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1. 发明申请

US20100000407A1 PROCESS FOR REMOVAL OF HYDROGEN SULPHIDE, IRON PENTACARBONYL AND NICKEL TETRACARBONYL FROM A SYNTHESIS GAS STREAM 有权
标题翻译：从合成气流中去除硫化氢，铁，戊二酮和镍的四氯化碳的方法
公开(公告)号：US20100000407A1
公开(公告)日：2010-01-07
申请号：US12442874
申请日：2007-09-26
申请人： Rudolf Robert Gouman , Adriaan Johannes Kodde , Cornelis Jacobus Smit
发明人： Rudolf Robert Gouman , Adriaan Johannes Kodde , Cornelis Jacobus Smit
IPC分类号： C01B3/52 , B01D53/14 , C01B3/56
CPC分类号： B01D53/1462 , B01D53/02 , B01D2253/102 , B01D2257/706 , C01B3/52 , C01B3/56 , C01B2203/0415 , C01B2203/042 , C01B2203/0485 , C01B2203/146 , Y02P20/152
摘要： The invention provides a process for removal of hydrogen sulphide, iron pentacarbonyl and nickel tetracarbonyl from a feed synthesis gas stream, the process comprising the steps of: (a) removal of hydrogen sulphide and of iron pentacarbonyl by contacting the feed synthesis gas stream with an absorbing liquid comprising water, physical solvent and an amine, to obtain a synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl; (b) adsorption of nickel tetracarbonyl by contacting the synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl with solid adsorbent comprising activated carbon to obtain solid adsorbent enriched in nickel tetracarbonyl and a purified synthesis gas stream.
摘要翻译：本发明提供了一种从进料合成气流中除去硫化氢，五羰基铁和四羰基铁的方法，该方法包括以下步骤：（a）通过使原料合成气流与包含水，物理溶剂和胺的吸收液体，以获得贫硫化氢和贫铁铁五羰基的合成气流; （b）通过使耗尽硫化氢的合成气流和五羰基铁的贫铁与包含活性炭的固体吸附剂接触来吸附四羰基镍，以获得富含四羰基镍的固体吸附剂和纯化的合成气流。

2. 发明授权

US07918922B2 Process for removal of hydrogen sulphide, iron pentacarbonyl and nickel tetracarbonyl from a synthesis gas stream 有权
标题翻译：从合成气流中除去硫化氢，五羰基铁和四羰基镍的方法
公开(公告)号：US07918922B2
公开(公告)日：2011-04-05
申请号：US12442874
申请日：2007-09-26
申请人： Rudolf Robert Gouman , Adriaan Johannes Kodde , Cornelis Jacobus Smit
发明人： Rudolf Robert Gouman , Adriaan Johannes Kodde , Cornelis Jacobus Smit
IPC分类号： B01D53/04 , B01D53/14
CPC分类号： B01D53/1462 , B01D53/02 , B01D2253/102 , B01D2257/706 , C01B3/52 , C01B3/56 , C01B2203/0415 , C01B2203/042 , C01B2203/0485 , C01B2203/146 , Y02P20/152
摘要： The invention provides a process for removal of hydrogen sulphide, iron pentacarbonyl and nickel tetracarbonyl from a feed synthesis gas stream, the process comprising the steps of: (a) removal of hydrogen sulphide and of iron pentacarbonyl by contacting the feed synthesis gas stream with an absorbing liquid comprising water, physical solvent and an amine, to obtain a synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl; (b) adsorption of nickel tetracarbonyl by contacting the synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl with solid adsorbent comprising activated carbon to obtain solid adsorbent enriched in nickel tetracarbonyl and a purified synthesis gas stream.
摘要翻译：本发明提供了一种从进料合成气流中除去硫化氢，五羰基铁和四羰基铁的方法，该方法包括以下步骤：（a）通过将原料合成气流与包含水，物理溶剂和胺的吸收液体，以获得贫硫化氢和贫铁铁五羰基的合成气流; （b）通过使耗尽硫化氢的合成气流和五羰基铁的贫铁与包含活性炭的固体吸附剂接触来吸附四羰基镍，以获得富含四羰基镍的固体吸附剂和纯化的合成气流。

3. 发明申请

US20080242749A1 Process For the Removal of Cos From a Synthesis Gas Stream Comprising H2S and Cos 有权
标题翻译：用于从包含H 2 S和Cos的合成气流中除去Cos的方法
公开(公告)号：US20080242749A1
公开(公告)日：2008-10-02
申请号：US11632883
申请日：2005-07-22
申请人： Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
发明人： Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
IPC分类号： C07C29/74
CPC分类号： B01D53/8606 , B01D53/04 , B01D2253/112 , B01D2255/20707 , B01D2255/30 , B01D2256/00 , B01D2257/306 , C01B3/54 , C01B3/56 , C01B2203/042 , C01B2203/0435 , C01B2203/0485
摘要： The invention provides a process for the removal of COS from a first synthesis gas stream comprising COS and H2S, the process having the steps of: (a) converting COS in the first synthesis gas stream to H2S by contacting the first synthesis gas stream with a COS-hydrolysing catalyst in the presence of water in a hydrolysis zone to obtain a second synthesis gas stream depleted of COS and enriched in H2S; (b) removing H2S from the second synthesis gas stream by contacting the second synthesis gas stream with a solid adsorbent in a H2S removal zone to obtain a third synthesis gas stream depleted of H2S and depleted of COS
摘要翻译：本发明提供了从包含COS和H 2 S的第一合成气流中除去COS的方法，该方法具有以下步骤：（a）将第一合成气流中的COS转化为H 通过在水解区中在水的存在下使第一合成气流与COS-水解催化剂接触以获得消耗COS并富集H 2的第二合成气流， / SUB> S; （b）通过使第二合成气流与H 2 S 2去除区中的固体吸附剂接触，从第二合成气流中除去H 2 S，得到第三合成物耗尽H 2 S且耗尽COS的气流

4. 发明授权

US07846325B2 Process for the removal of COS and H2S from a synthesis gas stream comprising H2S and COS 有权
标题翻译：从包含H 2 S和COS的合成气流中除去COS和H 2 S的方法
公开(公告)号：US07846325B2
公开(公告)日：2010-12-07
申请号：US11632883
申请日：2005-07-22
申请人： Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
发明人： Robert Martijn Van Hardeveld , Rudolf Henri Max Herold , Adriaan Johannes Kodde , Thijme Last , Cornelis Jacobus Smit
IPC分类号： C01D17/00 , B01D53/86 , C07C27/00
CPC分类号： B01D53/8606 , B01D53/04 , B01D2253/112 , B01D2255/20707 , B01D2255/30 , B01D2256/00 , B01D2257/306 , C01B3/54 , C01B3/56 , C01B2203/042 , C01B2203/0435 , C01B2203/0485
摘要： The invention provides a process for the removal of COS and H2S from a synthesis gas stream comprising COS and H2S, the process having the steps of: removing H2S from a feed synthesis gas stream with a first solid adsorbent to obtain a first synthesis gas stream, converting COS in the first synthesis gas stream to H2S by contacting the first synthesis gas stream with a COS-hydrolysing catalyst in the presence of water in a hydrolysis zone to obtain a second synthesis gas stream depleted of COS and enriched in H2S; and removing H2S from the second synthesis gas stream by contacting the second synthesis gas stream with a second solid adsorbent in a H2S removal zone to obtain a third synthesis gas stream depleted of H2S and depleted of COS to very low levels.
摘要翻译：本发明提供了从包含COS和H 2 S的合成气流中除去COS和H 2 S的方法，该方法具有以下步骤：用第一固体吸附剂从原料合成气流除去H 2 S，得到第一合成气流，通过在水解区中在水的存在下使第一合成气流与COS-水解催化剂接触将第一合成气流中的COS转化为H 2 S，得到耗尽COS并富集H 2 S的第二合成气流; 以及通过在H 2 S去除区中使第二合成气流与第二固体吸附剂接触来从第二合成气流中除去H 2 S，以获得耗尽H 2 S并耗尽COS的第三合成气流至非常低的水平。

5. 发明申请

US20100139317A1 METHOD OF COOLING A HYDROCARBON STREAM AND AN APPARATUS THEREFOR 审中-公开
标题翻译：冷却油气流及其装置的方法
公开(公告)号：US20100139317A1
公开(公告)日：2010-06-10
申请号：US12630560
申请日：2009-12-03
申请人： Francois Chantant , Adriaan Johannes Kodde , Alexandre M C R Santos
发明人： Francois Chantant , Adriaan Johannes Kodde , Alexandre M C R Santos
IPC分类号： F25J3/00 , F02C3/20 , F02C6/00
CPC分类号： F25J1/0022 , C10L3/10 , F25J1/0052 , F25J1/023 , F25J1/0283 , F25J2215/62 , F25J2220/62 , F25J2220/64 , F25J2230/60 , F25J2240/80 , F25J2245/02 , F25J2245/90
摘要： A hydrocarbon feed stream is separated in one or more separators to provide a hydrocarbon stream and at least one methane-lean stream comprising a first ethane-rich header feed stream. The hydrocarbon stream is heat exchanged with at least one refrigerant stream to provide at least one cooled hydrocarbon stream and at least one at least partially evapourated refrigerant stream. The first ethane-rich header feed stream is passed to at least one fuel gas header, from which header fuel gas is removed as at least one fuel gas stream.
摘要翻译：烃进料流在一个或多个分离器中分离以提供烃流和至少一个富含甲烷的流，其包含第一富含乙烷的标题进料流。烃流与至少一个制冷剂流热交换以提供至少一个冷却的烃流和至少一个至少部分蒸发的制冷剂流。第一富含乙烷的标头进料流被传送到至少一个燃料气体集管，作为至少一个燃料气体流从其中去除集管燃料气体。

6. 发明授权

US08187365B2 Process for removal of metal carbonyls from a synthesis gas stream 失效
标题翻译：从合成气流中除去金属羰基化物的方法
公开(公告)号：US08187365B2
公开(公告)日：2012-05-29
申请号：US12442859
申请日：2007-09-26
申请人： Adriaan Johannes Kodde
发明人： Adriaan Johannes Kodde
IPC分类号： B01D53/02
CPC分类号： B01D53/04 , B01D2253/102 , B01D2253/108 , B01D2257/706 , B01D2259/4009 , B01D2259/4146 , C01B3/56 , C01B2203/042 , C01B2203/0465
摘要： The invention provides a process for removal of metal carbonyls from a synthesis gas stream comprising metal carbonyls, the process comprising the steps of: (a) adsorption of metal carbonyls by contacting the synthesis gas stream with solid adsorbent comprising activated carbon and/or hydrophobic zeolite to obtain solid adsorbent enriched in metal carbonyls and a synthesis gas stream depleted of metal carbonyls; (b) desorption of metal carbonyls by contacting the solid adsorbent enriched in metal carbonyls with CO-containing gas comprising at least 0.5 volume % CO to obtain regenerated adsorbent depleted of metal carbonyls and CO-containing gas enriched in metal carbonyls, wherein the temperature at which metal carbonyl desorption takes place is higher than the temperature at which metal carbonyl adsorption takes place.
摘要翻译：本发明提供从包含羰基金属羰基合成气流中除去金属羰基化合物的方法，该方法包括以下步骤：（a）通过使合成气流与包含活性炭和/或疏水性沸石的固体吸附剂接触来吸附羰基金属以获得富含金属羰基化合物的固体吸附剂和消耗金属羰基化合物的合成气流; （b）通过使富含金属羰基化物的固体吸附剂与包含至少0.5体积％CO的含CO气体接触以获得富含羰基金属的富含金属羰基化合物和含CO的气体的再生吸附剂，从而解吸金属羰基化物，其中，发生金属羰基解吸的程度高于发生金属羰基吸附的温度。

7. 发明申请

US20100115993A1 PROCESS FOR REMOVING MERCAPTANS FROM LIQUEFIED NATURAL GAS 审中-公开
标题翻译：从液化天然气中除去梅费尔坦的方法
公开(公告)号：US20100115993A1
公开(公告)日：2010-05-13
申请号：US12446583
申请日：2007-10-23
申请人： Anthonius Maria Demmers , Sander Kaart , Adriaan Johannes Kodde
发明人： Anthonius Maria Demmers , Sander Kaart , Adriaan Johannes Kodde
IPC分类号： F25J3/02 , B01D53/52
CPC分类号： C10L3/102 , B01D53/04 , B01D53/1487 , B01D53/75 , B01D2251/604 , B01D2253/108 , B01D2257/306 , B01D2257/308 , B01D2257/80 , B01D2258/06 , C10L3/10 , F25J3/0209 , F25J3/0233 , F25J3/0238 , F25J3/0242 , F25J2215/62 , F25J2220/60 , F25J2220/66 , F25J2245/02 , F25J2260/20 , F25J2260/60 , F25J2290/12
摘要： The invention provides a process for producing purified natural gas, the process comprising the steps of: expanding a pressurised natural gas stream comprising at least 4 ppmv of mercaptans and supplying it to a first separation column, in which the natural gas stream is separated into a gaseous overhead stream enriched in methane and a first fraction enriched in mercaptans; withdrawing the gaseous overhead stream enriched in methane from the separation column to obtain the purified natural gas; with drawing the fraction enriched in mercaptans from the separation column; removing mercaptans from the first fraction enriched in mercaptans.
摘要翻译：本发明提供了一种生产纯化天然气的方法，该方法包括以下步骤：将包含至少4ppmv硫醇的加压天然气流膨胀并将其供应到第一分离塔，其中将天然气流分离成富含甲烷的气态塔顶馏出物和富含硫醇的第一馏分; 从分离塔中取出富含甲烷的气态塔顶馏出物，得到纯化天然气; 从分离塔中抽出富含硫醇的馏分; 从富含硫醇的第一部分中除去硫醇。

8. 发明申请

US20100005965A1 PROCESS FOR REMOVAL OF METAL CARBONYLS FROM A SYNTHESIS GAS STREAM 失效
标题翻译：从合成气流中去除金属碳的方法
公开(公告)号：US20100005965A1
公开(公告)日：2010-01-14
申请号：US12442859
申请日：2007-09-26
申请人： Adriaan Johannes Kodde
发明人： Adriaan Johannes Kodde
IPC分类号： B01D53/02
CPC分类号： B01D53/04 , B01D2253/102 , B01D2253/108 , B01D2257/706 , B01D2259/4009 , B01D2259/4146 , C01B3/56 , C01B2203/042 , C01B2203/0465
摘要： The invention provides a process for removal of metal carbonyls from a synthesis gas stream comprising metal carbonyls, the process comprising the steps of: (a) adsorption of metal carbonyls by contacting the synthesis gas stream with solid adsorbent comprising activated carbon and/or hydrophobic zeolite to obtain solid adsorbent enriched in metal carbonyls and a synthesis gas stream depleted of metal carbonyls; (b) desorption of metal carbonyls by contacting the solid adsorbent enriched in metal carbonyls with CO-containing gas comprising at least 0.5 volume % CO to obtain regenerated adsorbent depleted of metal carbonyls and CO-containing gas enriched in metal carbonyls, wherein the temperature at which metal carbonyl desorption takes place is higher than the temperature at which metal carbonyl adsorption takes place.
摘要翻译：本发明提供从包含羰基金属羰基合成气流中除去金属羰基化合物的方法，该方法包括以下步骤：（a）通过使合成气流与包含活性炭和/或疏水性沸石的固体吸附剂接触来吸附羰基金属以获得富含金属羰基化合物的固体吸附剂和消耗金属羰基化合物的合成气流; （b）通过使富含金属羰基化物的固体吸附剂与包含至少0.5体积％CO的含CO气体接触以获得富含羰基金属的富含金属羰基化合物和含CO的气体的再生吸附剂，从而解吸金属羰基化物，其中，发生金属羰基解吸的程度高于发生金属羰基吸附的温度。

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