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1. 发明申请

US20080076832A1 Clay Comprising Charge-Balancing Organic Ions And Nanocomposite Materials Comprising The Same 审中-公开
标题翻译：包含电荷平衡有机离子和纳米复合材料的粘土包括它
公开(公告)号：US20080076832A1
公开(公告)日：2008-03-27
申请号：US11792201
申请日：2005-11-17
申请人： Robin Winters , Siebe De Vos , Elwin Schomaker
发明人： Robin Winters , Siebe De Vos , Elwin Schomaker
IPC分类号： C08G79/10 , B01J20/26 , C08J9/00 , C11D17/00 , C09K8/035 , C08F283/00
CPC分类号： C01B33/44 , C01F7/005 , C01P2002/22 , C01P2002/78
摘要： The invention relates to clays comprising charge-balancing organic ions wherein at least part of the organic ions are rosin-based ions. The invention further pertains to a hybrid organic-inorganic composite material comprising a polymer matrix and a clay comprising charge-balancing organic ions wherein at least part of the organic ions are rosin-based ions.
摘要翻译：本发明涉及包含电荷平衡有机离子的粘土，其中至少部分有机离子是基于松香的离子。本发明还涉及包含聚合物基质和包含电荷平衡有机离子的粘土的杂化有机 - 无机复合材料，其中至少部分有机离子是松香基离子。

2. 发明授权

US07968740B2 Process for preparing organically modified layered double hydroxide 失效
标题翻译：制备有机改性层状双氢氧化物的方法
公开(公告)号：US07968740B2
公开(公告)日：2011-06-28
申请号：US12096433
申请日：2006-12-01
申请人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriëtte Zijtveld-Van Der Wiel
发明人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriëtte Zijtveld-Van Der Wiel
IPC分类号： C07F5/06
CPC分类号： C01F7/005 , C01B13/363 , C01F7/002 , C01P2002/22 , C01P2002/78
摘要： A process is disclosed for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of about 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) solvothermally treating the precursor suspension to obtain a double layered hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that deoxycholic acid is not the sole organic anion.
摘要翻译：公开了一种制备有机改性的层状双氢氧化物的方法，其具有约1.5nm的层状双氢氧化物的各层之间的距离，并且包含作为电荷平衡阴离子的有机阴离子，该方法包括以下步骤：（a）制备包含二价金属离子源和三价金属离子源的前体悬浮液; （b）溶剂化处理前体悬浮液以获得双层氢氧化物，其中在步骤（b）的层状双氢氧化物的形成之前或期间，或在形成层状双氢氧化物之后加入有机阴离子，以便获得有机改性的层状双氢氧化物，条件是脱氧胆酸不是唯一的有机阴离子。

3. 发明申请

US20080300352A1 Process for Preparing Organically Modified Layered Double Hydroxide 失效
标题翻译：制备有机改性层状双氢氧化物的方法
公开(公告)号：US20080300352A1
公开(公告)日：2008-12-04
申请号：US12096485
申请日：2006-12-04
申请人： Elwin Schomaker , Robin Winters
发明人： Elwin Schomaker , Robin Winters
IPC分类号： C07C29/70 , C08K5/05 , C07C31/30
CPC分类号： C01F7/005 , C01B13/363 , C01P2002/22
摘要： The invention relates to a process for preparing a layered double hydroxide comprising a charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension or solution comprising a divalent metal ion source, a trivalent metal ion source, water, and a solvent which is miscible with water and in which at least 5 g/l of a charge-balancing anion precursor can be dissolved; (b) treating the precursor suspension or solution to obtain the layered double hydroxide, wherein the charge-balancing anion precursor is added to the suspension or solution before, during or after step (b), and wherein, if the charge-balancing anion is an organic anion, less than 50 wt % of the charge-balancing anion precursors, based on the total weight of charge-balancing anion precursors, is a salt, with the proviso that the charge-balancing anion is not carbonate. The invention further pertains to a layered double hydroxide obtainable by this process.
摘要翻译：本发明涉及一种制备包含电荷平衡阴离子的层状双氢氧化物的方法，该方法包括以下步骤：（a）制备包含二价金属离子源，三价金属离子源，水，和与水混溶并且其中可以溶解至少5g / l的电荷平衡阴离子前体的溶剂; （b）处理前体悬浮液或溶液以获得层状双氢氧化物，其中在步骤（b）之前，期间或之后将电荷平衡阴离子前体加入到悬浮液或溶液中，并且其中如果电荷平衡阴离子是基于电荷平衡阴离子前体的总重量，少于50重量％的电荷平衡阴离子前体的有机阴离子是盐，条件是电荷平衡阴离子不是碳酸盐。本发明还涉及通过该方法可获得的层状双氢氧化物。

4. 发明申请

US20080293957A1 Process for Preparing Organically Modified Layered Double Hydroxide 失效
标题翻译：制备有机改性层状双氢氧化物的方法
公开(公告)号：US20080293957A1
公开(公告)日：2008-11-27
申请号：US12096433
申请日：2006-12-01
申请人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriette Zijtveld-Van Der Wiel
发明人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos , Marianne Frederika Reedijk , Johanna Henriette Zijtveld-Van Der Wiel
IPC分类号： C07F5/06
CPC分类号： C01F7/005 , C01B13/363 , C01F7/002 , C01P2002/22 , C01P2002/78
摘要： The invention relates to a process for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of above 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) solvothermally treating the precursor suspension to obtain the layered double hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that deoxycholic acid is not the sole organic anion. The invention further pertains to a process for preparing an organically modified layered double hydroxide having a distance between the individual layers of the layered double hydroxide of above 1.5 nm and comprising an organic anion as charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension comprising a divalent metal ion source and a trivalent metal ion source; (b) thermally treating the precursor suspension to obtain the layered double hydroxide, wherein an organic anion is added before or during the formation of the layered double hydroxide of step (b), or following the formation of the layered double hydroxide, so as to obtain the organically modified layered double hydroxide, with the proviso that in step a) the trivalent metal ion source is not reacted with the organic anion at a temperature of between 60 and 85° C. for 4 to 8 hours prior to the addition of the divalent metal ion source and step b) is subsequently carried out at a temperature of 90 to 95° C. for 4 to 8 hours.
摘要翻译：本发明涉及一种制备有机改性层状双氢氧化物的方法，其具有1.5nm以上层状双氢氧化物的各层之间的距离，并且包含作为电荷平衡阴离子的有机阴离子，该方法包括以下步骤：（a ）制备包含二价金属离子源和三价金属离子源的前体悬浮液; （b）溶剂化处理前体悬浮液以获得层状双氢氧化物，其中在形成步骤（b）的层状双氢氧化物之前或阶段期间加入有机阴离子，或在形成层状双氢氧化物之后加入有机阴离子，以便获得有机改性的层状双氢氧化物，条件是脱氧胆酸不是唯一的有机阴离子。本发明还涉及一种制备有机改性的层状双氢氧化物的方法，其具有1.5nm以上层状双氢氧化物的各层之间的距离，并且包含有机阴离子作为电荷平衡阴离子，该方法包括以下步骤：（ a）制备包含二价金属离子源和三价金属离子源的前体悬浮液; （b）热处理前体悬浮液以获得层状双氢氧化物，其中在步骤（b）的层状双氢氧化物形成之前或期间，或在形成层状双氢氧化物之后加入有机阴离子，以便获得有机改性的层状双氢氧化物，条件是在步骤a）中，三价金属离子源在有机阴离子之间在60至85℃的温度下不与有机阴离子反应4至8小时，然后加入二价金属离子源和步骤b）随后在90至95℃的温度下进行4至8小时。

5. 发明申请

US20080293849A1 Nanocomposite Material Comprising Rubber and Modified Layered Double Hydroxide, Process for Its Preparation and Use Thereof 审中-公开
标题翻译：包含橡胶和改性层状双氢氧化物的纳米复合材料，其制备和使用方法
公开(公告)号：US20080293849A1
公开(公告)日：2008-11-27
申请号：US12096455
申请日：2006-12-01
申请人： Robin Winters , Haimo Tonnaer , Elwin Schomaker
发明人： Robin Winters , Haimo Tonnaer , Elwin Schomaker
IPC分类号： C08J3/22 , C08F36/00 , C08F36/06 , C08L21/00
CPC分类号： C08J3/226 , C08J2421/00 , C08K5/548 , C08K9/04 , C08L21/00
摘要： The present invention pertains to a nanocomposite material comprising rubber and a modified layered double hydroxide comprising: a charge-balancing organic ion having a first functional group and a second functional group, wherein at least part of the organic anions is chemically linked to the rubber through the second functional group; and/or a silane coupling agent having at least one alkoxysilane group and at least one reactive group, at least one alkoxysilane group being chemically linked to the layered double hydroxide, at least one reactive group being chemically linked to the rubber. The invention further pertains to a process for preparing the nanocomposite material or a precursor thereof.
摘要翻译：本发明涉及包含橡胶和改性层状双氢氧化物的纳米复合材料，其包含：具有第一官能团和第二官能团的电荷平衡有机离子，其中至少部分有机阴离子通过化学连接到橡胶第二功能组; 和/或具有至少一个烷氧基硅烷基团和至少一个反应性基团的硅烷偶联剂，至少一个烷氧基硅烷基团与层状双氢氧化物化学连接，至少一个与橡胶化学连接的反应性基团。本发明还涉及制备纳米复合材料或其前体的方法。

6. 发明申请

US20080311410A1 Clay Comprising Charge-Balancing Organic Ions and Nanocomposite Materials Comprising the Same 审中-公开
标题翻译：包含电荷平衡有机离子和纳米复合材料的粘土
公开(公告)号：US20080311410A1
公开(公告)日：2008-12-18
申请号：US12096442
申请日：2006-12-01
申请人： Elwin Schomaker , Robin Winters , Siebe Cornelis De Vos
发明人： Elwin Schomaker , Robin Winters , Siebe Cornelis De Vos
IPC分类号： B32B9/00 , C08J3/22
CPC分类号： C01F7/005 , C01B13/363 , C01F7/002 , C01P2002/22 , C01P2002/78 , C01P2004/61
摘要： The invention relates to a layered double hydroxide having a distance between the individual layers of the layered double hydroxide of above 1.5 nm and comprising 2 or more charge-balancing organic anions having 8 or more carbon atoms, wherein at least 2 of the organic anions have a different number of carbon atoms, and wherein less than 10% of the total of charge-balancing anions are charge-balancing organic anions having 2 or more anionic groups.
摘要翻译：本发明涉及层状双氢氧化物，其具有1.5nm以上的层状双氢氧化物的各层之间的距离，并且包含具有8个或更多个碳原子的2个或更多个电荷平衡有机阴离子，其中至少2个有机阴离子具有不同数量的碳原子，并且其中小于10％的电荷平衡阴离子是具有2个或更多个阴离子基团的电荷平衡有机阴离子。

7. 发明申请

US20110003719A1 POLYMER-CONTAINING COMPOSITION, ITS PREPARATION AND USE 审中-公开
标题翻译：含聚合物的组合物，其制备和使用
公开(公告)号：US20110003719A1
公开(公告)日：2011-01-06
申请号：US12918926
申请日：2009-03-09
申请人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos
发明人： Robin Winters , Elwin Schomaker , Siebe Cornelis De Vos
IPC分类号： C08G63/08 , C08L67/00 , C08L23/00 , C08L69/00 , C08L5/00 , C09D11/10 , C11D3/37 , C09K8/24 , C04B26/18 , D21H17/46
CPC分类号： C08L51/003 , C08G63/08 , C08G63/823 , C08L51/06 , C08L51/08 , C08L67/04 , C08L101/00 , C08L2666/02 , C09D151/003 , C09D151/06 , C09D151/08 , C09J151/003 , C09J151/06 , C09J151/08
摘要： Process for the preparation of a polymer-containing composition comprising the steps of: a) preparing a mixture of at least one cyclic monomer selected from glycolide and lactide and a layered double hydroxide comprising as charge-balancing anions 10 to 100% of an organic anion and 0 to 90% of hydroxide, based on the total amount of charge-balancing anions, and b) polymerising said monomer, optionally in the presence of a polymerisation initiator or catalyst.
摘要翻译：制备含聚合物的组合物的方法，包括以下步骤：a）制备选自乙交酯和丙交酯的至少一种环状单体和包含作为电荷平衡阴离子的10-50％有机阴离子的层状双氢氧化物的混合物和0至90％的氢氧化物，基于电荷平衡阴离子的总量，和b）任选地在聚合引发剂或催化剂存在下聚合所述单体。

8. 发明授权

US07786202B2 Process for preparing organically modified layered double hydroxide 失效
标题翻译：制备有机改性层状双氢氧化物的方法
公开(公告)号：US07786202B2
公开(公告)日：2010-08-31
申请号：US12096485
申请日：2006-12-04
申请人： Elwin Schomaker , Robin Winters
发明人： Elwin Schomaker , Robin Winters
IPC分类号： C08K5/05
CPC分类号： C01F7/005 , C01B13/363 , C01P2002/22
摘要： The invention relates to a process for preparing a layered double hydroxide comprising a charge-balancing anion, the process comprising the steps of: (a) preparing a precursor suspension or solution comprising a divalent metal ion source, a trivalent metal ion source, water, and a solvent which is miscible with water and in which at least 5 g/l of a charge-balancing anion precursor can be dissolved; (b) treating the precursor suspension or solution to obtain the layered double hydroxide, wherein the charge-balancing anion precursor is added to the suspension or solution before, during or after step (b), and wherein, if the charge-balancing anion is an organic anion, less than 50 wt % of the charge-balancing anion precursors, based on the total weight of charge-balancing anion precursors, is a salt, with the proviso that the charge-balancing anion is not carbonate. The invention further pertains to a layered double hydroxide obtainable by this process.
摘要翻译：本发明涉及一种制备包含电荷平衡阴离子的层状双氢氧化物的方法，该方法包括以下步骤：（a）制备包含二价金属离子源，三价金属离子源，水，和与水混溶并且其中可以溶解至少5g / l的电荷平衡阴离子前体的溶剂; （b）处理前体悬浮液或溶液以获得层状双氢氧化物，其中在步骤（b）之前，期间或之后将电荷平衡阴离子前体加入到悬浮液或溶液中，并且其中如果电荷平衡阴离子是基于电荷平衡阴离子前体的总重量，少于50重量％的电荷平衡阴离子前体的有机阴离子是盐，条件是电荷平衡阴离子不是碳酸盐。本发明还涉及通过该方法可获得的层状双氢氧化物。

9. 发明申请

US20100179249A1 PROCESS FOR MODIFYING INORGANIC OXYGEN-CONTAINING PARTICULATE MATERIAL, PRODUCT OBTAINED THEREFROM, AND USE THEREOF 有权
标题翻译：无机含氧含颗粒材料的制备方法及其获得的产品及其用途
公开(公告)号：US20100179249A1
公开(公告)日：2010-07-15
申请号：US11993785
申请日：2006-06-16
申请人： Elwin Schomaker , Rudolf Anthonius Maria Venderbosch
发明人： Elwin Schomaker , Rudolf Anthonius Maria Venderbosch
IPC分类号： C08K9/00
CPC分类号： C09D5/033 , C08L71/02 , C09D143/04 , Y02P20/582
摘要： The present invention pertains to a process for preparing a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of an aqueous suspension of inorganic oxygen-containing particulate material and an alkoxylated alcohol according to the formula (I) wherein R1 is a C1-C8 alkyl, C4-C8 cycloalkyl or phenyl, R2 is hydrogen or methyl, and n is an integer from 1 to 5; b) optionally adding a first resin and/or a first resin precursor; c) adding one or more coupling agents to the mixture; d) optionally adding a second resin and/or a second resin precursor to the resulting mixture; and wherein optionally water is removed at least partially from the mixture before or during step b), c) or d), or after step d); and optionally converting the first resin precursor into the first resin before, during or after step c) and/or the second resin precursor into the second resin after step d).
摘要翻译：本发明涉及一种制备改性无机含氧颗粒材料的方法，包括以下步骤：a）制备根据式（I）的无机含氧颗粒材料的水悬浮液和烷氧基化醇的混合物，其中 R 1是C 1 -C 8烷基，C 4 -C 8环烷基或苯基，R 2是氢或甲基，n是1至5的整数; b）任选地加入第一树脂和/或第一树脂前体; c）向混合物中加入一种或多种偶联剂; d）任选地向所得混合物中加入第二树脂和/或第二树脂前体; 并且其中任选地在步骤b），c）或d）之前或之后或在步骤d）之后或之后至少部分地从混合物中除去水。并且在步骤d）之后，在步骤c）和/或第二树脂前体之前，期间或之后，任选地将第一树脂前体转化为第二树脂。

10. 发明申请

US20090101205A1 PROCESS FOR PREPARING A RUBBER COMPOSITION, RUBBER COMPOSITION OBTAINED THEREFROM, AND USE THEREOF 审中-公开
标题翻译：制备橡胶组合物的方法，其获得的橡胶组合物及其用途
公开(公告)号：US20090101205A1
公开(公告)日：2009-04-23
申请号：US12293393
申请日：2007-03-14
申请人： Rudolf Anthonius Maria Venderbosch , Elwin Schomaker , Auke Gerardus Talma
发明人： Rudolf Anthonius Maria Venderbosch , Elwin Schomaker , Auke Gerardus Talma
IPC分类号： H01L31/00 , C08K3/18 , C08K5/06
CPC分类号： C08K9/04 , C08K3/36 , C08K7/18 , C08L21/00 , C08L83/04
摘要： The present invention pertains to a process for preparing a rubber precursor or a rubber composition comprising a modified inorganic oxygen-containing particulate material comprising the steps of: a) preparing a mixture of the modified inorganic oxygen-containing particulate material and a first solvent; and b1) adding the mixture to a rubber precursor comprising at least one polymer and optionally a second solvent; or b2) adding the mixture to a rubber composition comprising at least one monomer of a rubber precursor and optionally a second solvent, and polymerising the monomer(s) to form the rubber precursor; c) optionally cross-linking the rubber precursor in the presence of a cross-linking agent to form a rubber composition; and d) optionally removing the first and/or second solvents before, during or after any of the steps b1), b2), and c). The invention further pertains to rubber compositions comprising rubber and inorganic oxygen-containing particulate material modified with a coupling agent.
摘要翻译：本发明涉及一种制备橡胶前体或包含改性无机含氧颗粒材料的橡胶组合物的方法，包括以下步骤：a）制备改性无机含氧颗粒材料和第一溶剂的混合物; 和b1）将混合物加入到包含至少一种聚合物和任选的第二溶剂的橡胶前体中; 或b2）将混合物加入到包含橡胶前体和任选的第二溶剂的至少一种单体的橡胶组合物中，并聚合单体以形成橡胶前体; c）任选地在交联剂存在下交联橡胶前体以形成橡胶组合物; 和d）在任何步骤b1），b2）和c）之前，期间或之后任选地除去第一和/或第二溶剂。本发明还涉及包含用偶联剂改性的橡胶和无机含氧颗粒材料的橡胶组合物。

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