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1. 发明授权

US4777285A Preparation of alkenecarboxylates 失效
标题翻译：烯烃羧酸盐的制备
公开(公告)号：US4777285A
公开(公告)日：1988-10-11
申请号：US28135
申请日：1987-03-19
申请人： Rudolf Kummer , Uwe Vagt , Rolf Fischer , Walter Seufert , Rainer Becker
发明人： Rudolf Kummer , Uwe Vagt , Rolf Fischer , Walter Seufert , Rainer Becker
IPC分类号： C07C69/533 , C07C67/03 , C07C67/475 , C07C69/52 , C07C67/30
CPC分类号： C07C67/03
摘要： Alkenecarboxylates of the formula I ##STR1## where R.sub.1 is alkyl of 1 to 6 carbon atoms and n is 2, 3 or 4, are prepared by a process which comprises reacting a lactone of the formula II ##STR2## where R.sub.2 is hydrogen or methyl and m is 1 or 2, with an alkanol of 1 to 6 carbon atoms in the presence of an acidic catalyst at from 150.degree. to 400.degree. C.
摘要翻译：其中R 1为1至6个碳原子的烷基，n为2,3或4的式I的烯烃羧酸盐通过包括使式II的内酯与其中R 2为氢的反应制备或甲基，m为1或2，在酸性催化剂存在下，在150-400℃下加入具有1-6个碳原子的链烷醇。

2. 发明授权

US4745228A Preparation of cyclic ketones 失效
标题翻译：环酮的制备
公开(公告)号：US4745228A
公开(公告)日：1988-05-17
申请号：US65959
申请日：1987-06-24
申请人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
发明人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
IPC分类号： C07C45/48 , C07C45/00 , C07C45/51
CPC分类号： C07C45/48
摘要： Cyclic ketones of the formula ##STR1## where n is an integer from 4 to 6, are prepared by converting an aliphatic dicarboxylate of the formulaR.sup.1 OCC--(CH.sub.2).sub.n --COOR.sup.2 IIwhere n has the above meaning, R.sup.1 and R.sup.2 are each alkyl, cycloalkyl, aralkyl or aryl and R.sup.2 may furthermore be hydrogen, at from 150.degree. to 450.degree. C. over a solid oxide catalyst.
摘要翻译：通过将式R 1 OCC-（CH 2）n -COOR 2 II的脂肪族二羧酸酯转化为其中n具有上述含义，R1和R2各自为烷基，其中n为4-6的整数，其中n为4至6的整数的式，环烷基，芳烷基或芳基，R2可以为氢，在固体氧化物催化剂上为150-450℃。

3. 发明授权

US5189182A Preparation of 5-methylbutyrolactone 失效
标题翻译： 5-甲基丁酰胺的制备
公开(公告)号：US5189182A
公开(公告)日：1993-02-23
申请号：US236199
申请日：1988-08-25
申请人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.
摘要翻译：通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

4. 发明授权

US4837346A Preparation of esters of tetrahydropyran-4-carboxylic acid 失效
标题翻译：四氢吡喃-4-羧酸酯的制备
公开(公告)号：US4837346A
公开(公告)日：1989-06-06
申请号：US170768
申请日：1988-03-21
申请人： Rainer Becker , Heinz Eckhardt , Rolf Fischer , Wolfgang Spiegler , Uwe Vagt
发明人： Rainer Becker , Heinz Eckhardt , Rolf Fischer , Wolfgang Spiegler , Uwe Vagt
IPC分类号： C07D309/08
CPC分类号： C07D309/08
摘要： A process for the preparation of esters of tetrahydropyran-4-carboxylic acid of the general formula I, where R.sup.1 is an alkyl, cycloalkyl, or aryl group, by treating butyrolactones of the general formula II, where R.sup.2 is a hydrogen atom, an alkyl group, or an acyl group --CO--R.sup.3, R.sup.3 being a hydrogen atom or an alkyl group with from 1 to 6 carbon atoms, with alcohols of the general formula III at temperatures of from 150.degree. C. to 400.degree. C. in the presence of acid catalysts. ##STR1##
摘要翻译：制备通式Ⅰ的四氢吡喃-4-羧酸的酯的方法，其中R1是烷基，环烷基或芳基，通过处理通式Ⅱ的丁内酯，其中R2是氢原子，烷基基团或酰基-CO-R 3，R 3为氢原子或具有1至6个碳原子的烷基，与通式III的醇在150℃至400℃的温度下反应存在酸催化剂。

5. 发明授权

US4963672A Preparation of caprolactam 失效
标题翻译：己内酰胺的制备
公开(公告)号：US4963672A
公开(公告)日：1990-10-16
申请号：US448899
申请日：1989-12-12
申请人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
发明人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
IPC分类号： B01J23/46 , C07B61/00 , C07D201/08 , C07D201/16
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared in a process comprising the following steps:(a) reacting the 5-formylvaleric ester with liquid ammonia as reaction medium and hydrogen in the presence of a ruthenium catalyst in liquid phase at from 80.degree. to 140.degree. C. under a hydrogen partial pressure of from 40 to 100 bar,(b) replacing the reaction medium ammonia by an aromatic hydrocarbon having a boiling point of from 80.degree. to 240.degree. C. which is liquid under the reaction conditions,(c) heating the resulting mixture in liquid phase under superatmospheric pressure at 230.degree.-350.degree. C. to form caprolactam, and(d) isolating caprolactam from the resulting reaction mixture.
摘要翻译：己内酰胺以包括以下步骤的方法制备：（a）使5-甲酰基戊酸酯与液氨作为反应介质和氢在钌催化剂存在下在液相中在80-140℃下在氢气分压为40〜100巴，（b）在反应条件下用沸点为80〜240℃的芳烃替代反应介质氨，（c）将所得混合物加热液相在超大气压下在230-350℃下反应形成己内酰胺，和（d）从所得反应混合物中分离己内酰胺。

6. 发明授权

US4731445A Preparation of epsilon-caprolactam 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4731445A
公开(公告)日：1988-03-15
申请号：US007585
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： B01J23/00 , B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) the 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as the solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture,(c) the resulting reaction mixture is reacted with water at elevated temperatures with simultaneous removal of alkanols, and(d) the reaction mixture thus obtained is heated to 150.degree.-370.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在作为溶剂的链烷醇存在下和氢化催化剂存在下，在超大气压下在40℃的液相中反应（b）从反应混合物中分离出过量的氨和氢，（c）将所得的反应混合物在高温下与水反应，同时除去链烷醇，和（d）由此得到的反应混合物加热至150-370℃，得到ε-己内酰胺。

7. 发明授权

US4730041A Preparation of .epsilon.-caprolactams 失效
标题翻译： ε-己内酰胺的制备
公开(公告)号：US4730041A
公开(公告)日：1988-03-08
申请号：US7789
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
发明人： Hans-Martin Hutmacher , Franz Merger , Franz J. Broecker , Rolf Fischer , Uwe Vagt , Wolfgang Harder , Claus-Ulrich Priester , Heinz-Walter Schneider , Wolfgang Richter
IPC分类号： B01J23/74 , B01J23/78 , B01J25/00 , C07B61/00 , C07D201/08
CPC分类号： C07D201/08 , Y02P20/52
摘要： Caprolactam is prepared by a process in which(a) a 5-formylvalerate is reacted with excess ammonia and hydrogen in the presence of an alkanol as a solvent and in the presence of a hydrogenation catalyst under superatmospheric pressure in the liquid phase at from 40.degree. to 130.degree. C.,(b) excess ammonia and hydrogen are separated off from the reaction mixture and(c) the reaction mixture thus obtained is heated to 150.degree.-250.degree. C. and .epsilon.-caprolactam is obtained.
摘要翻译：己内酰胺通过以下方法制备：其中（a）5-烷基戊酸酯与过量的氨和氢在烷醇作为溶剂的存在下和氢化催化剂的存在下在超大气压下在40℃的液相中反应至130℃，（b）从反应混合物中分离出过量的氨和氢，（c）将所得反应混合物加热至150-250℃，得到ε-己内酰胺。

8. 发明授权

US4950429A Preparation of 6-aminocaproic acid 失效
标题翻译： 6-氨基己酸的制备
公开(公告)号：US4950429A
公开(公告)日：1990-08-21
申请号：US327432
申请日：1989-03-23
申请人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
发明人： Uwe Vagt , Rolf Fischer , Franz Merger , Hans-Martin Hutmacher
IPC分类号： C07C51/09 , C07C67/00 , C07C227/00 , C07C227/08 , C07C229/08 , C07C227/04
CPC分类号： C07C227/08 , C07C51/09
摘要： 6-Aminocaproic acid is prepared by(a) reacting a 5-formylvaleric acid ester with water in the presence of an acid agent at 30.degree.-200.degree. C. and(b) reacting the 5-formylvaleric acid thus obtained with excess ammonia and hydrogen in the presence of a hydrogenation catalyst and of a solvent which is inert under the reaction conditions at 50.degree.-150.degree. C. under superatmospheric pressure.
摘要翻译： 6-氨基己酸的制备方法是：（a）在酸性试剂存在下，在30℃-200℃下使5-甲酰基戊酸酯与水反应，和（b）使所得到的5-甲酰基戊酸与过量的氨和在氢化催化剂存在下，在50〜150℃的反应条件下，在超大气压下进行惰性的溶剂。

9. 发明授权

US5068398A Preparation of 6-aminocaproic esters 失效
标题翻译： 6-氨基磷酸酯的制备
公开(公告)号：US5068398A
公开(公告)日：1991-11-26
申请号：US448900
申请日：1989-12-12
申请人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
发明人： Franz Merger , Rolf Fischer , Wolfgang Harder , Claus-Ulrich Priester , Uwe Vagt
IPC分类号： B01J23/46 , C07B61/00 , C07C227/04 , C07C227/08 , C07C229/08
CPC分类号： C07C227/08
摘要： 6-Aminocaproic esters are prepared by reacting alkyl 5-formylvalerates with excess ammonia and hydrogen in the presence of ruthenium catalysts at elevated temperature under superatmospheric pressure in liquid ammonia as reaction medium.
摘要翻译： 6-氨基己酸酯通过在钌催化剂存在下，在高于大气压的高温下在液氨中作为反应介质使5-甲酰基戊酸烷基酯与过量的氨和氢反应来制备。

10. 发明授权

US5032684A Continuous purification of caprolactam 失效
标题翻译：持续纯化己内酰胺
公开(公告)号：US5032684A
公开(公告)日：1991-07-16
申请号：US551790
申请日：1990-07-12
申请人： Gerald Neubauer , Josef Ritz , Hugo Fuchs , David Agar , Rolf Fischer , Uwe Vagt
发明人： Gerald Neubauer , Josef Ritz , Hugo Fuchs , David Agar , Rolf Fischer , Uwe Vagt
IPC分类号： C07D223/10 , C07D201/16
CPC分类号： C07D201/16
摘要： Caprolactam is purified continuously by passing a 75-95% strength by weight aqueous caprolactam solution together with hydrogen at 50.degree.-95.degree. C. and 1.5-100 bar upward through a fixed-bed supported palladium or nickel catalyst in a tubular zone while maintaining a residence time of from 10 to 100 min.
摘要翻译：通过将75-95％的重量比的己内酰胺水溶液与氢在-50-95℃和1.5-100巴上通过固定床负载的钯或镍催化剂在管状区域中连续纯化，同时保持己内酰胺停留时间为10至100分钟。

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