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1. 发明授权

US4088743A Catalytic incineration of hydrogen sulfide from gas streams 失效
标题翻译：从气流催化焚烧硫化氢
公开(公告)号：US4088743A
公开(公告)日：1978-05-09
申请号：US605642
申请日：1975-08-18
申请人： Robert H. Hass , Rowland C. Hansford , Harvey Hennig
发明人： Robert H. Hass , Rowland C. Hansford , Harvey Hennig
IPC分类号： B01D53/52 , C01B17/50 , B01D53/34
CPC分类号： B01D53/52 , Y10S423/19
摘要： A process for the conversion of H.sub.2 S to SO.sub.2 in a feed gas containing H.sub.2 S is effected by oxidation with air or oxygen at temperatures between 300.degree. and 900.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. The preferred catalyst comprises between 5 and 15 wt.% V.sub.2 O.sub.5 on hydrogen mordenite or alumina. Hydrogen, carbon monoxide and light hydrocarbons present in the feed gas are not oxidized. The invention is especially contemplated for use in treating waste gases from geothermal steam power plants.
摘要翻译：在含有H 2 S的进料气体中将H 2 S转化为SO 2的方法通过在空气或氧气下在300-900°F的温度下氧化来实现。氧化是在极其稳定的包含氧化物和氧化物的氧化催化剂的存在下进行的， /或负载在非碱性多孔难熔氧化物上的钒的硫化物。优选的催化剂在氢丝光沸石或氧化铝上含有5至15重量％的V 2 O 5。进料气中存在的氢，一氧化碳和轻烃不被氧化。本发明特别考虑用于处理地热蒸汽发电厂的废气。

2. 发明授权

US4311683A Process for removal of hydrogen sulfide from gas streams 失效
标题翻译：从气流中除去硫化氢的方法
公开(公告)号：US4311683A
公开(公告)日：1982-01-19
申请号：US161694
申请日：1980-06-23
申请人： Robert H. Hass , Rowland C. Hansford
发明人： Robert H. Hass , Rowland C. Hansford
IPC分类号： C01B17/04
CPC分类号： C01B17/0465
摘要： A process for the removal of H.sub.2 S from a feed gas, and the production of sulfur therefrom, is effected by oxidation with oxygen and/or SO.sub.2 at temperatures between 250.degree. and 450.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. Sulfur deposition and consequent catalyst deactivation are prevented by maintaining the partial pressure of free sulfur in the oxidation reactor below that necessary for condensation. H.sub.2, CO, and light hydrocarbons present in the feed gas are not oxidized. Typical uses of the process include the removal of H.sub.2 S and the production of sulfur from sour natural gases or gases obtained from the gasification of coal.Feed gases which contain SO.sub.2 and H.sub.2 S in mole ratios greater than 0.5, or which contain other gaseous sulfur compounds such as COS, CS.sub.2, SO.sub.3 and mercaptans, can be desulfurized by hydrogenating all of such sulfur components to H.sub.2 S and subsequently removing the H.sub.2 S from the hydrogenated feed gas by the oxidation process of the invention. This hydrogenation-oxidation combination is especially contemplated for the desulfurization of Claus tail gases and stack gas effluents.
摘要翻译：从进料气体中除去H 2 S和从其中产生硫的方法是通过在250-450°F的温度下用氧和/或SO 2进行氧化来实现的。氧化是在非常稳定的条件下进行的包含负载在非碱性多孔难熔氧化物上的钒的氧化物和/或硫化物的氧化催化剂。通过将氧化反应器中的游离硫的分压维持在低于冷凝所需的程度来防止硫沉积和随之而来的催化剂失活。存在于进料气体中的H 2，CO和轻烃不被氧化。该方法的典型用途包括从酸性天然气或煤气化获得的气体中除去H 2 S和产生硫。含有大于0.5摩尔比的SO2和H2S的进料气体或含有其它气态硫化合物如COS，CS2，SO3和硫醇的进料气体可以通过将所有这些硫组分氢化成H 2 S并随后从H 2 S中除去H 2 S来脱硫氢化原料气通过本发明的氧化方法。这种氢化 - 氧化组合特别适用于克劳斯尾气和烟道气体废气的脱硫。

3. 发明授权

US4243647A Process for removal of hydrogen sulfide from gas streams 失效
标题翻译：从气流中除去硫化氢的方法
公开(公告)号：US4243647A
公开(公告)日：1981-01-06
申请号：US700513
申请日：1976-06-28
申请人： Robert H. Hass , Rowland C. Hansford
发明人： Robert H. Hass , Rowland C. Hansford
IPC分类号： C01B17/04
CPC分类号： C01B17/0465
摘要： A process for the removal of H.sub.2 S from a feed gas, and the production of sulfur therefrom, is effected by oxidation with oxygen and/or SO.sub.2 at temperatures between 250.degree. and 450.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. Sulfur deposition and consequent catalyst deactivation are prevented by maintaining the partial pressure of free sulfur in the oxidation reactor below that necessary for condensation. H.sub.2, CO, and light hydrocarbons present in the feed gas are not oxidized. Typical uses of the process include the removal of H.sub.2 S and the production of sulfur from sour natural gases or gases obtained from the gasification of coal.Feed gases which contain SO.sub.2 and H.sub.2 S in mole ratios greater than 0.5, or which contain other gaseous sulfur compounds such as COS, CS.sub.2, SO.sub.3 and mercaptans, can be desulfurized by hydrogenating all of such sulfur components to H.sub.2 S and subsequently removing the H.sub.2 S from the hydrogenated feed gas by the oxidation process of the invention. This hydrogenation-oxidation combination is especially contemplated for the desulfurization of Claus tail gases and stack gas effluents.
摘要翻译：从进料气体中除去H 2 S和从其中产生硫的方法是通过在250-450°F的温度下用氧和/或SO 2进行氧化来实现的。氧化是在非常稳定的条件下进行的包含负载在非碱性多孔难熔氧化物上的钒的氧化物和/或硫化物的氧化催化剂。通过将氧化反应器中的游离硫的分压维持在低于冷凝所需的程度来防止硫沉积和随之而来的催化剂失活。存在于进料气体中的H 2，CO和轻烃不被氧化。该方法的典型用途包括从酸性天然气或煤气化获得的气体中除去H 2 S和产生硫。含有大于0.5摩尔比的SO2和H2S的进料气体或含有其它气态硫化合物如COS，CS2，SO3和硫醇的进料气体可以通过将所有这些硫组分氢化成H 2 S并随后从H 2 S中除去H 2 S来脱硫氢化原料气通过本发明的氧化方法。这种氢化 - 氧化组合特别适用于克劳斯尾气和烟道气体废气的脱硫。

4. 发明授权

US4169136A Catalytic incineration of hydrogen sulfide from gas streams 失效
标题翻译：从气流催化焚烧硫化氢
公开(公告)号：US4169136A
公开(公告)日：1979-09-25
申请号：US787904
申请日：1977-04-15
申请人： Robert H. Hass , Rowland C. Hansford
发明人： Robert H. Hass , Rowland C. Hansford
IPC分类号： B01D53/52 , C01B17/50 , B01D53/34
CPC分类号： B01D53/52 , C01B17/508 , Y10S423/19
摘要： A process for the conversion of H.sub.2 S to SO.sub.2 in a feed gas containing H.sub.2 S is effected by oxidation with air or oxygen at temperatures between 300.degree. and 900.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. The preferred catalyst comprises between 5 and 15 wt. % V.sub.2 O.sub.5 on hydrogen mordenite or alumina. Hydrogen, carbon monoxide, light hydrocarbons, and ammonia present in the feed gas are not oxidized. The invention is especially contemplated for use in treating waste gases from geothermal steam power plants.
摘要翻译：在含有H 2 S的进料气体中将H 2 S转化为SO 2的方法通过在空气或氧气下在300-900°F的温度下氧化来实现。氧化是在极其稳定的氧化催化剂的存在下进行的，包括氧化物和 /或负载在非碱性多孔难熔氧化物上的钒的硫化物。优选的催化剂包含5至15wt。％V2O5对氢丝光沸石或氧化铝。进料气体中存在的氢，一氧化碳，轻质烃和氨不被氧化。本发明特别考虑用于处理地热蒸汽发电厂的废气。

5. 发明授权

US4246141A Catalyst for incinerating H.sub.2 S to SO.sub.2 失效
标题翻译：将H2S焚烧成SO2的催化剂
公开(公告)号：US4246141A
公开(公告)日：1981-01-20
申请号：US36801
申请日：1979-05-07
申请人： Robert H. Hass , Rowland C. Hansford
发明人： Robert H. Hass , Rowland C. Hansford
IPC分类号： B01J29/26 , C01B17/50
CPC分类号： B01J29/26 , C01B17/508
摘要： A catalyst for incinerating H.sub.2 S to SO.sub.2 in the temperature range of 300.degree.-900.degree. F. comprises a vanadium oxide or sulfide supported on a refractory oxide comprising hydrogen mordenite.
摘要翻译：在300-900°F的温度范围内将H 2 S焚烧成SO 2的催化剂包括负载在包含氢丝光沸石的难熔氧化物上的氧化钒或硫化物。

6. 发明授权

US4124629A Thermally stable coprecipitated catalysts useful for methanation and other reactions 失效
标题翻译：用于甲烷化和其他反应的热稳定性共沉淀催化剂
公开(公告)号：US4124629A
公开(公告)日：1978-11-07
申请号：US758042
申请日：1977-01-10
申请人： Rowland C. Hansford
发明人： Rowland C. Hansford
IPC分类号： B01J23/74 , B01J23/75 , B01J23/755 , B01J37/03 , C07C1/02 , C07C1/04 , C07C1/10
CPC分类号： B01J23/755 , B01J23/74 , B01J23/75 , B01J37/03 , C07C1/02 , C07C2521/04 , C07C2523/745 , C07C2523/75 , C07C2523/755
摘要： Catalysts having a high degree of thermal stability, comprising alumina and one or more of the iron group metals are prepared from aqueous solutions containing a dissolved aluminum salt, a salt of at least one of the iron group metals and a delayed precipitant such as urea. The solution is heated to a temperature sufficient to hydrolyze the delayed precipitant with resultant liberation of ammonia and carbon dioxide homogeneously throughout the solution, until the pH of the solution rises sufficiently to effect coprecipitation of the metal salts as hydroxides and/or carbonates. The resulting coprecipitate is then recovered, washed, dried, shaped and calcined in conventional fashion to obtain a final product which, after hydrogen-reduction is very active, and displays much greater thermal stability than corresponding prior art catalysts prepared by non-homogeneous coprecipitation with alkaline, ionic reagents such as sodium carbonate, ammonium hydroxide, or ammonium carbonate. The nickel-containing catalysts are particularly useful for methanation, but they are all useful in a variety of other reactions.
摘要翻译：含有氧化铝和一种或多种铁族金属的高热稳定性的催化剂由含有溶解的铝盐，至少一种铁族金属的盐和延迟沉淀剂如尿素的水溶液制备。将溶液加热到足以水解延迟的沉淀剂的温度，同时在整个溶液中均匀释放氨和二氧化碳，直到溶液的pH升高到足以实现金属盐作为氢氧化物和/或碳酸盐的共沉淀。然后将所得的共沉淀物以常规方式回收，洗涤，干燥，成型和煅烧，以获得最终产物，其在氢还原非常活泼之后，并且显示出比通过非均相共沉淀制备的相应的现有技术催化剂大得多的热稳定性，碱性离子试剂如碳酸钠，氢氧化铵或碳酸铵。含镍催化剂特别可用于甲烷化，但它们都可用于各种其他反应。

7. 发明授权

US3988263A Thermally stable coprecipitated catalysts useful for methanation and other reactions 失效
标题翻译：用于甲烷化和其他反应的热稳定性共沉淀催化剂
公开(公告)号：US3988263A
公开(公告)日：1976-10-26
申请号：US621769
申请日：1975-10-14
申请人： Rowland C. Hansford
发明人： Rowland C. Hansford
IPC分类号： B01D53/86 , B01J23/06 , B01J23/70 , B01J23/72 , B01J23/75 , B01J23/755 , B01J23/80 , B01J37/03 , C07C1/04 , C07C45/00 , B01J21/04 , B01J23/74
CPC分类号： B01J23/72 , B01D53/864 , B01J23/06 , B01J23/70 , B01J23/75 , B01J23/755 , B01J23/80 , B01J37/03 , C07C1/0445 , C07C2521/04 , C07C2523/75
摘要： Catalysts having a high degree of thermal stability, comprising alumina and one or more of the metals iron, cobalt, nickel, copper and zinc, are prepared from aqueous solutions containing a dissolved aluminum salt, a salt of at least one of the aforesaid metals in divalent form, and a delayed precipitant such as urea. With all components in homogeneous solution at a relatively low pH and temperature, the solution is heated to a temperature sufficient to hydrolyze the delayed precipitant with resultant liberation of ammonia and carbon dioxide homogeneously throughout the solution, until the pH of the solution rises sufficiently to effect coprecipitation of the metal salts as hydroxides and/or carbonates. The resulting coprecipitate is then recovered, washed, dried, shaped and calcined in conventional fashion to obtain a final product which is very active, and displays much greater thermal stability than corresponding prior art catalysts prepared by non-homogeneous coprecipitation with alkaline, ionic reagents such as sodium carbonate, ammonium hydroxide, or ammonium carbonate. The nickel-containing catalysts are particularly useful for methanation, but they are all useful in a variety of other reactions.
摘要翻译：包含氧化铝和一种或多种金属铁，钴，镍，铜和锌的热稳定性的催化剂由含有溶解的铝盐，至少一种前述金属的盐的水溶液制备，二价形式和延迟沉淀剂如尿素。将均匀溶液中的所有组分在相对低的pH和温度下，将溶液加热至足以水解延迟沉淀剂的温度，同时在整个溶液中均匀释放氨和二氧化碳，直到溶液的pH升高到足以达到作为氢氧化物和/或碳酸盐的金属盐的共沉淀。然后将所得的共沉淀物以常规方式回收，洗涤，干燥，成形并煅烧以获得非常活泼的最终产物，并且显示出比用碱性离子试剂如非均相共沉淀制备的相应的现有技术催化剂大得多的热稳定性作为碳酸钠，氢氧化铵或碳酸铵。含镍催化剂特别可用于甲烷化，但它们都可用于各种其他反应。

8. 发明授权

US3963644A Conversion catalysts 失效
标题翻译：转化催化剂
公开(公告)号：US3963644A
公开(公告)日：1976-06-15
申请号：US433739
申请日：1974-01-09
申请人： Rowland C. Hansford
发明人： Rowland C. Hansford
IPC分类号： B01J29/08 , C10G47/20 , B01J29/06
CPC分类号： B01J29/084 , C10G47/20
摘要： Hydrocracking catalysts are disclosed consisting essentially of a physical, particle-form mixture of (1) a crystalline alumino-silicate component having a sodium content of less than 4 percent by weight, and (2) a hydrogenation component comprising a predominant proportion of a porous support, other than a crystalline aluminosilicate, and a minor proportion of at least one constituent exhibiting hydrogenation activity. Hydrocracking processes using such catalysts are also disclosed.
摘要翻译：公开了加氢裂化催化剂，其基本上由（1）钠含量小于4重量％的结晶铝硅酸盐组分的物理，颗粒形式的混合物组成，和（2）包含主要部分的多孔载体，除了结晶硅铝酸盐，和少量至少一种具有氢化活性的组分。还公开了使用这种催化剂的加氢裂化方法。

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