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1. 发明授权

US4230722A Dihalovinylcyclopropanethiolic acid esters and their use in pest control 失效
标题翻译：二卤乙烯基环丙硫醇酸酯及其在病虫害防治中的应用
公开(公告)号：US4230722A
公开(公告)日：1980-10-28
申请号：US49367
申请日：1979-06-18
申请人： Roger Malherbe , Daniel Bellus , Laurenz Gsell
发明人： Roger Malherbe , Daniel Bellus , Laurenz Gsell
IPC分类号： A01N37/14 , A01N53/00 , A01N53/08 , C07C327/10 , C07C327/20 , C07C327/22 , C07C153/023
CPC分类号： A01N53/00 , C07C327/00
摘要： Dihalovinylcyclopropanethiolic acid esters of the formula ##STR1## wherein X.sub.1 represents fluorine, chlorine or bromine, R.sub.1 represents hydrogen, methyl, ethynyl or cyano, and Y represents hydrogen, fluorine, chlorine or bromine, processes for their manufacture, and a method of controlling pests which comprises the use of these compounds.
摘要翻译：式（I）的二卤乙烯基环丙硫醇酸酯，其中X1表示氟，氯或溴，R1表示氢，甲基，乙炔基或氰基，Y表示氢，氟，氯或溴，其制备方法和方法控制害虫，包括使用这些化合物。

2. 发明授权

US4130656A Pesticidal 1-(phenyl)-cyclobutane-1-carboxylates 失效
标题翻译：杀虫剂1-（苯基） - 环丁烷-1-羧酸酯
公开(公告)号：US4130656A
公开(公告)日：1978-12-19
申请号：US818899
申请日：1977-07-25
申请人： Hans Greuter , Pierre Martin , Daniel Bellus , Laurenz Gsell , Willy Meyer
发明人： Hans Greuter , Pierre Martin , Daniel Bellus , Laurenz Gsell , Willy Meyer
IPC分类号： A01N37/10 , A01N37/38 , C07C67/00 , C07C69/753 , C07C253/00 , C07C255/38 , A01N9/20 , A01N9/24 , C07C69/76 , C07C121/75
CPC分类号： A01N37/10 , A01N37/38
摘要： Cyclobutane-1-carboxylates of the formula ##STR1## wherein R.sub.1 and R.sub.2 each represent hydrogen, fluorine, chlorine, bromine or methyl andR.sub.3 represents hydrogen, cyano or ethynyl, processes for producing them and their use in combating pests.
摘要翻译：其中R 1和R 2各自表示氢，氟，氯，溴或甲基，R 3表示氢，氰基或乙炔基的环丁烷-1-羧酸酯，其制备方法及其在防治害虫中的用途。

3. 发明授权

US07655650B2 Oxadiazine derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US07655650B2
公开(公告)日：2010-02-02
申请号：US11745550
申请日：2007-05-08
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A61K31/54 , C07D273/04
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：下式的化合物，其中A是未取代或单取代，四取代的，芳族的或非芳香的单环或双环杂环基，其中一至两个A的取代基可以选自卤代-C 1 -C 3烷基环丙基，卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3炔基，卤代-C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤代C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，，卤代烯硫基，氰基和硝基，A至1-4个取代基可以选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 3 -C 6环烷基，C 2 -C 6烯基或C 2 -C 6炔基; 且X为N-NO 2或N-CN，并且如果合适，其互变异构体（以每种形式为游离形式或盐形式）可用作农业化学活性成分，并且可以以本身已知的方式制备。

4. 发明申请

US20070219188A1 Oxadiazine Derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US20070219188A1
公开(公告)日：2007-09-20
申请号：US11745550
申请日：2007-05-08
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A61K31/5395 , C07D273/04
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中A是未取代或单 - 四取代的芳族或非芳族单环或双环杂环基的式的化合物，其中A的一个至两个取代基可以选自卤代-C C 1 -C 3烷基，环丙基，卤代环丙基，C 2 -C 3链烯基，C 2 - C 1 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3 - 炔基，炔基，卤代C 1 -C 3烷氧基，C 1 -C 3烷基，C 1 -C 3烷基，烷硫基，卤代-C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基的A可以选自C 1 -C 3 -C 3烷基，C 1 -C 3 - 烷基，C 1 -C 3 - 烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 1 -C 6烷基， C 3 -C 6环烷基，C 2 -C 6链烯基或C 2 - C 6炔基; 并且X为N-NO 2 N或N-CN，并且如果合适，其互变异构体（在每种情况下为游离形式或盐形式）均可用作农业化学活性成分，并且可以制备为本身已知的方式。

5. 发明授权

US5245040A Process for the preparation of nitroguanidine derivatives 失效
标题翻译：制备硝基胍衍生物的方法
公开(公告)号：US5245040A
公开(公告)日：1993-09-14
申请号：US777856
申请日：1991-10-16
申请人： Peter Maienfisch , Odd Kristiansen , Laurenz Gsell
发明人： Peter Maienfisch , Odd Kristiansen , Laurenz Gsell
IPC分类号： C07C277/00 , C07C279/32 , C07C279/36 , C07C323/44 , C07D213/36 , C07D213/40 , C07D213/61 , C07D213/89 , C07D233/64 , C07D239/26 , C07D251/08 , C07D261/08 , C07D263/32 , C07D265/06 , C07D265/30 , C07D265/32 , C07D271/04 , C07D271/06 , C07D271/08 , C07D273/00 , C07D273/04 , C07D277/20 , C07D277/32 , C07D279/06 , C07D279/12 , C07D285/00 , C07D285/18 , C07D285/34 , C07D307/52 , C07D333/20 , C07D401/06 , C07D401/14 , C07D417/06 , C07D471/04 , C07D498/04 , C07D513/04
CPC分类号： C07D213/40 , C07C279/36 , C07D213/61 , C07D213/89 , C07D251/08 , C07D277/32 , C07D401/06 , C07D401/14 , C07D417/06
摘要： A process for the preparation of 1,3-disubstituted 2-nitroguanidines of the formula I ##STR1## in which R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl or a radical --CH.sub.2 B; A is an unsubstituted or mono- to tetrasubstituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, which may contain one or two substituents from the group comprising C.sub.1 -C.sub.3 haloalkyl having 1 to 7 halogen atoms, cyclopropyl, halocyclopropyl having 1 to 3 halogen atoms, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, C.sub.2 -C.sub.3 haloalkenyl and C.sub.2 -C.sub.3 haloalkynyl having 1 to 4 halogen atoms, C.sub.1 -C.sub.3 haloalkoxy having 1 to 7 halogen atoms, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkylthio having 1 to 7 halogen atoms, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro and one to four substituents from the group comprising C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; and B is optionally substituted phenyl or pyridyl, which comprises hydrolysing a compound of the formula II ##STR2## in which R.sub.3 is unsubstituted or substituted C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.6 cycloalkyl, phenyl or benzyl.The compounds of the formula I are suitable as intermediates for the preparation of pesticides.
摘要翻译：制备式I的1,3-二取代2-硝基胍的方法，其中R 1是氢或C 1 -C 4烷基，R 2是氢，C 1 -C 6烷基，C 3 -C 6环烷基或基团-CH 2 B ; A是未取代的或单取代或四取代的芳族或非芳族单环或双环杂环基团，其可以含有一个或两个取代基，该取代基包括具有1至7个卤素原子的C 1 -C 3卤代烷基，环丙基，具有1至3个卤素的卤代环丙基 C 1 -C 3烯基，C 2 -C 3炔基，C 2 -C 3卤代烯基和具有1至4个卤素原子的C 2 -C 3卤代炔基，具有1至7个卤素原子的C 1 -C 3卤代烷氧基，C 1 -C 3烷硫基，具有1至7个卤素原子的C 1 -C 3卤代烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基，包括C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; 并且B是任选取代的苯基或吡啶基，其包括水解其中R 3为未取代或取代的C 1 -C 10烷基，C 3 -C 6环烷基，苯基或苄基的式II化合物（II）。式I的化合物适合作为制备农药的中间体。

6. 发明授权

US5063236A Pyridyl substituted guanidines useful as insecticides 失效
标题翻译：吡啶基取代的胍类作为杀虫剂有用
公开(公告)号：US5063236A
公开(公告)日：1991-11-05
申请号：US539297
申请日：1990-06-18
申请人： Laurenz Gsell
发明人： Laurenz Gsell
IPC分类号： C07D213/36 , A01N43/40 , A01N43/50 , A01N43/54 , A01N47/44 , C07D213/40 , C07D213/61 , C07D401/06
CPC分类号： C07D213/40 , A01N43/50 , A01N43/54 , A01N47/44 , C07D401/06
摘要： ##STR1## in which each of R
1 and R
3 , independently of the other, is hydrogen or C
1 -C
4 alkyl; R
2 is hydrogen, C
1 -C
4 alkyl, benzyl or picolyl; or R
2 and R
3 are together a -(CH
2 )
4 - or -(CH
2 )
5 - radical; X is halogen; and n is an integer 0, 1, 2 or 3; and the salts of compounds of formula I; with the execption of N-picolyl-N'-cyanoguanidine and N-picolyl-N'-methyl-N"-cyanoguanidine. Also described are processes fot the preparation of these compounds, the corresponding starting materials and intermediates, and the use of the novel compounds in pest control, especially for controlling insects and representatives of the order Acarina, particularly insect pests in rice crops.

7. 发明授权

US4963572A N-pyridyl methyl-N-'-cyanoisothiourea compounds useful in controlling insect pests 失效
标题翻译：可用于防治害虫的N-吡啶基甲基-N'-氰基异硫脲化合物
公开(公告)号：US4963572A
公开(公告)日：1990-10-16
申请号：US229209
申请日：1988-08-08
申请人： Laurenz Gsell
发明人： Laurenz Gsell
IPC分类号： A01N47/42 , C07D213/36 , C07D213/40 , C07D213/61
CPC分类号： C07D213/40
摘要： Novel substituted N-pyridylmethyl-N'-cyanoisothioureas of formula ##STR1## wherein R is C.sub.1 -C.sub.4 alkyl, cyclopropyl or benzyl; R.sub.1 is C.sub.1 -C.sub.4 alkyl or cyclopropyl; X is halogen; and n is the integer 0, 1, 2 or 3.Processes for the preparation of these compounds, the corresponding starting materials and intermediates and the use of the novel compounds in pest control, especially for controlling insects and representatives of the order Acarina, especially insect pests in rice crops, and as starting materials for the synthesis of novel pesticidal compositions are described.
摘要翻译：新颖的取代的N-吡啶基甲基-N'-氰基异硫脲，其结构式为：其中R为C1-C4烷基，环丙基或苄基; R1是C1-C4烷基或环丙基; X是卤素; 并且n是整数0,1,2或3.用于制备这些化合物的方法，相应的起始原料和中间体以及新型化合物在害虫防治中的用途，特别是用于防治昆虫和蜱螨纲的代表，特别是描述了水稻作物中的害虫，以及作为合成新型农药组合物的原料。

8. 发明授权

US4587255A Isomers of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid-.alpha.-methyl-(6-phenoxy-2-picolyl)ester, processes for producing them, and their use for controlling pests 失效
标题翻译： 3-（2,2-二氯乙烯基）-2,2-二甲基环丙烷甲酸-α-甲基 - （6-苯氧基-2-吡啶甲基）酯的异构体，其制备方法及其用于防治害虫
公开(公告)号：US4587255A
公开(公告)日：1986-05-06
申请号：US559544
申请日：1983-12-08
申请人： Peter Ackermann , Laurenz Gsell , Boris Kohler
发明人： Peter Ackermann , Laurenz Gsell , Boris Kohler
IPC分类号： A01N53/00 , A01N53/08 , C07D213/64 , C07D213/647 , A01N43/40
CPC分类号： C07D213/647 , A01N53/00
摘要： Novel isomers of the compound of the formula ##STR1## are described, and processes for producing these compounds and their use for controlling pests are given.
摘要翻译：描述了式“IMAGE”化合物的新异构体，并且给出了这些化合物的制备方法及其用于防治害虫的方法。

9. 发明授权

US4348408A Pesticidal .alpha.-allenyl-3-phenoxybenzyl-2,2-dimethyl-3-(2,2-dihalovinyl)-cyclopr opane-1-carboxylates 失效
标题翻译：杀虫α亚甲基-3-苯氧基苄基-2,2-二甲基-3-（2,2-二卤代乙烯基） - 环丙烷-1-羧酸酯
公开(公告)号：US4348408A
公开(公告)日：1982-09-07
申请号：US292080
申请日：1981-08-12
申请人： Peter Ackermann , Laurenz Gsell , Rudolf Wehrli
发明人： Peter Ackermann , Laurenz Gsell , Rudolf Wehrli
IPC分类号： A01N53/00 , C07C43/295 , C07C69/743
CPC分类号： A01N53/00 , C07C43/295
摘要： The invention describes cyclopropanecarboxylic acid .alpha.-allenyl-3-phenoxybenzyl esters of the formula ##STR1## wherein X.sub.1 is halogen and each of Y.sub.1 and Y.sub.2 is hydrogen or halogen, a process for the production of these compounds, and the use thereof for controlling a variety of pests of animals and plants. The intermediates of the formula ##STR2## wherein X is hydroxyl or halogen and each of Y.sub.1 and Y.sub.2 is hydrogen or halogen, are also described.
摘要翻译：本发明描述了下式的环丙烷羧酸α-亚环烷基-3-苯氧基苄基酯：其中X1是卤素，Y1和Y2各自是氢或卤素，这些化合物的制备方法及其用于控制各种动物和植物的害虫。还描述了其中X是羟基或卤素并且Y1和Y2中的每一个是氢或卤素的式“IMAGE”的中间体。

10. 发明授权

US4301304A 3-Phenoxy-.alpha.-(1',2'-dibromovinyl)-benxyl alcohol 失效
标题翻译： 3-苯氧基-α-（1'，2'-二溴乙烯基） - 丁醇
公开(公告)号：US4301304A
公开(公告)日：1981-11-17
申请号：US142496
申请日：1980-04-18
申请人： Jozef Drabek , Peter Ackermann , Saleem Farooq , Laurenz Gsell , Odd Kristiansen
发明人： Jozef Drabek , Peter Ackermann , Saleem Farooq , Laurenz Gsell , Odd Kristiansen
IPC分类号： C07C69/74 , A01N53/00 , A01N53/08 , C07C43/295 , C07C43/275
CPC分类号： C07C43/295 , A01N53/00
摘要： Cyclopropanecarboxylic acid-phenoxy-.alpha.-vinyl-benzyl esters of the formula ##STR1## in which Y is chlorine or bromine, and R.sub.1 is --CH.dbd.CH.sub.2 or ##STR2## processes for producing them, and their use in combating pests.
摘要翻译：其中Y为氯或溴，R1为-CH = CH2或的式为“IMAGE”的环丙烷羧酸 - 苯氧基-α-乙烯基 - 苄酯，用于制备它们，以及它们在防治害虫中的用途。

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