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1. 发明申请

US20080280204A1 Method For The Production Of Nickel Oxide Surfaces Having Increase Conductivity 失效
标题翻译：增加电导率的氧化镍表面生产方法
公开(公告)号：US20080280204A1
公开(公告)日：2008-11-13
申请号：US11632790
申请日：2005-07-09
申请人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Holthuis , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
发明人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Holthuis , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
IPC分类号： H01M4/32 , H01B1/02 , H01M4/26
CPC分类号： C25B11/041 , H01M4/32 , H01M4/485 , H01M4/52 , H01M4/8817 , H01M4/8882 , H01M4/9016
摘要： The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to said method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, said process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to said method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.
摘要翻译：本发明涉及一种用于制造由含镍材料制成的导电氧化镍表面的方法。根据所述方法，镍表面首先脱脂，然后在含有约1％盐酸的溶液中粗糙化大约十分钟，所述方法通过加入过氧化氢溶液加速，导致电解质变绿。镍表面短暂润湿，将镍材料引入3.5摩尔碱液的溶液中，向其中加入约10％的过氧化氢并保存在其中10分钟，并将所得氢氧化镍表面在随后的热处理中脱水然后进一步氧化以获得氧化镍。本发明还涉及根据所述方法制备的导电边界层，其电极及其在氯碱电解过程中，在燃料电池和蓄电池中的应用。

2. 发明授权

US08057713B2 Method for the production of nickel oxide surfaces having increase conductivity 失效
标题翻译：用于生产具有增加的导电性的氧化镍表面的方法
公开(公告)号：US08057713B2
公开(公告)日：2011-11-15
申请号：US11632790
申请日：2005-07-09
申请人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Holthuis , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
发明人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Holthuis , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
IPC分类号： H01B1/02
CPC分类号： C25B11/041 , H01M4/32 , H01M4/485 , H01M4/52 , H01M4/8817 , H01M4/8882 , H01M4/9016
摘要： The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to the method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, the process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to the method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.
摘要翻译：本发明涉及一种用于制造由含镍材料制成的导电氧化镍表面的方法。根据该方法，首先将镍表面脱脂，然后在含有约1％盐酸的溶液中粗糙化约10分钟，通过加入过氧化氢溶液加速该过程，导致电解质变绿。镍表面短暂润湿，将镍材料引入3.5摩尔碱液的溶液中，向其中加入约10％的过氧化氢并保存在其中10分钟，并将所得氢氧化镍表面在随后的热处理中脱水然后进一步氧化以获得氧化镍。本发明还涉及根据该方法制造的导电边界层，其电极及其在氯碱电解过程中，在燃料电池和蓄电池中的用途。

3. 发明申请

US20080292944A1 Silver Gas Diffusion Electrode for Use in Air Containing Co2, and Method for the Production Thereof 审中-公开
标题翻译：用于含有CO 2的空气中的银气扩散电极及其制造方法
公开(公告)号：US20080292944A1
公开(公告)日：2008-11-27
申请号：US11632789
申请日：2005-07-09
申请人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
发明人： Roland Beckmann , Karl-Heinz Dulle , Peter Woltering , Randolf Kiefer , Frank Funck , Wolfram Stolp , Hans-Joachim Kohnke , Joachim Helmke
IPC分类号： H01M4/88 , H01M4/90
CPC分类号： H01M4/90 , H01M4/8605 , H01M4/8896 , H01M4/9075 , H01M8/0668 , H01M8/083 , Y02P70/56
摘要： The invention relates to a method for the production of a gas diffusion electrode from a silver catalyst on a PTFE-substrate. The pore system of the silver catalyst is filled with a moistening filling agent. A dimensionally stable solid body having a particle size greater than the particle size of the silver catalyst is mixed with the silver catalyst. Said compression-stable mass is formed in a first calendar in order to form a homogenous catalyst band. In a second calendar, an electroconductive discharge material is embossed in the catalyst band, and heating takes places between the first and the second calendar by means of a heating device, wherein at least parts of the moistened filling agent are eliminated. The invention also relates to a gas diffusion electrode which is produced according to said method.
摘要翻译：本发明涉及一种从PTFE基材上的银催化剂生产气体扩散电极的方法。银催化剂的孔体系填充润湿填充剂。将具有大于银催化剂粒度的粒径的尺寸稳定的固体与银催化剂混合。所述压缩稳定物质在第一历法中形成以形成均匀的催化剂带。在第二个日历中，导电放电材料在催化剂带中压花，并且通过加热装置在第一和第二压延机之间进行加热，其中至少部分润湿的填充剂被去除。本发明还涉及根据所述方法生产的气体扩散电极。

4. 发明授权

US06428665B1 Electrochemical gas sensor 失效
标题翻译：电化学气体传感器
公开(公告)号：US06428665B1
公开(公告)日：2002-08-06
申请号：US09425677
申请日：1999-10-12
申请人： Dejan Ilic , Konrad Holl , Joachim Helmke , Hans-Joachim Kohnke , August Winsel
发明人： Dejan Ilic , Konrad Holl , Joachim Helmke , Hans-Joachim Kohnke , August Winsel
IPC分类号： G01N27404
CPC分类号： G01N27/4045
摘要： An electrochemical gas sensor has a first gas diffusion electrode for a first reaction gas, which is inactive with respect to a second reaction gas at least in a first potential window, and a second gas diffusion electrode for the second reaction gas, which is active with respect to the second reaction gas at least in a second potential window for measuring two different gases in gas mixtures in a casing. The two gas diffusion electrodes are electronically isolated from one another, but electrically connected electrolytically to a reversibly loadable electrode and have contacts for connecting external closing circuits for adjusting the cell currents. The gas mixture is fed to the gas diffusion electrodes in series or parallel. The casing containing the electrodes is, in particular, in the form of a button cell. The reversibly loadable electrode is a Cu/CuO, Zn/ZnO or hydrogen electrode. The gas diffusion electrodes have a porous structure based on carbon or have a porous silver structure.
摘要翻译：电化学气体传感器具有用于第一反应气体的第一气体扩散电极，其至少在第一电位窗中相对于第二反应气体是无活性的，以及用于第二反应气体的第二气体扩散电极，其与至少在用于测量套管中的气体混合物中的两种不同气体的第二电势窗中的第二反应气体。两个气体扩散电极彼此电子隔离，但是电解电连接到可逆负载的电极，并且具有用于连接用于调节电池电流的外部闭合电路的触点。将气体混合物串联或并联地供给到气体扩散电极。包含电极的外壳特别是按钮式电池的形式。可逆负载电极是Cu / CuO，Zn / ZnO或氢电极。气体扩散电极具有基于碳的多孔结构或具有多孔银结构。

5. 发明申请

US20070119707A1 ELECTROLYZER 失效
标题翻译：电解液
公开(公告)号：US20070119707A1
公开(公告)日：2007-05-31
申请号：US11539497
申请日：2006-10-06
申请人： Joachim Helmke , Hans-Joachim Kohnke , Gabi Balan
发明人： Joachim Helmke , Hans-Joachim Kohnke , Gabi Balan
IPC分类号： C25B11/03
CPC分类号： C25B1/12 , C25B9/08 , Y02E60/366
摘要： An electrolysis cell includes an inner chamber containing a stack of porous anode and cathode plates with separators therebetween. Electrolyte is circulated through the porous anodes and cathodes in the inner chamber to generate hydrogen and oxygen gas. A plurality of electrolysis cells can be mounted together to form an electrolyzer unit.
摘要翻译：电解槽包括内室，该内室包含多孔阳极和阴极板的叠层，隔板之间具有隔板。电解液循环通过内腔中的多孔阳极和阴极，产生氢气和氧气。多个电解槽可以安装在一起形成电解槽单元。

6. 发明授权

US07651602B2 Electrolyzer 失效
标题翻译：电解液
公开(公告)号：US07651602B2
公开(公告)日：2010-01-26
申请号：US11539497
申请日：2006-10-06
申请人： Joachim Helmke , Hans-Joachim Kohnke , Gabi Balan
发明人： Joachim Helmke , Hans-Joachim Kohnke , Gabi Balan
IPC分类号： C25B15/08
CPC分类号： C25B1/12 , C25B9/08 , Y02E60/366
摘要： An electrolysis cell includes an inner chamber containing a stack of porous anode and cathode plates with separators therebetween. Electrolyte is circulated through the porous anodes and cathodes in the inner chamber to generate hydrogen and oxygen gas. A plurality of electrolysis cells can be mounted together to form an electrolyzer unit.
摘要翻译：电解槽包括内室，该内室包含多孔阳极和阴极板的叠层，隔板之间具有隔板。电解液循环通过内腔中的多孔阳极和阴极，产生氢气和氧气。多个电解槽可以安装在一起形成电解槽单元。

7. 发明申请

US20080257740A1 Electrolysis Cell Electrolyte Pumping System 审中-公开
标题翻译：电解槽电解液泵送系统
公开(公告)号：US20080257740A1
公开(公告)日：2008-10-23
申请号：US11718478
申请日：2005-11-02
申请人： Joachim Helmke , Gerhard Sauer
发明人： Joachim Helmke , Gerhard Sauer
IPC分类号： C25D21/12
CPC分类号： C25B15/08 , C25B1/12 , Y02E60/366
摘要： A system for pumping electrolyte through an electrolysis cell where the pressure of at least a portion of the gas generated by the electrolysis cell is used as driving force for the pumping. The system may include an electrolyte reservoir and a pumping chamber connected via an inlet conduit to receive electrolyte from the electrolysis cell and connected via an outlet conduit to flow electrolyte to the electrolysis cell. The pumping chamber is connected to the electrolysis cell to receive at least a portion of the gas generated by the electrolysis cell to elevate the pressure of the electrolyte therein and force it into the electrolysis cell.
摘要翻译：一种用于将电解质泵送通过电解池的系统，其中由电解池产生的至少一部分气体的压力用作泵送的驱动力。该系统可以包括经由入口管道连接的电解质储存器和泵送室，以从电解池接收电解质并经由出口导管连接以将电解质流动到电解槽。泵送室连接到电解池以接收由电解池产生的气体的至少一部分，以提升其中的电解质的压力并迫使其进入电解槽。

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