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    • 1. 发明授权
    • Hydrodesulfurization process
    • 加氢脱硫工艺
    • US3964995A
    • 1976-06-22
    • US481797
    • 1974-06-21
    • Ronald H. WolkSeymour B. AlpertMichael C. Chervenak
    • Ronald H. WolkSeymour B. AlpertMichael C. Chervenak
    • C10G45/16C10G65/04C10G23/02
    • C10G45/16C10G2300/107
    • A two-stage hydrodesulfurization process for a 65 to 80 percent desulfurization of a high metal content residuum, such as those obtained from Venezuela, in which the contact solids activity in both stages is maintained at an equilibrium level by constant replacement of the contact solids in both stages. The first stage contains a porous alumina solids contact material activated with at least one promoter oxide selected from Fe.sub.2 O.sub.3, TiO.sub.2 and SiO.sub.2, which has as its primary purpose the removal of vanadium and nickel from the feed material. However, the treatment of the feed in the first stage was found to improve the second stage performance by a factor greater than the amount of metals removed. The second stage contains a highly active desulfurization catalyst of limited porosity.
    • 一种二阶段加氢脱硫方法,用于高金属含量残渣(如委内瑞拉获得的那些)的65%至80%的脱硫,其中两个阶段的接触固体活性通过不断更换接触固体而保持在平衡水平 两个阶段 第一阶段包含用至少一种选自Fe 2 O 3,TiO 2和SiO 2的助催化剂氧化物活化的多孔氧化铝固体接触材料,其主要目的是从进料中除去钒和镍。 然而,发现在第一阶段中进料的处理通过大于除去金属的量来提高第二阶段性能。 第二阶段包含孔隙率有限的高活性脱硫催化剂。