characterized in that it has as indispensable components (A) a hydroxyl group-containing resin that is obtained by the addition and polymerization of (a) a compound that contains one carboxyl group and does not have a radical polymerizable double bond, (b) a lactone compound, and (c) an epoxy group-containing radical polymerizable monomer, and, if necessary, (d) another radical polymerizable monomer, and which has a resin hydroxyl value of from 180 to 400 mgKOH/g and a weight average molecular weight of from 2000 to 30,000, and in which the structural unit based on the lactone compound component (b) is from 20 to 60% by mass of the resin solids content; and (B) a crosslinking agent containing per molecule at least one functional group that reacts with hydroxyl groups.
    • 提供具有优异耐酸雨性,耐污染性,耐水性,耐候性和涂漆加工性的漆膜的涂料组合物,具有特别优异的耐车辆洗涤损伤性; 和一个绘画和整理方法,并绘制文章。 [克服方法]一种涂料组合物,其特征在于,其具有通过(a)含有一个羧基并且不具有自由基的化合物的加成和聚合而获得的含羟基树脂作为不可缺少的成分(A) 可聚合双键,(b)内酯化合物和(c)含环氧基的可自由基聚合的单体,如果需要,(d)另一种可自由基聚合的单体,其树脂羟值为180-400mgKOH / g,重均分子量为2000〜30,000,其中基于内酯化合物成分(b)的结构单元的树脂固含量为20〜60质量% 和(B)每分子含有至少一个与羟基反应的官能团的交联剂。