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1. 发明授权

US4995895A Process for the manufacture of a toughened and/or bent sheet of glass with a silver coating 失效
标题翻译：用银涂层制造钢化和/或弯曲的玻璃板的方法
公开(公告)号：US4995895A
公开(公告)日：1991-02-26
申请号：US431700
申请日：1989-11-03
申请人： Rolf Groth , Thomas Paul
发明人： Rolf Groth , Thomas Paul
IPC分类号： C03C17/27 , C03C17/36 , C03C17/40
CPC分类号： C03C17/3605 , B32B17/10036 , B32B17/1022 , B32B17/10761 , C03C17/36 , C03C17/3613 , C03C17/3615 , C03C17/3618 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C17/3689 , C03C2217/73
摘要： Process for the manufacture of a toughened and/or bent, infrared-reflecting sheet of glass made of sodalime silicate glass, in which on at least side of a transparent glass base a silver coating is applied and on its side facing away from the glass base at least one anti-reflection coating made of metal oxide is applied and a thermal toughening and/or bending process at a temperature of 580.degree. C. to 680.degree. C., preferably 600.degree. C. to 650.degree. C., is carried out, characterised by the fact that a silver coating and an outer coating made of a metal or a metal alloy are applied onto the essentially flat glass base and by the fact that after this the toughening and/or bending process is carried out, in which the outer coating is converted with an increase in volume into an essentially absorption-free metal oxide, forming at least part of the anti-reflection coating, with an index of refraction .gtoreq.1.7, sheet of glass produced according to this and its application.
摘要翻译：用于制造由钠钙硅酸盐玻璃制成的钢化玻璃和/或弯曲的红外线反射片材的方法，其中在透明玻璃基底的至少一侧施加银涂层并且在其背离玻璃基底的一侧施加至少一种由金属氧化物制成的抗反射涂层，并且在580℃至680℃，优选600℃至650℃的温度下进行热增韧和/或弯曲加工。其特征在于，将银涂层和由金属或金属合金制成的外涂层施加到基本上平坦的玻璃基底上，并且在此之后进行增韧和/或弯曲加工，其中外部涂层以体积增加转变为基本上无吸收的金属氧化物，形成至少部分防反射涂层，折射率> / = 1.7，根据此制造的玻璃片及其应用。

2. 发明授权

US4827729A Method of removing a mist coating from the interior face of a glazed panel of a refrigerating cabinet 失效
标题翻译：从制冷柜的玻璃板的内表面去除雾涂层的方法
公开(公告)号：US4827729A
公开(公告)日：1989-05-09
申请号：US216591
申请日：1988-07-07
申请人： Rolf Groth , Hans Bause
发明人： Rolf Groth , Hans Bause
IPC分类号： A47F3/04 , F25D21/04
CPC分类号： A47F3/0434 , F25D21/04 , F25B2600/112 , F25B2700/02 , F25D2700/02
摘要： There is disclosed a method for the removal of a coating of mist at the interior face of a glazing panel, especially of high thermally insulating glass, of a refrigerating cabinet, operating with forced air circulation, after the opening and closing of a door of the cabinet. In order to remove the coating, the speed of circulation of the air after closing of the door is temporarily increased until decomposition of the coating has taken place and thereafter is reduced back to the level required for normal cooling operation.
摘要翻译：公开了一种在打开和关闭门的门后，在强制空气循环操作的冷藏柜的玻璃板，特别是高隔热玻璃的内表面上除去雾涂层的方法。内阁。为了除去涂层，关闭门后空气的循环速度暂时增加，直到涂层发生分解，然后减小到正常冷却操作所需的水平。

3. 发明授权

US4327967A Heat-reflecting panel having neutral-color outer appearance 失效
标题翻译：具有中性色外观的热反射面板
公开(公告)号：US4327967A
公开(公告)日：1982-05-04
申请号：US158481
申请日：1980-06-11
申请人： Rolf Groth
发明人： Rolf Groth
IPC分类号： B32B15/04 , B32B9/00 , B32B17/06 , C03C17/06 , C03C17/36 , C03C27/12 , G02B5/08 , G02B5/28 , G02B17/00
CPC分类号： C03C17/3618 , C03C17/36 , C03C17/3628 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , G02B5/282 , C03C2217/734 , Y10S428/926 , Y10T428/12549 , Y10T428/12597 , Y10T428/12611 , Y10T428/12812 , Y10T428/12847 , Y10T428/12889 , Y10T428/12931
摘要： A heat-reflecting panel having a neutral-color outer appearance has a transparent film support, such as a glass pane, an interference film having a refractive index >2 disposed on the support, a heat reflecting gold film of a thickness of 70-105 A disposed on the side of the interference film remote from the support, and neutralization film formed from chromium, iron, nickel, titanium or alloys thereof, or an alloy of chromium, aluminium and iron, the neutralization film disposed on the side of the gold film remote from the interference film.
摘要翻译：具有中性色外观的热反射面板具有诸如玻璃板的透明膜支撑体，设置在支撑体上的折射率> 2的干涉膜，厚度为70-105的热反射金膜 A设置在远离支撑件的干涉膜侧，以及由铬，铁，镍，钛或其合金形成的中和膜，或铬，铝和铁的合金，中和膜设置在金的一侧影片远离干涉膜。

4. 发明授权

US3999039A Resistance heated vaporizer 失效
标题翻译：电阻加热蒸发器
公开(公告)号：US3999039A
公开(公告)日：1976-12-21
申请号：US533621
申请日：1974-12-17
申请人： Rolf Groth
发明人： Rolf Groth
IPC分类号： C23C14/26 , C23C13/12
CPC分类号： C23C14/26
摘要： A resistance-heated vaporizer for vacuum depositing thin metallic coatings on glass panes or the like is disclosed with at least one metal strip that is placed in spaced parallel relationship to the pane and connected to a source of electricity and with at least one relatively flat pocket provided on the metal strip facing the pane. The pocket is made of an electrically conductive and net-like material.
摘要翻译：公开了一种用于在玻璃板等上真空沉积薄金属涂层的电阻加热蒸发器，其具有至少一个金属带，该金属带与玻璃板间隔开并且连接到电源并且与至少一个相对平坦的袋提供在面向窗格的金属条上。口袋由导电和网状材料制成。

5. 发明授权

US4715879A Method for the manufacture of a tempered and/or curved glass pane with reduced transmission 失效
标题翻译：用于制造具有减小的透射率的回火和/或弯曲玻璃板的方法
公开(公告)号：US4715879A
公开(公告)日：1987-12-29
申请号：US927174
申请日：1986-11-05
申请人： Franz-Josef Schmitte , Dieter Muller , Rolf Groth
发明人： Franz-Josef Schmitte , Dieter Muller , Rolf Groth
IPC分类号： C03C17/36 , C03C17/00
CPC分类号： C03C17/3605 , C03C17/36 , C03C17/3613 , C03C17/3615 , C03C17/3618 , C03C17/3649 , C03C17/366 , C03C17/3681
摘要： Method for the manufacture of a prestressed and/or curved glass pane of soda-lime-silica glass having reduced transmission in a prescribable spectral range (in prescribable spectral ranges), in particular a sunshade pane, whereby at least one metal layer having a majority content of a metal or of a metal alloy from the elements having the atomic numbers 22 through 28 of the periodic table is applied to at least one side of a glass carrier and a protective layer of at least one metal oxide or mixed metal oxide is applied to that side thereof facing away from the glass carrier, and whereby a thermal prestressing and/or bending process is carried out in air at a temperature of 580.degree. C. through 680.degree. C., preferably 600.degree. C. through 650.degree. C., characterized in that both the metal layer as well as the protective layer are applied to the essentially planar glass carrier before the thermal prestressing and/or bending process; and in that the protective layer is applied with an oxygen deficit x, referrred to a metal atom of the metal oxide or, respectively, oxides, of 0.05.ltoreq.x.ltoreq.0.4 and in a thickness from 10 nm through 100 nm, being applied in such a composition that no noteworthy oxygen diffusion into the metal layer occurs during the prestressing and/or bending process.
摘要翻译：用于制造预处理和/或弯曲的钠钙石英玻璃的方法，其在规定的光谱范围（在规定的光谱范围内）具有降低的透射率，特别是遮阳板，其中至少一个具有多数的金属层将来自元素周期表的原子序数22至28的元素的金属或金属合金的含量施加到玻璃载体的至少一侧，并施加至少一种金属氧化物或混合金属氧化物的保护层在其一侧背离玻璃载体，由此在580℃至680℃，优选600℃至650℃的空气中进行热预应力和/或弯曲加工。其特征在于，在热预应力和/或弯曲过程之前，将金属层以及保护层都施加到基本平面的玻璃载体上; 并且其中保护层被施加有缺氧x，指的是金属氧化物的金属原子或分别为0.05≤x≤0.4且厚度为10nm至100nm的氧化物，应用于这样的组合物中，在预应力和/或弯曲过程中不会发生对金属层中的显着的氧扩散。

6. 发明授权

US4188452A Heat-reflecting glass pane 失效
标题翻译：热反射玻璃板
公开(公告)号：US4188452A
公开(公告)日：1980-02-12
申请号：US839938
申请日：1977-10-06
申请人： Rolf Groth
发明人： Rolf Groth
IPC分类号： C03C17/27 , C03C17/34 , C23C14/08 , G02B27/00 , B32B9/04
CPC分类号： C03C17/3417 , Y10T428/265 , Y10T428/2993
摘要： A heat reflecting pane comprises a substantially transparent glass substrate which has a layer of silicon oxide thereon and a layer of titanium dioxide in the rutile form on the side of the silicon oxide layer remote from the glass pane, the glass substrate having been toughened by heat treatment. The pane is formed by coating the glass substrate with a thin layer of silicon oxide, then applying a layer of titanium to the silicon oxide layer by vacuum deposition, the oxidizing the titanium at over 550.degree. C. to form titanium oxide in the rutile form.The silicon oxide layer prevents the rutile layer from becoming opaque when the pane is heated to the temperature necessary for heat treatment of the glass substrate, which may be during the heating step in which the titanium is oxidized or may be subsequently.
摘要翻译：热反射板包括基本上透明的玻璃基板，其上具有氧化硅层，并且在距离玻璃板的氧化硅层一侧具有金红石形式的二氧化钛层，玻璃基板已被加热而增韧治疗。通过用薄层氧化硅涂覆玻璃基板，然后通过真空沉积将一层钛施加到氧化硅层上形成窗格，在超过550℃下氧化钛以形成金红石形式的氧化钛。当将玻璃加热到玻璃基板的热处理所需的温度时，氧化硅层防止金红石层变得不透明，这可能是在钛被氧化或可能随后的加热步骤期间。

7. 发明授权

US3978273A Heat-reflecting window pane 失效
标题翻译：热反射窗
公开(公告)号：US3978273A
公开(公告)日：1976-08-31
申请号：US484609
申请日：1974-07-01
申请人： Rolf Groth
发明人： Rolf Groth
IPC分类号： C03C17/36 , G02B5/26 , G02B1/10 , B05D5/06
CPC分类号： C03C17/3615 , C03C17/36 , C03C17/3628 , C03C17/3644 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681
摘要： A heat reflecting window pane consisting of a laminate of a transparent support layer, an absorption layer, a silver reflecting layer and an anti-reflecting layer. A fifth layer of transparent material may also be provided.

8. 发明授权

US4857094A Method for the manufacture of a toughened and/or bent pane with solar control coating containing platinum or the like 失效
标题翻译：用于制造包含铂等的太阳能控制涂层的钢化和/或弯曲板的方法
公开(公告)号：US4857094A
公开(公告)日：1989-08-15
申请号：US241822
申请日：1988-09-06
申请人： Rolf Groth , Franz-Josef Schmitte
发明人： Rolf Groth , Franz-Josef Schmitte
IPC分类号： C03C17/36
CPC分类号： C03C17/3605 , C03C17/36 , C03C17/3649 , C03C17/366 , C03C17/3681
摘要： Method for the manufacture of a toughened and/or bent glass pane of soda-lime-silica glass with reduced transmission for solar radiation, in which to at least one side of the transparent glass carrier is applied a metal layer of platinum, iridium or optionally rhodium, alloys of these metals or metal alloys with a majority content of at least one of these metals in a thickness such that the light transmittance of the laminate formed from the glass carrier and the metal layer is between 10 and 90%, particularly between 30 and 90% of that of the glass carrier alone and a toughening and/or bending process is performed in air at a temperature of 580.degree. to 680.degree. C., preferably 600.degree. to 650.degree. C., whereby the metal layer is applied to the substantially flat glass carrier before the toughening and/or bending process and on the side of the metal layer remote from the glass carrier an oxide stabilizing layer from or with a majority content of at least one metal oxide or mixed metal oxide, preferably from the group Bi, In, Ni, Sb, Sn, Ta, Ti and Zn is applied with a thickness of 2 to 20 nm before the toughening and/or bending process.
摘要翻译：用于制造具有减少的太阳辐射传播的钠钙石英玻璃的增韧和/或弯曲玻璃板的方法，其中向透明玻璃载体的至少一侧施加铂，铱或任选的金属层铑，这些金属的合金或这些金属中的至少一种的大部分含量的金属合金，其厚度使得由玻璃载体和金属层形成的叠层的透光率为10至90％，特别是30 在空气中在580℃〜680℃，优选600〜650℃的温度下进行单独的玻璃载体的90％和增韧和/或弯曲加工，由此将金属层施加到在增韧和/或弯曲过程之前的金属层和远离玻璃载体的氧化物稳定层的至少一种金属氧化物或混合金属氧化物的大部分含量的基本平坦的玻璃载体，优选从Bi，In，Ni，Sb，Sn，Ta，Ti和Zn的厚度施加2〜20nm的增韧和/或弯曲加工之前。

9. 发明授权

US4497700A Method of coating a transparent substrate 失效
标题翻译：涂布透明基材的方法
公开(公告)号：US4497700A
公开(公告)日：1985-02-05
申请号：US592239
申请日：1984-03-22
申请人： Rolf Groth , Dieter Muller
发明人： Rolf Groth , Dieter Muller
IPC分类号： C03C17/36 , C23C14/00 , C23C15/00
CPC分类号： C03C17/3618 , C03C17/36 , C03C17/3644 , C03C17/3657 , C23C14/0036 , C03C2217/732
摘要： Optical filters, e.g. for reflecting infrared radiation while passing visible light radiation is made by applying to the silver reflective coating a protective coating of a metal oxide by magnetron cathode sputtering and only thereafter is the dereflective layer applied by magnetron cathode sputtering. The protective coating-oxygen partial pressure and coating rate are substantially less than the dereflective coating-oxygen partial pressure and coating rate. Apparently the protective coating prevents damage to the reflective coating.
摘要翻译：光学滤波器，例如用于通过可见光辐射反射红外辐射的方法是通过向银反射涂层施加磁控管阴极溅射的金属氧化物的保护涂层，然后仅通过磁控管阴极溅射施加的反射层。保护涂层 - 氧分压和涂布速率基本上小于反射涂层 - 氧分压和涂布速率。显然，保护涂层可防止对反射涂层的损坏。

10. 发明授权

US4216259A Heat reflecting pane and a method of producing it 失效
标题翻译：热反射板及其制作方法
公开(公告)号：US4216259A
公开(公告)日：1980-08-05
申请号：US000104
申请日：1979-01-02
申请人： Rolf Groth
发明人： Rolf Groth
IPC分类号： C03C17/27 , C23C14/16 , C23C14/58 , C03C17/22 , B05D3/02 , B05D3/04 , B05D5/06
CPC分类号： C23C14/16 , C03C17/27 , C23C14/58 , C23C14/5806 , C23C14/5853 , C03C2217/212 , C03C2218/151 , C03C2218/322 , Y10T428/24975
摘要： A heat-reflecting pane consists of a substantially transparent glass substrate with two layers of titanium oxide, the outside layer being in the rutile form with the intermediate layer being in the anatase form. The pane is formed by double coating the glass substrate with layers of titanium applied by vacuum deposition. A weaker vacuum is used to obtain the anatase form with a stronger vacuum used to obtain the rutile form. Both layers are then oxidized at temperatures of at least 550.degree. C. to form TiO.sub.2. The intermediate layer of TiO.sub.2 in the anatase form prevents the rutile layer from becoming opaque when the pane is heated to the temperature necessary for heat treatment of the glass substrate. The treatment may be effected either during the heating step in which the titanium is oxidized or in a subsequent additional heating step.
摘要翻译：热反射板由具有两层氧化钛的基本上透明的玻璃基板组成，外层为金红石型，中间层为锐钛型。该玻璃板通过双层涂覆玻璃基板与通过真空沉积施加的钛层而形成。使用较弱的真空度获得具有较强真空度的锐钛矿形式以获得金红石形式。然后将两个层在至少550℃的温度下氧化以形成TiO 2。当将玻璃板加热到玻璃基板的热处理所需的温度时，锐钛矿形式的TiO 2中间层防止金红石层变得不透明。处理可以在其中钛被氧化的加热步骤中或在随后的另外的加热步骤中进行。

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