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1. 发明授权

US08945712B2 Fluorinated compositions and surface treatments made therefrom 有权
标题翻译：氟化组合物和由其制成的表面处理
公开(公告)号：US08945712B2
公开(公告)日：2015-02-03
申请号：US12663027
申请日：2008-06-05
申请人： Rudolf J. Dams , Steven J. Martin , Mark J. Pellerite , Chetan P. Jariwala , Gregory D. Clark , Jason T. Petrin
发明人： Rudolf J. Dams , Steven J. Martin , Mark J. Pellerite , Chetan P. Jariwala , Gregory D. Clark , Jason T. Petrin
IPC分类号： B32B15/04 , C09D7/12 , C09D133/14 , C08F8/40 , C08F220/22 , C08F220/36 , C08J3/09 , C09D133/06 , C09D133/16 , C09D143/02 , C08F220/10 , C08F220/18
CPC分类号： C08F14/185 , C08F8/40 , C08F220/10 , C08F220/18 , C08F220/22 , C08F220/36 , C08J3/09 , C08J2333/16 , C09D127/12 , C09D133/06 , C09D133/14 , C09D133/16 , C09D143/02 , Y10T428/3154 , Y10T428/31678 , C08F20/22 , C08F230/02
摘要： A polymeric or oligomeric composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant phosphonate group —P(O)(OY)2 or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently —P(O)(OY)2 or —O—P(O)(OY)2. Rf is a perfluoropolyether group. Q is a bond, —C(O)—N(R1)—, or —C(O)—O—. R″, R′″, R and R1 are each independently hydrogen and alkyl having from 1 to 4 carbon atoms. X is alkylene, arylalkylene, and alkylarylene, wherein alkylene, arylalkylene, and alkylarylene are each optionally interrupted by at least one ether linkage. Y is hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.
摘要翻译：一种聚合物或低聚物组合物，其包含至少一种由式表示的第一二价单元和至少一种包含膦酸酯基-P（O）（OY）2侧基的第二二价单元或包含硫醚键和末端的一价单元 Z基团，其中每个Z基团独立地为-P（O）（OY）2或-O-P（O）（OY）2。 Rf是全氟聚醚基团。 Q是键，-C（O）-N（R 1） - 或-C（O）-O-。 R“，R”“，R”和“R”各自独立地为氢和具有1至4个碳原子的烷基。 X是亚烷基，芳基亚烷基和烷基亚芳基，其中亚烷基，芳基亚烷基和烷基亚芳基各自任选被至少一个醚键中断。 Y是氢，烷基，三烷基甲硅烷基和抗衡阳离子。提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。还提供制备这些组合物的方法。

2. 发明申请

US20100183889A1 FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM 有权
标题翻译：氟化组合物和表面处理
公开(公告)号：US20100183889A1
公开(公告)日：2010-07-22
申请号：US12663027
申请日：2008-06-05
申请人： Rudolf J. Dams , Steven J. Martin , Mark J. Pellerite , Chetan P. Jariwala , Gregory D. Clark , Jason T. Petrin
发明人： Rudolf J. Dams , Steven J. Martin , Mark J. Pellerite , Chetan P. Jariwala , Gregory D. Clark , Jason T. Petrin
IPC分类号： B32B15/04 , C09D7/12
CPC分类号： C08F14/185 , C08F8/40 , C08F220/10 , C08F220/18 , C08F220/22 , C08F220/36 , C08J3/09 , C08J2333/16 , C09D127/12 , C09D133/06 , C09D133/14 , C09D133/16 , C09D143/02 , Y10T428/3154 , Y10T428/31678 , C08F20/22 , C08F230/02
摘要： A composition comprising at least one first divalent unit represented by formula (A) or formula (B); and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. Rf is a perfluoropolyether group. Q is selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. R″, R′″, R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. X is selected from the group consisting of alkylene, arylalkylene, and alkylarylene, wherein alkylene, arylalkylene, and alkylarylene are each optionally interrupted by at least one ether linkage. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.
摘要翻译：包含由式（A）或式（B）表示的至少一种第一二价单元的组合物; 和包含Z侧基团或包含硫醚键和末端Z基团的一价单元的第二二价单元中的至少一个，其中每个Z基团独立地选自-P（O）（OY）2和 -O-P（O）（OY）2。 Rf是全氟聚醚基团。 Q选自-C（O）-N（R 1） - 和-C（O）-O-。 R“，R”“，R”和“R”各自独立地选自氢和具有1至4个碳原子的烷基。 X选自亚烷基，芳基亚烷基和烷基亚芳基，其中亚烷基，芳基亚烷基和烷基亚芳基各自任选地被至少一个醚键中断。 Y选自氢，烷基，三烷基甲硅烷基和抗衡阳离子。提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。还提供制备这些组合物的方法。

3. 发明授权

US07998585B2 Compositions for aqueous delivery of fluorinated oligomeric silanes 失效
标题翻译：含氟低聚硅烷的水分输送组合物
公开(公告)号：US07998585B2
公开(公告)日：2011-08-16
申请号：US12784892
申请日：2010-05-21
申请人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
发明人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
IPC分类号： B32B17/00
CPC分类号： C04B41/009 , C03C17/30 , C04B41/495 , C04B41/52 , C04B41/84 , C08F30/08 , C08L27/12 , C09D127/12 , Y10T428/31612 , Y10T428/31663 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00 , C08L33/00
摘要： The invention relates to a dilutable, non-aqueous concentrate and an aqueous dilution used for aqueous delivery of fluorinated oligomeric silanes to a substrate, a method of treating a substrate with the aqueous dilution composition to render it oil and water repellent, and articles having coatings made from the aqueous dilution.
摘要翻译：本发明涉及一种可稀释的非水性浓缩物和用于将氟化低聚硅烷水性输送到底物的水性稀释液，用水稀释组合物处理底物以使其具有防水和防水性的方法，以及具有涂层的制品由水稀释制成。

4. 发明申请

US20100233492A1 COMPOSITIONS FOR AQUEOUS DELIVERY OF FLUORINATED OLIGOMERIC SILANES 失效
标题翻译：氟化低聚硅烷的水分输送组合物
公开(公告)号：US20100233492A1
公开(公告)日：2010-09-16
申请号：US12784892
申请日：2010-05-21
申请人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
发明人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
IPC分类号： B32B17/10 , C08G18/42 , B05D3/10 , C08K5/05 , C08K5/3415 , C08K5/20 , C08K5/07 , C08K5/06 , C08K5/02 , C08L83/00 , B32B18/00
CPC分类号： C04B41/009 , C03C17/30 , C04B41/495 , C04B41/52 , C04B41/84 , C08F30/08 , C08L27/12 , C09D127/12 , Y10T428/31612 , Y10T428/31663 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00 , C08L33/00
摘要： The invention relates to a dilutable, non-aqueous concentrate and an aqueous dilution used for aqueous delivery of fluorinated oligomeric silanes to a substrate, a method of treating a substrate with the aqueous dilution composition to render it oil and water repellent, and articles having coatings made from the aqueous dilution.
摘要翻译：本发明涉及一种可稀释的非水性浓缩物和用于将氟化低聚硅烷水性输送到底物的水性稀释液，用水稀释组合物处理底物以使其具有防水和防水性的方法，以及具有涂层的制品由水稀释制成。

5. 发明授权

US07321018B2 Compositions for aqueous delivery of fluorinated oligomeric silanes 失效
标题翻译：含氟低聚硅烷的水分输送组合物
公开(公告)号：US07321018B2
公开(公告)日：2008-01-22
申请号：US10745003
申请日：2003-12-23
申请人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
发明人： Rudolf J. Dams , Mark J. Pellerite , Steven J. Martin , Michael S. Terrazas
IPC分类号： C08G77/20
CPC分类号： C04B41/009 , C03C17/30 , C04B41/495 , C04B41/52 , C04B41/84 , C08F30/08 , C08L27/12 , C09D127/12 , Y10T428/31612 , Y10T428/31663 , C04B41/502 , C04B2103/40 , C04B41/5022 , C04B33/00 , C08L33/00
摘要： The invention relates to a dilutable, non-aqueous concentrate and an aqueous dilution used for aqueous delivery of fluorinated oligomeric silanes to a substrate, a method of treating a substrate with the aqueous dilution composition to render it oil and water repellent, and articles having coatings made from the aqueous dilution.
摘要翻译：本发明涉及一种可稀释的非水性浓缩物和用于将氟化低聚硅烷水性输送到底物的水性稀释液，用水稀释组合物处理底物以使其具有防水和防水性的方法，以及具有涂层的制品由水稀释制成。

6. 发明授权

US06613860B1 Compositions comprising fluorinated polyether silanes for rendering substrates oil and water repellent 有权
标题翻译：包含氟化聚醚硅烷的组合物，用于使底物油和憎水性
公开(公告)号：US06613860B1
公开(公告)日：2003-09-02
申请号：US09689013
申请日：2000-10-12
申请人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
发明人： Rudolf J. Dams , Franceska M. Fieuws , Steven J. Martin , Michael S. Terrazas , Mark J. Pellerite
IPC分类号： C08G7760
CPC分类号： C04B41/009 , C03C17/30 , C04B41/4933 , C04B41/84 , C08G65/007 , C08G65/336 , C04B41/46 , C04B41/463 , C04B41/502 , C04B33/00
摘要： The present invention provides composition for treating a substrate comprising a homogeneous mixture of: (a) a fluorinated polyether silane of the formula: Rf1—[—Q—SiY3−xR1x]y (I) wherein Rf1 represents a monovalent or divalent polyfluoropolyether group, Q represents an organic divalent linking group, R1 represents a C1-C4 alkyl group, Y represents a hydrolysable group; x is 0 or 1 and y is 1 or 2; (b) an organic or an inorganic acid; (c) water; and (d) an organic solvent. The invention further provides a method of making such a composition and the use thereof to treat substrates to render them oil and water repellent.
摘要翻译：本发明提供了一种用于处理底物的组合物，其包含以下均匀混合物：（a）下式的氟化聚醚硅烷：其中Rf1表示一价或二价多氟聚醚基团，Q表示有机二价连接基团，R1表示C1-C4 烷基，Y表示可水解基团; x为0或1，y为1或2;（b）有机或无机酸;（c）水; 和（d）有机溶剂。本发明还提供了一种制备这种组合物的方法及其用途来处理基材以使其具有防水和防水性。

7. 发明授权

US06991826B2 Antisoiling coatings for antireflective substrates 失效
标题翻译：抗反射底物的抗异氰酸酯涂料
公开(公告)号：US06991826B2
公开(公告)日：2006-01-31
申请号：US10828451
申请日：2004-04-20
申请人： Mark J. Pellerite , Rudolf J. Dams , Steven J. Martin
发明人： Mark J. Pellerite , Rudolf J. Dams , Steven J. Martin
IPC分类号： C23C14/12 , C23C14/24 , G02C7/02 , G02B1/10
CPC分类号： C08J7/06 , C08G65/226 , C08J2369/00 , C09D4/00 , C09D5/006 , C09D5/1668 , C09D5/1675 , C09D183/08 , C09D183/12 , C23C14/12 , G02B1/105 , G02B1/111 , G02B1/18 , C08G77/24
摘要： This invention relates to antisoiling compositions for antireflective substrates. More particularly, this invention relates to methods for depositing antisoiling compositions onto antireflective substrates. In particular, this invention relates to a method of depositing an antisoiling composition on an antireflective substrate comprising vaporizing an antisoiling composition and depositing the antisoiling composition onto an antireflective substrate. In another aspect, this invention relates to method of preparing an antireflective film stack comprising depositing an antireflective layer onto the surface of a transparent substrate and vapor depositing an antisoiling layer onto the surface of the antireflective layer. In yet another aspect, this invention relates to a method of depositing an antisoiling composition on an antireflective coated ophthalmic lens comprising vaporizing an antisoiling composition and depositing the antisoiling composition onto an antireflective coated ophthalmic lens.
摘要翻译：本发明涉及抗反射底物的防污组合物。更具体地说，本发明涉及将防污组合物沉积到抗反射底物上的方法。特别地，本发明涉及一种在防反射基材上沉积防污组合物的方法，包括使防污组合物蒸发并将防污组合物沉积在抗反射基材上。另一方面，本发明涉及制备抗反射膜叠层的方法，包括在透明基底的表面上沉积防反射层，并将防污层气相沉积到抗反射层的表面上。另一方面，本发明涉及一种在防反射涂层眼科镜片上沉积防污组合物的方法，包括使防污组合物汽化并将防污组合物沉积在抗反射涂层眼镜上。

8. 发明授权

US08158264B2 Method for easy-to-clean substrates and articles therefrom 有权
标题翻译：易于清洁基材和其制品的方法
公开(公告)号：US08158264B2
公开(公告)日：2012-04-17
申请号：US12445978
申请日：2007-10-18
申请人： Moses M. David , Steven J. Martin , Rudolf J. Dams , Wayne W. Fan
发明人： Moses M. David , Steven J. Martin , Rudolf J. Dams , Wayne W. Fan
IPC分类号： B32B9/04
CPC分类号： B05D5/083 , B05D1/62 , B05D7/14 , C23C16/0245 , C23C16/401 , C23C16/56 , C23C28/00 , Y10T428/265 , Y10T428/31544 , Y10T428/31663
摘要： A method of forming an easy-to-clean metal or metallized substrate, the method comprising forming a layer comprising silicon, oxygen, and hydrogen on at least a portion of a surface of the substrate by plasma deposition; and applying an at least partially fluorinated composition comprising at least one silane group to at least a portion of a surface of the layer comprising the silicon, oxygen, and hydrogen; and an easy-to-clean article made by the method are disclosed.
摘要翻译：一种形成容易清洁的金属或金属化衬底的方法，所述方法包括通过等离子体沉积在衬底表面的至少一部分上形成包含硅，氧和氢的层; 以及将包含至少一个硅烷基团的至少部分氟化的组合物施加到包含硅，氧和氢的层的表面的至少一部分上; 并且公开了通过该方法制成的易于清洁的制品。

9. 发明授权

US08833449B2 Methods for treating carbonate hydrocarbon-bearing formations with fluorinated amphoteric compounds 有权
标题翻译：用氟化两性化合物处理碳酸盐含烃地层的方法
公开(公告)号：US08833449B2
公开(公告)日：2014-09-16
申请号：US13382554
申请日：2010-07-02
申请人： Rudolf J. Dams , Steven J. Martin , Yong K. Wu
发明人： Rudolf J. Dams , Steven J. Martin , Yong K. Wu
IPC分类号： E21B43/22 , E21B43/26 , C09K8/60 , B01F17/00 , C08F8/44 , C03C12/02 , C09K8/68 , C25C1/00
CPC分类号： C09K8/68 , B01F17/0035 , C03C12/02 , C08F8/44 , C09K8/602 , C09K8/604 , C25C1/00
摘要： Method of treating a carbonate hydrocarbon-bearing formation. The method includes contacting the hydrocarbon-bearing formation with a composition comprising solvent and a fluorinated amphoteric compound. Carbonate hydrocarbon-bearing formations treated according to the method are also disclosed.
摘要翻译：处理碳酸盐含烃地层的方法该方法包括使含烃地层与包含溶剂和氟化两性化合物的组合物接触。还公开了根据该方法处理的含碳酸盐的地层。

10. 发明申请

US20120055668A1 SOLVENTS AND COMPOSITIONS FOR TREATING HYDROCARBON-BEARING FORMATIONS 审中-公开
标题翻译：用于处理碳氢化合物轴承的溶剂和组合物
公开(公告)号：US20120055668A1
公开(公告)日：2012-03-08
申请号：US13320089
申请日：2009-05-11
申请人： Yong K. Wu , Rudolf J. Dams , Steven J. Martin , Wayne W. Fan
发明人： Yong K. Wu , Rudolf J. Dams , Steven J. Martin , Wayne W. Fan
IPC分类号： E21B43/22 , E21B47/07 , C09K8/58
CPC分类号： C09K8/602 , C08G18/0823 , C08G18/2885 , C08G18/289 , C08G18/792 , C09K8/588 , C09K8/604 , C09K8/80
摘要： A method of treating a hydrocarbon-bearing formation that includes receiving data comprising a temperature and a brine composition of the hydrocarbon-bearing formation; selecting a treatment composition for the hydrocarbon-bearing formation comprising a fluorinated compound and solvent, wherein, at the temperature, a mixture of an amount of the brine composition and the treatment composition separates into at least two separate transparent liquid layers, and wherein the mixture is free of precipitated solid; and contacting the hydrocarbon-bearing formation with the treatment composition. Compositions containing certain fluorinated polymers and solvents containing water, monohydroxy alcohols, and ketones are also disclosed.
摘要翻译：一种处理含烃地层的方法，包括接收包含含烃地层的温度和盐水组成的数据; 选择含氟化合物和溶剂的含烃地层的处理组合物，其中在该温度下，一定量的盐水组合物和处理组合物的混合物分离成至少两个分开的透明液体层，并且其中混合物无沉淀固体; 并使含烃地层与处理组合物接触。还公开了含有某些含氟聚合物和含有水，单羟基醇和酮的溶剂的组合物。

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