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1. 发明授权

US5264596A Isotactic poly(glycidyl nitrate) and synthesis thereof 失效
标题翻译：全同立构聚（硝酸缩水甘油酯）及其合成
公开(公告)号：US5264596A
公开(公告)日：1993-11-23
申请号：US928716
申请日：1992-08-13
申请人： Rodney L. Willer , Alfred G. Stern , Robert S. Day
发明人： Rodney L. Willer , Alfred G. Stern , Robert S. Day
IPC分类号： C07D303/16 , C08G65/22 , C08G65/28 , C07D303/36 , C07D301/00 , C08G65/10
CPC分类号： C08G65/22 , C07D303/16
摘要： Isotactic poly(glycidyl nitrate) useful in solid propellants is produced by polymerizing chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate. Chiral (R) glycidyl nitrate or its enantiomer is prepared by sequential treatment of chiral (S) glycidyl tosylate or its enantiomer with nitric acid and sodium hydroxide. Chiral (S) glycidyl tosylate or its enantiomer, (R) glycidyl tosylate, can be produced by Sharpless epoxidation of allyl alcohol or by direct tosylation or commercially available chiral glycidol. Likewise, chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate, can be prepared directly via nitration of (S) or (R) glycidol, respectively.
摘要翻译：可用于固体推进剂的全同立构聚（缩水甘油硝酸盐）是通过聚合手性（R）缩水甘油硝酸酯或其对映异构体，（S）硝酸缩水甘油酯来制备的。手性缩水甘油基硝酸酯或其对映异构体通过用硝酸和氢氧化钠顺序处理手性（S）缩水甘油基甲苯磺酸酯或其对映异构体来制备。手性（S）缩水甘油甲苯磺酸酯或其对映异构体，（R）缩水甘油甲苯磺酸酯可以通过烯丙醇的无稀释环氧化或通过直接甲苯磺酰化或商购手性缩水甘油来制备。同样地，手性（R）缩水甘油基硝酸酯或其对映体（S）缩水甘油基硝酸酯可以分别通过（S）或（R）缩水甘油的硝化直接制备。

2. 发明授权

US5232526A Diethanolammoniummethylcubane nitrates hydroxylammonium nitrate (HAN) solutions as aqueous liquid gun propellant ingredients 失效
标题翻译：二乙醇铵甲基丁烷硝酸盐硝酸铵（HAN）溶液作为水性液体枪推进剂成分
公开(公告)号：US5232526A
公开(公告)日：1993-08-03
申请号：US911937
申请日：1992-07-10
申请人： Rodney L. Willer , Alfred G. Stern
发明人： Rodney L. Willer , Alfred G. Stern
IPC分类号： C06B25/00 , C06B31/00 , C06B47/00 , C07C215/08
CPC分类号： C06B25/00 , C06B31/00 , C06B47/00 , C07C215/08 , C07C2103/90
摘要： This invention is for new compounds, namely, diethanolammoniummethylcubane nitrates, a composition of diethanolammonium methylcubyl nitrates - hydroxylammonium nitrate (HAN) solutions and their method of use as aqueous liquid gun propellant ingredients.
摘要翻译：本发明涉及新的化合物，即二乙醇铵甲基碳酸氢钠，二乙醇铵硝基甲酸铵 - 硝酸铵（HAN）溶液的组成及其作为水性液体枪推进剂成分的使用方法。

3. 发明授权

US5017356A Preparation of cyanogen from glyoxime 失效
标题翻译：从乙醛肟制备氰
公开(公告)号：US5017356A
公开(公告)日：1991-05-21
申请号：US526163
申请日：1990-05-21
申请人： Rodney L. Willer , Dennis Park , Alfred G. Stern
发明人： Rodney L. Willer , Dennis Park , Alfred G. Stern
IPC分类号： C01C3/00
CPC分类号： C01C3/003
摘要： Cyanogen is prepared from glyoxime by reaction with acetic anhydride to form N,N'-diacetoxyglyoxime which is then pyrolyzed to cyanogen.
摘要翻译：由乙醛与乙酸酐反应生成氰基，形成N，N'-二乙酰氧基乙二肟，然后将其热解成氰。

4. 发明授权

US5162494A Isotactic poly(glydicyl nitrate) and synthesis thereof 失效
标题翻译：异构聚（硝基甘氨酸）及其合成
公开(公告)号：US5162494A
公开(公告)日：1992-11-10
申请号：US609198
申请日：1990-11-05
申请人： Rodney L. Willer , Alfred G. Stern , Robert S. Day
发明人： Rodney L. Willer , Alfred G. Stern , Robert S. Day
IPC分类号： C07D303/16 , C08G65/22 , C08G65/28
CPC分类号： C08G65/22 , C07D303/16
摘要： Isotactic poly(glycidyl nitrate) useful in solid propellants is produced by polymerizing chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate. Chiral (R) glycidyl nitrate or its enantiomer is prepared by sequential treatment of chiral (S) glycidyl tosylate or its enantiomer with nitric acid and sodium hydroxide. Chiral (S) glycidyl tosylate or its enantiomer, (R) glycidyl tosylate, can be produced by Sharpless epoxidation of allyl alcohol or by direct tosylation of commercially available chiral glycidol. Likewise, chiral (R) glycidyl nitrate or its enantiomer, (S) glycidyl nitrate, can be prepared direcly via nitration of (S) or (R) glycidol, respectively.

5. 发明授权

US5120827A Process for producing improved poly(glycidyl nitrate) 失效
标题翻译：生产改性聚（甘氨酸）的方法
公开(公告)号：US5120827A
公开(公告)日：1992-06-09
申请号：US561797
申请日：1990-08-02
申请人： Rodney L. Willer , Robert S. Day , Alfred G. Stern
发明人： Rodney L. Willer , Robert S. Day , Alfred G. Stern
IPC分类号： C06B45/10 , C08G65/02 , C08G65/10 , C08G65/22 , C08G65/26 , C08G65/28 , C08G65/30
CPC分类号： C06B45/105 , C08G65/105 , C08G65/22 , C08G65/2654
摘要： An improved process for producing poly(glycidyl nitrate) having a functionality substantially equivalent to the hydroxy functionality of the initiator employed in which a catalyst-initiator complex is reacted with glycidyl nitrate and wherein the ratio of mols catalyst/mols hydroxyls in the initiator is

6. 发明授权

US07192649B1 Passivation layer on aluminum surface and method thereof 失效
标题翻译：铝表面钝化层及其制备方法
公开(公告)号：US07192649B1
公开(公告)日：2007-03-20
申请号：US10637090
申请日：2003-08-06
申请人： R. Jason Jouet , Alfred G. Stern , David M. Rosenberg
发明人： R. Jason Jouet , Alfred G. Stern , David M. Rosenberg
IPC分类号： B22F9/00 , B22F9/06 , B22F9/16
CPC分类号： B22F1/0062 , B22F9/30 , B22F2998/00 , B22F2998/10 , B82Y30/00 , Y10T428/12736 , Y10T428/2991 , Y10T428/2998 , Y10T428/31678 , B22F9/00 , B22F9/14 , B22F9/16 , B22F1/0088 , B22F2201/10
摘要： A protective passivation layer is formed on the surface of an aluminum mass, such as bare aluminum particles, creating a protected aluminum mass. Formation of the protective layer onto the aluminum mass may occur from an in-situ process.
摘要翻译：在诸如裸铝颗粒的铝质材料的表面上形成保护性钝化层，形成受保护的铝质量块。保护层在铝质块上的形成可以从原位过程发生。

7. 发明授权

US08853220B1 Synthesis of 2,6,9-tri-substituted-4,8-dinitro-2,6,9-triazabicyclo[3.3.1]nona-3,7-diene intermediates toward the preparation of polyaza-adamantanes 有权
标题翻译：合成2,6,9-三取代-4,8-二硝基-2,6,9-三氮杂双环[3.3.1]壬-3,7-二烯中间体制备多金属 - 金刚烷
公开(公告)号：US08853220B1
公开(公告)日：2014-10-07
申请号：US12932929
申请日：2011-02-25
申请人： Alfred G. Stern , Craig J. Diamond
发明人： Alfred G. Stern , Craig J. Diamond
IPC分类号： C07D487/08 , C07D487/18
CPC分类号： C07D487/18 , C07D487/08
摘要： The present invention relates to methods for synthesizing energetic compounds and intermediates thereof. Specifically, the present invention relates to methods for synthesizing adamantanes and intermediates that are useful in such synthesis. Synthesized intermediates are useful in the synthesis of bicyclic and tricyclic substituted adamantanes. Examples of various intermediates are: acyclic 2-nitromalonaldehyde intermediates, 2,6,9-tri-substituted-4,8-dinitro-2,6,9-triazabicyclo[3.3.1]nona-3,7-dienes and 2,6-dinitro-4,8,9,10-tetra-aza-4,8,9,10-tetra-substituted adamantanes. Intermediates synthesized according to the methods of the present invention are useful toward the synthesis of tetraaza-adamantanes, which can serve as precursors to potentially superior new high-energy-density compounds (HEDCs). The tricyclic intermediate compound has a structure of Formula III: where R is one of a benzyl, 4-methoxybenzyl, acetyl, nitro, formyl, allyl, and a carboethoxyl group.
摘要翻译：本发明涉及合成能量化合物的方法及其中间体。具体地，本发明涉及用于合成金刚烷和中间体的方法。合成的中间体可用于双环和三环取代的金刚烷的合成。各种中间体的实例是：无环2-硝基丙醛中间体，2,6,9-三取代-4,8-二硝基-2,6,9-三氮杂二环[3.3.1]壬-3,7-二烯和2， 6-二硝基-4,8,9,10-四氮杂-4,8,9,10-四取代金刚烷。根据本发明的方法合成的中间体可用于四氮杂 - 金刚烷的合成，四氮杂金刚烷可以作为潜在优异的新型高能密度化合物（HEDC）的前体。三环中间体化合物具有式III的结构：其中R是苄基，4-甲氧基苄基，乙酰基，硝基，甲酰基，烯丙基和羰乙氧基之一。

8. 发明授权

US5714714A Process for preparing ammonium dinitramide 失效
标题翻译：二硝酸铵制备方法
公开(公告)号：US5714714A
公开(公告)日：1998-02-03
申请号：US990116
申请日：1992-10-15
申请人： Alfred G. Stern , William M. Koppes , Michael E. Sitzmann , Lori A. Nock , Donna M. Cason-Smith
发明人： Alfred G. Stern , William M. Koppes , Michael E. Sitzmann , Lori A. Nock , Donna M. Cason-Smith
IPC分类号： C01B21/087 , C01C1/18 , C06B31/00 , C07C271/08 , D03D23/00
CPC分类号： C07C271/08 , C01B21/087 , C01C1/18 , C06B31/00 , Y10S149/122
摘要： A process for preparing ammonium dinitramide by: (1) nitrating either ethyl carbamate or methyl carbamate to form the corronding mononitrate compound, ethyl N-nitrocarbamate or methyl N-nitrocarbamate; (2) reacting the N-nitrocarbamate with ammonia under anhydrous conditions to produce the corresponding ammonium salt, ammonium ethyl N-nitrocarbamate or ammonium methyl N-nitrocarbamate; (3) nitrating the ammonium salt and then treating the reaction mixture with ammonia to produce ammonium dinitramide, ammonium nitrate, and regenerate the original ethyl carbamate or methyl carbamate compound.
摘要翻译：一种通过以下步骤制备二硝化铵铵的方法：（1）硝酸氨基甲酸酯或氨基甲酸甲酯形成相应的一硝酸酯化合物，N-硝基氨基甲酸乙酯或N-硝基氨基甲酸甲酯; （2）在无水条件下使N-硝基氨基甲酸铵与氨反应生成相应的铵盐，N-硝基氨基甲酸铵铵或N-硝基氨基甲酸铵铵; （3）硝化铵盐，然后用氨处理反应混合物，生成硝酸铵铵，再生原氨基甲酸乙酯或甲基氨基甲酸酯化合物。

9. 发明授权

US5380777A Polyglycidyl nitrate plasticizers 失效
标题翻译：聚缩水甘油基增塑剂
公开(公告)号：US5380777A
公开(公告)日：1995-01-10
申请号：US224098
申请日：1994-03-28
申请人： Rodney Willer , Alfred G. Stern , Robert S. Day
发明人： Rodney Willer , Alfred G. Stern , Robert S. Day
IPC分类号： C06B45/10 , C07C203/04 , C08G65/22 , C08G65/26 , C08G65/325 , C08G59/14 , C08K5/32 , C08L71/02
CPC分类号： C06B45/105 , C07C203/04 , C08G65/22 , C08G65/26 , C08G65/325
摘要： This invention is first, a difunctional poly(glycidyl nitrate) oligomer (PGN oligomer), second, nitrated PGN oligomer and third, the use of the nitrated PGN oligomer as a plasticizer, particularly as a plasticizer for binders used in and/or as energetic formulations. Examples of energetic formulations are propellants, pyrotechnics and explosives and other such compositions. More particularly, this invention is a difunctional poly(glycidyl nitrate) oligomer of the formula ##STR1## where n is 0 to 3, having a M.sub.n of from about 304 to about 994. Another embodiment is the nitrated difunctional poly(glycidyl nitrate) oligomer of the formula ##STR2## where n is 0 to 3, having a M.sub.n of from about 394 to about 1084. This invention also comprises a plasticizer for binder compounds, namely, the nitrated PGN oligomer above; preferably the plasticizer above is used wherein the binder compound is used in energetic formulations; and preferably the binder compound is an energetic compound; more preferably the energetic formulation is selected from the group consisting of propellants, pyrotechnics and explosives.
摘要翻译：本发明首先是二官能聚（缩水甘油基硝酸酯）低聚物（PGN低聚物），第二种硝化PGN低聚物，第三种是使用硝化PGN低聚物作为增塑剂，特别是作为用于和/或作为能量的粘合剂的增塑剂配方。能量制剂的实例是推进剂，烟火和爆炸物以及其它这样的组合物。更具体地说，本发明是具有约304至约994的Mn的式“IMAGE”的二官能聚（缩水甘油基硝酸酯）低聚物，其中n为0-3。另一个实施方案是硝化双官能聚（缩水甘油基硝酸酯）低聚物其中n为0至3，Mn为约394至约1084。本发明还包含用于粘合剂化合物的增塑剂，即上述硝化PGN低聚物; 优选使用上述增塑剂，其中粘合剂化合物用于能量制剂中; 并且优选地，粘合剂化合物是能量化合物; 更优选地，能量制剂选自由推进剂，烟火和炸药组成的组。

10. 发明授权

US08895736B1 Synthesis of substituted 2-nitromalonaldehyde intermediates toward the preparation of polyaza-adamantanes 有权
标题翻译：取代的2-硝基醛醛中间体合成制备多金属 - 金刚烷
公开(公告)号：US08895736B1
公开(公告)日：2014-11-25
申请号：US12932930
申请日：2011-02-25
申请人： Alfred G. Stern , Craig J. Diamond
发明人： Alfred G. Stern , Craig J. Diamond
IPC分类号： C07D239/06 , C07D487/08
CPC分类号： C07D239/06 , C07C251/08 , C07D487/08
摘要： The present invention relates to methods for synthesizing energetic compounds and intermediates thereof. Specifically, the present invention relates to methods for synthesizing adamantanes and intermediates that are useful in such synthesis. Synthesized intermediates are useful in the synthesis of bicyclic and tricyclic substituted adamantanes. Examples of various intermediates are: acyclic 2-nitromalonaldehyde intermediates, 2,6,9-tri-substituted-4,8-dinitro-2,6,9-triazabicyclo[3.3.1]nona-3,7-dienes and 2,6-dinitro-4,8,9,10-tetra-aza-4,8,9,10-tetra-substituted adamantanes. Intermediates synthesized according to the methods of the present invention are useful toward the synthesis of tetraaza-adamantanes, which can serve as precursors to potentially superior new high-energy-density compounds (HEDCs).
摘要翻译：本发明涉及合成能量化合物的方法及其中间体。具体地，本发明涉及用于合成金刚烷和中间体的方法。合成的中间体可用于双环和三环取代的金刚烷的合成。各种中间体的实例是：无环2-硝基丙醛中间体，2,6,9-三取代-4,8-二硝基-2,6,9-三氮杂二环[3.3.1]壬-3,7-二烯和2， 6-二硝基-4,8,9,10-四氮杂-4,8,9,10-四取代金刚烷。根据本发明的方法合成的中间体可用于四氮杂 - 金刚烷的合成，四氮杂金刚烷可以作为潜在优异的新型高能密度化合物（HEDC）的前体。

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