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1. 发明授权

US4310686A Preparation of butanedicarboxylic esters 失效
标题翻译：丁烷二羧酸酯的制备
公开(公告)号：US4310686A
公开(公告)日：1982-01-12
申请号：US153572
申请日：1980-05-27
申请人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
发明人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
IPC分类号： C07C67/08 , B01J31/00 , B01J31/20 , C07B61/00 , C07C67/38 , C07C67/58 , C07C69/34 , C07C69/44
CPC分类号： C07C69/34 , C07C67/38
摘要： A process for the preparation of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated with excess carbon monoxide and hydrogen in the presence of active charcoal laden with cobalt carbonyl,(b) the resulting aqueous solution of cobalt carbonyl hydride is extracted with butadiene or a butadiene containing hydrocarbon mixture and the aqueous phase is separated off,(c) the butadiene, or butadiene/hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl, is reacted with carbon monoxide and excess C.sub.1 -C.sub.4 -alkanol in the presence of a tertiary nitrogen base,(d) the resulting reaction mixture is freed from the tertiary nitrogen base contained therein, down to a content of from 0.1 to 0.3 mole per mole of pentenoic acid ester, and from excess hydrocarbons, and the pentenoic acid ester remaining in the reaction mixture is reacted with carbon monoxide and excess C.sub.1 -C.sub.4 -alkanol in the presence of the cobalt carbonyl and tertiary nitrogen base contained in the reaction mixture,(e) the reaction mixture is treated with an oxidizing agent in the presence of the aqueous acid solution which has been separated off in stage (b), and the mixture is separated into an organic phase, from which butanedicarboxylic acid esters are isolated by distillation, and an aqueous phase, and(f) the aqueous phase is extracted with water-immiscible solvents, the phases are separated, and the resulting aqueous phase is freed from alkanols and tertiary nitrogen base and is recycled to stage (a).
摘要翻译：制备丁烷二羧酸酯的方法，其中（a）钴水溶液在过量的一氧化碳和氢气的存在下，在负载有羰基钴的活性炭存在下处理，（b）得到的氢化羰基碳水溶液为用丁二烯或含丁二烯的烃混合物萃取并分离出水相，（c）含有羰基氢化钴，羰基钴和三丁基钴的三羰基化合物的丁二烯或丁二烯/烃混合物与一氧化碳和过量的C1 -C 4 - 链烷醇，（d）将所得反应混合物与其中所含的叔氮碱脱除，至每摩尔戊烯酸酯为0.1至0.3摩尔，过量碳氢化合物和残留在反应混合物中的戊烯酸酯在羰基钴a存在下与一氧化碳和过量的C 1 -C 4烷醇反应（e）反应混合物在步骤（b）中分离的酸性水溶液存在下用氧化剂处理，并将混合物分离成有机相通过蒸馏分离丁二羧酸酯和水相，（f）水相用不与水混溶的溶剂萃取，分离相，所得水相脱离链烷醇和叔氮碱，被回收到舞台（a）。

2. 发明授权

US4523027A Purification of carboxylates containing aldehydes, acetals and/or unsaturated compounds 失效
标题翻译：含醛，缩醛和/或不饱和化合物的羧酸盐的纯化
公开(公告)号：US4523027A
公开(公告)日：1985-06-11
申请号：US518006
申请日：1983-07-28
申请人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
发明人： Rudolf Kummer , Heinz-Walter Schneider , Volker Taglieber , Franz-Josef Weiss
IPC分类号： C07C67/60 , C07C69/34 , C07C69/44 , C07C67/56
CPC分类号： C07C67/60
摘要： Carboxylates which contain aldehydes, acetals and/or unsaturated compounds and are obtained by reacting an olefinically unsaturated compound with carbon monoxide and an alkanol are purified by a process wherein the said carboxylates are treated with hydrogen at elevated temperatures in the presence of an acidic ion exchanger or zeolite doped with one or more metals of group VIII of the periodic table, and the resulting low and/or high boilers are separated off by distillation.
摘要翻译：通过使烯属不饱和化合物与一氧化碳和链烷醇反应得到的含醛，缩醛和/或不饱和化合物的羧酸盐通过其中所述羧酸盐在酸性离子交换剂存在下在高温下用氢处理的方法进行纯化或掺杂有周期表第Ⅷ族的一种或多种金属的沸石，并通过蒸馏分离得到的低和/或高沸点。

3. 发明授权

US4316047A Preparation of C.sub.1 -C.sub.4 -alkyl pent-3-enoates 失效
标题翻译：制备C1-C4烷基戊-3-烯酸酯
公开(公告)号：US4316047A
公开(公告)日：1982-02-16
申请号：US166569
申请日：1980-07-07
申请人： Rudolf Kummer , Franz-Josef Weiss , Heinz-Walter Schneider , Volker Taglieber
发明人： Rudolf Kummer , Franz-Josef Weiss , Heinz-Walter Schneider , Volker Taglieber
IPC分类号： B01J31/00 , C07B61/00 , C07C69/533 , C07C67/38
CPC分类号： C07C69/533
摘要： A process for the preparation of C.sub.1 -C.sub.4 -alkyl pent-3-enoates, wherein butadiene, or a hydrocarbon mixture containing butadiene, either of which contains not more than 0.1% by weight of butynes, is reacted with carbon monoxide and an alkanol of 1 to 4 carbon atoms in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base, having a pK.sub.A of 3-11, at from 100.degree. to 140.degree. C. under a pressure of from 300 to 1,000 bar.
摘要翻译：一种制备C 1 -C 4烷基戊-3-烯酸酯的方法，其中丁二烯或含有丁二烯的烃混合物（其中含有不超过0.1重量％的丁炔）与一氧化碳和链烷醇反应在羰基钴催化剂和叔氮碱的存在下，在300-1000巴的压力下，pKA为3-11，在100-140℃下存在1至4个碳原子。

4. 发明授权

US4801738A Preparation of .delta.-formylvalerates 失效
标题翻译：三甲酸戊酯的制备
公开(公告)号：US4801738A
公开(公告)日：1989-01-31
申请号：US608460
申请日：1984-05-09
申请人： Heinz-Walter Schneider , Rudolf Kummer , Volker Taglieber
发明人： Heinz-Walter Schneider , Rudolf Kummer , Volker Taglieber
IPC分类号： C07C67/313 , B01J29/12 , B01J31/00 , B01J31/20 , C07B61/00 , C07C67/333 , C07C67/38 , C07C69/67
CPC分类号： C07C67/347
摘要： .delta.-Formylvalerates are prepared by a process wherein a 3-pentenoate is treated with an isomerization catalyst at elevated temperatures and a 4-pentenoate is distilled off, and the resulting 4-pentenoate is reacted with carbon monoxide and hydrogen at from 80 to 160.degree. C. under from 1 to 30 bar in the presence of a rhodium carbonyl complex which has been modified with tertiary organic phosphines or phosphites.
摘要翻译： δ-甲酸戊酯通过其中3-异戊烯酸酯在高温下用异构化催化剂处理并蒸馏除去4-戊烯酸酯的方法制备，所得4-戊烯酸酯与一氧化碳和氢气在80至160℃下反应。在1至30巴下，在用叔有机膦或亚磷酸酯改性的羰基铑络合物的存在下。

5. 发明授权

US4454358A Continuous production of ethanol and plural stage distillation of the same 失效
标题翻译：连续生产乙醇和多级蒸馏相同
公开(公告)号：US4454358A
公开(公告)日：1984-06-12
申请号：US337683
申请日：1982-01-07
申请人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
IPC分类号： C07C29/132 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/04 , C07C29/149 , C07C29/80 , C07C29/92 , C07C31/08 , C07C67/00 , B01D3/00
CPC分类号： C07C29/80 , C07C29/149 , C07C67/08 , C07C67/36 , C07C67/54 , Y02P20/52 , Y10S203/06 , Y10S203/20
摘要： Ethanol is produced continuously via the carbonylation of methanol, by(a) carbonylating methanol, in a reactor R, in the presence of a carbonyl complex of a metal of group VIII of the periodic table and of a halogen compound,(b) separating, in a distillation column D1, the reactor discharge, into a top fraction comprising methyl acetate, methanol, dimethyl ether and an organohalogen compound, and into a bottom fraction comprising water, small quantities of acetic acid and the catalyst, if the latter is not in a fixed bed, the residence time being so adjusted that the greater part of the acetic acid reacts with the methanol present to give methyl acetate,(c) separating the top fraction from D1, in a distillation column D2, into a top fraction comprising small quantities of methyl acetate, methanol, dimethyl ether and the organo-halogen compound, and a bottom fraction comprising methyl acetate and methanol, and recycling the top fraction to reactor R,(d) distilling off, via the top of distillation column D3, the greater part of the water from the bottom fraction from D1and removing this water from circulation, and recycling to reactor R the bottom fraction consisting of small quantities of water, acetic acid and the catalyst,(e) using hydrogen to hydrogenate, in the hydrogenation reactor H, the bottom fraction from D2, in a conventional manner, to give a mixture of methanol and ethanol, and(f) separating the mixture into ethanol and methanol in a distillation column D4, and recycling the methanol to reactor R.
摘要翻译：通过（a）在反应器R中羰基化甲醇，在周期表第VIII族金属的羰基络合物和卤素化合物的存在下，连续生产乙醇，（b）分离，在蒸馏塔D1中，反应器排出成为包含乙酸甲酯，甲醇，二甲醚和有机卤素化合物的顶级馏分，并进入包含水，少量乙酸和催化剂的底部馏分，如果后者不在固定床，停留时间如此调节，使得大部分乙酸与存在的甲醇反应得到乙酸甲酯，（c）将蒸馏塔D2中的顶馏分与D1分离成包含小分子的顶馏分数量的乙酸甲酯，甲醇，二甲醚和有机卤素化合物，以及包含乙酸甲酯和甲醇的底部馏分，并将顶部馏分再循环到反应器R中，（d）通过顶部o蒸馏 f蒸馏塔D3，来自D1的底部馏分的大部分水从循环中除去，并且将反应器R再循环到由少量水，乙酸和催化剂组成的底部馏分，（e）使用氢气以常规方式在氢化反应器H中将来自D2的塔底馏分氢化，得到甲醇和乙醇的混合物，和（f）将混合物在蒸馏塔D4中分离成乙醇和甲醇，并将甲醇再循环至反应器

6. 发明授权

US4350572A Purification of carboxylic acid esters containing aldehydes and/or acetals 失效
标题翻译：含醛和/或缩醛的羧酸酯的纯化
公开(公告)号：US4350572A
公开(公告)日：1982-09-21
申请号：US204637
申请日：1980-11-06
申请人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
IPC分类号： C07C67/48 , C07C67/38 , C07C67/56 , C07C67/60 , C07C69/44 , B01D3/34
CPC分类号： C07C67/60
摘要： A process for purifying carboxylic acid esters which have been obtained by reacting olefinically unsaturated compounds with carbon monoxide and alkanols and which contain aldehydes or acetals, wherein the said esters are treated with a strongly acidic agent, with or without addition of water.
摘要翻译：通过使烯属不饱和化合物与一氧化碳和链烷醇反应并且含有醛或缩醛而获得的羧酸酯的方法，其中所述酯用强酸性剂处理，或不加入水。

7. 发明授权

US4929759A Production of amines from an olefin and ammonia or a primary or secondary amine 失效
标题翻译：从烯烃和氨或伯胺或仲胺制备胺
公开(公告)号：US4929759A
公开(公告)日：1990-05-29
申请号：US418939
申请日：1989-10-06
申请人： Volker Taglieber , Wolfgang Hoelderich , Rudolf Kummer , Wolf D. Mross , Guenter Saladin
发明人： Volker Taglieber , Wolfgang Hoelderich , Rudolf Kummer , Wolf D. Mross , Guenter Saladin
IPC分类号： B01J29/04 , B01J29/86 , C07C209/60
CPC分类号： B01J29/86 , B01J29/04 , C07C209/60 , Y02P20/582
摘要： Amines are prepared from an olefin and ammonia or a primary or secondary amine, or a mixture of these, in the presence of a borosilicate or borogermanate zeolite of the pentasil type as a catalyst, by a process in which the amine obtained is isolated from the reaction mixture, and unreacted starting materials are recycled.
摘要翻译：在硼烷硅酸盐或硼烷类硼沸石沸石作为催化剂的存在下，由烯烃和氨或伯胺或仲胺或它们的混合物制备胺，其中所得的胺与反应混合物和未反应的起始原料被再循环。

8. 发明授权

US4929758A Preparation of tert-butylamine from isobutene 失效
标题翻译：从异丁烯制备叔丁胺
公开(公告)号：US4929758A
公开(公告)日：1990-05-29
申请号：US212161
申请日：1988-06-13
申请人： Volker Taglieber , Wolfgang Hoelderich , Rudolf Kummer , Wolf D. Mross , Guenter Saladin
发明人： Volker Taglieber , Wolfgang Hoelderich , Rudolf Kummer , Wolf D. Mross , Guenter Saladin
IPC分类号： C07B61/00 , B01J21/00 , B01J29/04 , B01J29/40 , C07C67/00 , C07C209/00 , C07C209/60 , C07C211/02
CPC分类号： C07C209/60 , Y02P20/582
摘要： Amines are prepared from an olefin and ammonia or a primary and/or secondary amine in the presence of a zeolite catalyst of the pentasil type. Iron silicate zeolites of the pentasil type having an SiO.sub.2 /Fe.sub.2 O.sub.3 ratio greater than or equal to 10 are preferably used.
摘要翻译：胺在戊烯型沸石催化剂存在下由烯烃和氨或初级和/或仲胺制备。优选使用SiO 2 / Fe 2 O 3比例大于或等于10的pentasil型铁硅酸盐沸石。

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