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1. 发明授权

US6160191A Hydrocarbon conversion using large crystal zeolite catalyst 有权
标题翻译：使用大型晶体沸石催化剂的烃转化
公开(公告)号：US6160191A
公开(公告)日：2000-12-12
申请号：US384942
申请日：1999-08-27
申请人： Robert Scott Smith , Johannes Petrus Verduijn, deceased , by Jannetje Maatje van den Berge, executrix , Gary David Mohr , Thomas Herman Colle
发明人： Robert Scott Smith , Johannes Petrus Verduijn, deceased , by Jannetje Maatje van den Berge, executrix , Gary David Mohr , Thomas Herman Colle
IPC分类号： B01J29/06 , C01B39/02 , C01B39/04 , C07C2/66 , C07C4/06 , C07C5/27 , C07C5/41 , C07C6/12 , C07C15/08 , C10G11/05 , C10G29/20 , C10G35/095 , C10G45/64 , C07C5/22 , C10G11/02 , C10G47/00 , C10G47/12
CPC分类号： C10G45/64 , C01B39/02 , C01B39/04 , C07C2/66 , C07C4/06 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , C07C2529/18 , C07C2529/50 , C07C2529/65 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/095 , C07C15/00
摘要： A process for converting hydrocarbons by contacting a hydrocarbon feedstream under hydrocarbon conversion conditions with a large crystal zeolite catalyst. The large crystal zeolite of the catalyst used in the hydrocarbon conversion process is made by heating an aqueous zeolite synthesis mixture under agitation to a temperature equal to or less than the effective nucleation temperature of the synthesis mixture. After this step, the aqueous synthesis mixture is heated in the absence of agitation to a temperature equal to or greater than the effective nucleation temperature of the aqueous zeolite synthesis mixture. The process finds particular application in hydrocarbon conversion processes where reduced non-selective acidity is important for reaction selectivity and/or the maintenance of catalyst activity, e.g., toluene disproportionation, dealkylation, alkylation, and transalkylation.
摘要翻译：一种通过在烃转化条件下与烃类进料流与大型晶体沸石催化剂接触来转化烃的方法。在烃转化过程中使用的催化剂的大晶体沸石是通过在搅拌下将沸石合成混合物加热到等于或小于合成混合物的有效成核温度的温度来制备的。在该步骤之后，将水性合成混合物在不加搅拌的条件下加热到等于或大于沸石合成混合物的有效成核温度的温度。该方法在烃转化方法中具有特殊应用，其中降低的非选择性酸度对于反应选择性和/或维持催化剂活性，例如甲苯歧化，脱烷基化，烷基化和烷基转移是重要的。

2. 发明授权

US5958366A Synthesis of large crystal zeolites 失效
标题翻译：大型晶体沸石的合成
公开(公告)号：US5958366A
公开(公告)日：1999-09-28
申请号：US954341
申请日：1997-10-17
申请人： Robert Scott Smith , Johannes Petrus Verduijn, deceased , Jannetje Maatje van den Berge, executrix , Thomas H. Colle , Gary David Mohr , Gotz Burgfels , Josef Schonlinner
发明人： Robert Scott Smith , Johannes Petrus Verduijn, deceased , Jannetje Maatje van den Berge, executrix , Thomas H. Colle , Gary David Mohr , Gotz Burgfels , Josef Schonlinner
IPC分类号： C01B39/40 , C01B39/02 , C01B39/04 , C01B39/36
CPC分类号： C01B39/02 , C01B39/04 , Y10S423/22 , Y10S423/29
摘要： Large crystal zeolites are prepared by heating a zeolite synthesis mixture under agitation to a temperature equal to or less than the effective nucleation temperature of the zeolite synthesis mixture and thereafter the zeolite synthesis mixture is heated without agitation to a temperature equal to or greater than the effective nucleation temperature of the zeolite synthesis mixture.
摘要翻译：通过在搅拌下将沸石合成混合物加热到等于或小于沸石合成混合物的有效成核温度的温度来制备大型晶体沸石，然后将沸石合成混合物加热而不搅拌至等于或大于有效沸石合成混合物的成核温度。

3. 发明授权

US06627577B2 Hydrocarbon conversion catalyst and its use 失效
标题翻译：烃转化催化剂及其用途
公开(公告)号：US06627577B2
公开(公告)日：2003-09-30
申请号：US10161121
申请日：2002-05-31
申请人： Robert Scott Smith , Gary David Mohr , Jannetje Maatje van den Berge
发明人： Robert Scott Smith , Gary David Mohr , Jannetje Maatje van den Berge
IPC分类号： B01J2718
CPC分类号： C10G49/08 , B01J29/005 , B01J29/84 , B01J29/85 , B01J2229/26 , B01J2229/42 , C10G3/48 , C10G3/49 , C10G3/50 , C10G11/05 , C10G35/095 , C10G2300/1037 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要： There is provided catalysts and conversion processes for converting hydrocarbons using the catalysts. The catalysts comprises a first alumino-phosphospho-molecular sieves and a binder comprising a second alumino-phopho-molecular sieves. Exemplary conversion processes include the conversion of oxygenates to olefins, dewaxing, reforming, dealkylation, dehydrogenation, transalkylation, alkylation, and isomerization.
摘要翻译：提供了使用催化剂转化烃的催化剂和转化方法。催化剂包括第一铝磷磷分子筛和包含第二铝 - 磷光分子筛的粘合剂。示例性的转化方法包括将含氧化合物转化为烯烃，脱蜡，重整，脱烷基化，脱氢，烷基转移，烷基化和异构化。

4. 发明授权

US06864203B2 Aromatic conversion processes and zeolite catalyst useful therein 失效
标题翻译：芳族转化方法和沸石催化剂
公开(公告)号：US06864203B2
公开(公告)日：2005-03-08
申请号：US10086758
申请日：2002-02-28
申请人： Dan Eldon Hendriksen , Gary David Mohr , Johannes Petrus Verduijn , Robert Scott Smith
发明人： Dan Eldon Hendriksen , Gary David Mohr , Johannes Petrus Verduijn , Robert Scott Smith
IPC分类号： B01J29/08 , B01J29/18 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/87 , C07B61/00 , C07C2/66 , C07C2/86 , C07C5/27 , C07C6/12 , C07C15/02 , C07C15/073 , B01J29/06
CPC分类号： C07C6/126 , B01J29/18 , B01J29/40 , B01J29/7007 , B01J29/80 , B01J29/87 , B01J2229/26 , B01J2229/42 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2/865 , C07C2/868 , C07C5/2708 , C07C2529/035 , C07C2529/18 , C07C2529/40 , C07C2529/50 , C07C2529/65 , C07C2529/70 , C07C2529/80 , C07C2529/87 , Y02P20/52 , C07C15/00 , C07C15/08
摘要： A process is provided for the alkylation, transalkylation, or isomerization of aromatic hydrocarbons. The processes comprises contacting aromatic hydrocarbons under conversion conditions with a zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises first crystals of a first large pore zeolite which are bound together by second crystals of a second zeolite.
摘要翻译：提供了芳烃的烷基化，烷基转移或异构化的方法。该方法包括使转化条件下的芳烃与沸石结合的沸石催化剂接触。沸石结合的沸石催化剂包括通过第二沸石的第二晶体结合在一起的第一大孔沸石的第一晶体。

5. 发明授权

US6111157A Aromatic conversion processes and zeolite bound zeolite catalyst useful therein 失效
标题翻译：芳族转化方法和沸石结合的沸石催化剂可用于其中
公开(公告)号：US6111157A
公开(公告)日：2000-08-29
申请号：US865633
申请日：1997-05-29
申请人： Dan Eldon Hendriksen , Gary David Mohr , Johannes Petrus Verduijn , Robert Scott Smith
发明人： Dan Eldon Hendriksen , Gary David Mohr , Johannes Petrus Verduijn , Robert Scott Smith
IPC分类号： B01J29/08 , B01J29/18 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/87 , C07B61/00 , C07C2/66 , C07C2/86 , C07C5/27 , C07C6/12 , C07C15/02 , C07C15/073 , C07C2/68 , C07C5/22 , B01J24/06
CPC分类号： C07C6/126 , B01J29/40 , B01J29/80 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2/865 , C07C2/868 , C07C5/2708 , B01J2229/26 , B01J2229/42 , B01J29/18 , B01J29/7007 , B01J29/87 , C07C2529/035 , C07C2529/18 , C07C2529/40 , C07C2529/50 , C07C2529/65 , C07C2529/70 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： A process is provided for the alkylation, transalkylation, or isomerization of aromatic hydrocarbons. The processes comprises contacting aromatic hydrocarbons under conversion conditions with a zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises first crystals of a first large pore zeolite which are bound together by second crystals of a second zeolite.
摘要翻译：提供了芳烃的烷基化，烷基转移或异构化的方法。该方法包括使转化条件下的芳烃与沸石结合的沸石催化剂接触。沸石结合的沸石催化剂包括通过第二沸石的第二晶体结合在一起的第一大孔沸石的第一晶体。

6. 发明授权

US07906696B2 Process of using zeolite catalyst for hydrocarbon conversion 有权
标题翻译：沸石催化剂用于烃转化的方法
公开(公告)号：US07906696B2
公开(公告)日：2011-03-15
申请号：US11656182
申请日：2007-01-22
申请人： Gopalakrishnan G. Juttu , Robert Scott Smith
发明人： Gopalakrishnan G. Juttu , Robert Scott Smith
IPC分类号： C07C2/52
CPC分类号： B01J29/04 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/74 , C07C15/00
摘要： This invention is for a catalyst for conversion of a hydrocarbonaceous feed. The catalyst is a zeolite aluminosilicate with a silicon to aluminum molar ratio from about 70:1 to about 100:1 on which a noble metal has been deposited. The zeolite catalyst may contain other optional tetravalent and trivalent elements in the zeolite framework. The zeolite structure may be MFI, FAU, TON, MFL, VPI, MEL, AEL, AFI, MWW or MOR. The catalyst is synthesized by preparing a zeolite containing aluminum, silicon and, optionally, other elements, such as germanium, in the framework, depositing a noble metal, such as platinum, on the zeolite and calcining the zeolite. The catalyst may be used for aromatization of alkanes to aromatics. One embodiment is a MFI zeolite catalyst which may be used for the aromatization of alkanes having two to six carbon atoms per molecule to aromatics, such as benzene, toluene and xylenes.
摘要翻译：本发明是用于烃类进料转化的催化剂。该催化剂是一种硅铝酸盐沸石，其硅与铝的摩尔比为约70:1至约100:1，其上沉积有贵金属。沸石催化剂可以在沸石骨架中含有其它任选的四价和三价元素。沸石结构可以是MFI，FAU，TON，MFL，VPI，MEL，AEL，AFI，MWW或MOR。通过在骨架中制备含有铝，硅和任选的其它元素如锗的沸石来合成催化剂，在沸石上沉积贵金属如铂，并煅烧沸石。催化剂可用于将烷烃芳构化成芳族化合物。一个实施方案是MFI沸石催化剂，其可用于每分子具有2-6个碳原子的芳族化合物与芳族化合物如苯，甲苯和二甲苯的芳族化。

7. 发明授权

US07186871B2 Process for alkane aromatization using platinum-zeolite catalyst 有权
标题翻译：使用铂 - 沸石催化剂的烷烃芳构化方法
公开(公告)号：US07186871B2
公开(公告)日：2007-03-06
申请号：US10748418
申请日：2003-12-30
申请人： Scott F. Mitchell , Gopalakrishnan G. Juttu , Robert Scott Smith
发明人： Scott F. Mitchell , Gopalakrishnan G. Juttu , Robert Scott Smith
IPC分类号： C07C2/52
CPC分类号： B01J29/44 , B01J2229/183 , B01J2229/20 , B01J2229/42 , C07C2/00 , C07C15/02 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/12 , C07C2523/42 , C07C2529/44
摘要： Aromatization of alkanes having one to four carbon atoms per molecule to aromatics, such as benzene, toluene and xylenes (BTX), uses a catalyst of a crystalline zeolite on which platinum has been deposited, specifically a platinum-containing ZSM-5. A byproduct of the process is a light gas fraction of methane and ethane. The use of a platinum-containing ZSM-5 catalyst in an alkane aromatization process, such as the Cyclar process, suppresses the formation of methane and increases selectivity to BTX. The high content of ethane relative to methane in the light gas fraction allows this process effluent to be a feedstream for a cracker.
摘要翻译：每分子具有1-4个碳原子的烷烃芳族化合物，例如苯，甲苯和二甲苯（BTX）等芳族化合物，使用已沉积铂的结晶沸石催化剂，特别是含铂的ZSM-5。该方法的副产物是甲烷和乙烷的轻质气体馏分。在烷烃芳构化方法（如Cyclar法）中使用含铂的ZSM-5催化剂可抑制甲烷的形成，并增加对BTX的选择性。轻质气体馏分中乙烷相对于甲烷的高含量使得该工艺流出物成为裂解器的进料流。

8. 发明授权

US06473749B1 System and method for managing file content 失效
标题翻译：用于管理文件内容的系统和方法
公开(公告)号：US06473749B1
公开(公告)日：2002-10-29
申请号：US09510699
申请日：2000-02-22
申请人： Robert Scott Smith , Dale Penndorf , Jason McMinn , Thomas Mathew , Doug Wilson
发明人： Robert Scott Smith , Dale Penndorf , Jason McMinn , Thomas Mathew , Doug Wilson
IPC分类号： G06F1700
CPC分类号： G06F17/30011 , Y10S707/915 , Y10S707/99932
摘要： A system for managing file content, such as Microsoft Powerpoint for Windows™ presentation slides, is provided. The system includes an upload interface that can receive files, such as a file containing slides, from an upload client. The upload interface can extract data structures, such as slides or images, from each file, and index data from each data structure. The system also includes an index system that is connected to the upload interface. The index system can receive the index data from the upload interface and store the index data. A content storage system connected to the upload interface and the index system can receive data structures for storage from the upload interface system, and can provide a storage address for locating each data structure to the index system. A download interface is connected to the content storage system, and can be used to identify data structures matching a query and to download the data structures to a download client.
摘要翻译：提供了一种用于管理文件内容的系统，例如用于Windows（TM）演示幻灯片的Microsoft Powerpoint。该系统包括可以从上传客户端接收诸如包含幻灯片的文件的文件的上载界面。上传界面可以从每个文件中提取数据结构，如幻灯片或图像，以及从每个数据结构索引数据。该系统还包括连接到上传界面的索引系统。索引系统可以从上传接口接收索引数据，存储索引数据。连接到上传接口和索引系统的内容存储系统可以从上传接口系统接收用于存储的数据结构，并且可以提供用于将每个数据结构定位到索引系统的存储地址。下载界面连接到内容存储系统，可用于识别匹配查询的数据结构，并将数据结构下载到下载客户端。

9. 发明授权

US6075175A Isomerization of olefins 有权
标题翻译：烯烃异构化
公开(公告)号：US6075175A
公开(公告)日：2000-06-13
申请号：US163071
申请日：1998-09-29
申请人： Robert Scott Smith , Jos Peter Wristers
发明人： Robert Scott Smith , Jos Peter Wristers
IPC分类号： B01J23/04 , C07C5/25 , C07C5/22 , B01J23/02 , B01J23/70 , C07C5/23
CPC分类号： B01J23/04 , C07C5/2556 , C07C2102/42 , C07C2523/04
摘要： A process for catalytically isomerizing olefins, particularly for isomerizing alkenyl bridged ring compounds to the corresponding alkylidene bridged ring compounds. The catalyst is prepared by forming a dispersion of a metallic alkali metal on a support with simultaneous exposure to oxygen.
摘要翻译：烯烃催化异构化的方法，特别是将烯基桥连环化合物异构化成相应的亚烷基桥环化合物。催化剂通过在支撑体上同时暴露于氧形成金属碱金属的分散体而制备。

10. 发明授权

US6051746A Oxygenate conversions using modified small pore molecular sieve catalysts 失效
标题翻译：使用改性的小孔分子筛催化剂的氧化转化率
公开(公告)号：US6051746A
公开(公告)日：2000-04-18
申请号：US959673
申请日：1997-10-29
申请人： Hsiang-ning Sun , Stephen Neil Vaughn , Robert Scott Smith
发明人： Hsiang-ning Sun , Stephen Neil Vaughn , Robert Scott Smith
IPC分类号： B01J29/06 , B01J29/85 , B01J31/02 , B01J37/08 , C07C1/20 , C07C1/00
CPC分类号： B01J37/084 , B01J29/06 , B01J29/85 , B01J31/0254 , C07C1/20 , B01J2229/10 , B01J2229/12 , B01J2229/14 , B01J2229/30 , B01J2229/34 , B01J2229/40 , C07C2529/00 , C07C2529/85 , Y02P30/42
摘要： The invention relates to a process for converting oxygenated organic material, to olefins using small pore molecular sieve catalysts. More particularly, the invention relates to a method for converting oxygenated organic material to olefins with improved the olefin yields and decreased yields of methane and other light saturate byproducts. The improved yield slate is achieved by treating the small pore molecular sieve catalyst with a modifier selected from the group consisting of polynuclear aromatic heterocyclic compounds with at least three interconnected ring structures having at least one nitrogen atom as a ring substituent, each ring structure having at least five ring members, decomposed derivatives of said polynuclear aromatic heterocyclic compound, and mixtures thereof.
摘要翻译：本发明涉及使用小孔分子筛催化剂将含氧有机材料转化为烯烃的方法。更具体地说，本发明涉及一种将氧化的有机材料转化为烯烃的方法，其具有改善的烯烃产率和降低的甲烷和其它轻质饱和副产物的产率。通过用选自具有至少三个具有至少一个氮原子作为环取代基的至少三个互连环结构的多核芳族杂环化合物的改性剂处理小孔分子筛催化剂来实现改进的产量板，每个环结构具有至少五个环成员，所述多核芳族杂环化合物的分解衍生物及其混合物。

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