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    • 9. 发明申请
    • Allyl acetate purification
    • 醋酸烯丙酯净化
    • US20110152568A1
    • 2011-06-23
    • US12653677
    • 2009-12-17
    • Stephen H. HarrisShaw-Chan Lin
    • Stephen H. HarrisShaw-Chan Lin
    • C07C67/48
    • C07C67/54C07C29/095C07C67/60C07C33/03C07C69/007C07C69/155
    • A process for purifying allyl acetate is disclosed. An acetoxylation mixture is distilled at elevated pressure to remove propylene and generate a first bottoms mixture comprising allyl acetate, acetic acid, acrolein, allyl diacetate, and 3-acetoxypropionaldehyde. The first bottoms mixture is flash vaporized, and the resulting vapor is contacted with a solid acidic catalyst under conditions effective to decompose allyl diacetate and 3-acetoxypropionaldehyde. The flashed product, which comprises allyl acetate, acetic acid, and acrolein, is then distilled to remove acrolein and generate a second bottoms mixture comprising allyl acetate and acetic acid. The second bottoms mixture can be used to manufacture allyl alcohol.
    • 公开了一种纯化乙酸烯丙酯的方法。 在升高的压力下蒸馏乙酰氧基化混合物以除去丙烯,并产生包含乙酸烯丙酯,乙酸,丙烯醛,二乙酸烯丙酯和3-乙酰氧基丙醛的第一底部混合物。 将第一底部混合物闪蒸,并使所得蒸气在有效分解二乙酸烯丙酯和3-乙酰氧基丙醛的条件下与固体酸性催化剂接触。 然后蒸馏含有乙酸烯丙酯,乙酸和丙烯醛的闪蒸产物以除去丙烯醛,并产生包含乙酸烯丙酯和乙酸的第二底部混合物。 第二底部混合物可用于制造烯丙醇。