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    • 5. 发明申请
    • HYBRID IN-SITU DRY CLEANING OF OXIDIZED SURFACE LAYERS
    • 氧化表面层的混合干燥清洁
    • US20110212274A1
    • 2011-09-01
    • US12714152
    • 2010-02-26
    • Adam SelsleyFrank M. Cerio, JR.
    • Adam SelsleyFrank M. Cerio, JR.
    • B05D3/10
    • C23C14/5826
    • According to one embodiment, the method includes providing a substrate containing a metal-containing barrier layer having an oxidized surface layer, exposing the oxidized surface layer to a flow of a first process gas containing plasma-excited argon gas to activate the oxidized surface layer and applying substrate bias power during the exposing of the oxidized surface layer to the flow of the first process gas. The method further includes exposing the activated oxidized surface layer to a second process gas containing non-plasma-excited hydrogen gas, wherein the exposure to the first process gas, in addition to activating the oxidized surface layer, facilitates chemical reduction of the activated oxidized surface layer by the second process gas containing the hydrogen gas. A thickness of the metal-containing barrier layer is not substantially changed by the hybrid in-situ dry cleaning process.
    • 根据一个实施方案,该方法包括提供含有含氧化表面层的含金属阻挡层的基材,将氧化表面层暴露于含有等离子体激发的氩气的第一工艺气体的流动以活化氧化的表面层;以及 在将氧化的表面层暴露于第一工艺气体的流动期间施加衬底偏置功率。 该方法还包括将活化的氧化表面层暴露于含有非等离子体激发的氢气的第二工艺气体,其中暴露于第一工艺气体除了活化氧化的表面层之外,还促进活化的氧化表面的化学还原 通过含有氢气的第二工艺气体层。 通过混合原位干洗方法,实质上不能改变含金属阻挡层的厚度。