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    • 2. 发明授权
    • Variable doping of metal plugs for enhanced reliability
    • 金属插头的可变掺杂可提高可靠性
    • US6130156A
    • 2000-10-10
    • US281538
    • 1999-03-30
    • Robert H. HavemannGirish A. DixitStephen W. Russell
    • Robert H. HavemannGirish A. DixitStephen W. Russell
    • H01L23/52H01L21/28H01L21/3205H01L21/768H01L21/441
    • H01L21/76843H01L21/76873H01L21/76876H01L21/76877H01L21/76886H01L2221/1089H01L23/53219H01L23/53233H01L2924/0002
    • A method of fabricating an interconnect wherein there is initially provided a first layer of electrically conductive interconnect (3). A via (7) is formed which is defined by walls extending to the first layer of interconnect. A layer of titanium (9) is formed between the electrically conductive interconnect and the first layer of electrically conductive metal (11). A first layer of electrically conductive metal is formed on the walls of the via having a predetermined etch rate relative to a specific etch species and a second layer of electrically conductive metal (13) is formed on the first layer of electrically conductive metal having an etch rate relative to the specific etch species greater than the first layer and which preferably extends into the via. The first layer of electrically conductive interconnect is preferably aluminum, the first layer of electrically conductive metal is preferably a metal containing from about one percent by weight to about one hundred percent copper and the rest essentially aluminum and the second layer of electrically conductive metal is preferably copper doped aluminum having a lower copper content than the first electrically conductive layer.
    • 一种制造互连的方法,其中最初提供第一层导电互连(3)。 形成通孔(7),其通过延伸到第一互连层的壁限定。 在导电互连和导电金属(11)的第一层之间形成一层钛(9)。 第一层导电金属形成在通孔的壁上,具有相对于特定蚀刻物质的预定蚀刻速率,并且第二层导电金属(13)形成在具有蚀刻的第一导电金属层上 相对于比第一层大的特定蚀刻物质的速率,并且优选地延伸到通孔中。 导电互连的第一层优选为铝,第一层导电金属优选为含有约1%至约100%铜的金属,其余基本上为铝,而第二层导电金属优选为 铜掺杂的铝的铜含量低于第一导电层。
    • 3. 发明授权
    • Hydrogen passivation of chemical-mechanically polished copper-containing layers
    • 化学机械抛光含铜层的氢钝化
    • US06251771B1
    • 2001-06-26
    • US09255466
    • 1999-02-22
    • Patricia B. SmithGirish A. DixitEden ZielinskiStephen W. Russell
    • Patricia B. SmithGirish A. DixitEden ZielinskiStephen W. Russell
    • H01L214763
    • H01L21/3212H01L21/321
    • An embodiment of the instant invention is a method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, the method comprising the steps of: forming a dielectric layer over the semiconductor substrate, the dielectric layer having openings (step 102 of FIG. 1); forming a layer of the metallic conductor on the dielectric layer (step 104 of FIG. 1); removing a portion of the layer of the metallic conductor on the dielectric layer (step 106 of FIG. 1); and subjecting the exposed metallic conductor to a plasma which contains hydrogen or deuterium so as to passivate the metallic conductor (step 110 of FIG. 1). Preferably, the plasma contains a substance selected from the group consisting of: NH3, N2H2, H2S, and CH4, and the metallic conductors are comprised of a material selected from the group consisting of: copper, copper doped aluminum, Ag, Sn, Pb, Ti, Cr, Mg, Ta, and any combination thereof. The step of removing a portion of the layer of the metallic conductor is, preferably, performed by sputtering off a portion of the metallic conductor, chemical-mechanical polishing, etching, or a combination thereof.
    • 本发明的一个实施例是一种在半导体衬底上形成电子器件并具有至少一层金属导体的方法,该方法包括以下步骤:在半导体衬底上形成电介质层,电介质层具有开口( 图1的步骤102); 在介电层上形成金属导体层(图1的步骤104); 去除介电层上的金属导体层的一部分(图1的步骤106); 并将暴露的金属导体经受含有氢或氘的等离子体,以使金属导体钝化(图1的步骤110)。 优选地,等离子体包含选自由NH 3,N 2 H 2,H 2 S和CH 4组成的组的物质,金属导体由选自铜,铜掺杂的铝,Ag,Sn,Pb ,Ti,Cr,Mg,Ta及其任意组合。 优选地,通过溅射金属导体的一部分,化学机械抛光,蚀刻或其组合来去除金属导体的该层的一部分的步骤。