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1. 发明授权

US5754271A Heterocyclic chromenes and their use in the field of ophthalmic optics 失效
标题翻译：杂环色烯及其在眼科光学领域的应用
公开(公告)号：US5754271A
公开(公告)日：1998-05-19
申请号：US657401
申请日：1996-06-03
申请人： Robert Guglielmetti , Jean Luc Pozzo , Andre Samat
发明人： Robert Guglielmetti , Jean Luc Pozzo , Andre Samat
IPC分类号： C07D491/048 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C07D513/04 , C09D5/00 , C09D7/12 , C09K9/02 , G03C1/685 , G03C1/73 , G02C7/10 , C07D491/02 , C07D513/02
CPC分类号： C07D491/04 , C07D493/04 , C07D513/04 , G03C1/685 , G03C1/73
摘要： The invention relates to photochromic compounds of general formula: ##STR1## wherein R.sup.a, R.sup.b and R.sup.c is denote hydrogen; alkyl; aryl; OR, SR, COR or COOR, in which R denotes hydrogen, alkyl or aryl, amino of formula NR.sub.1 R.sub.2 in which R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or an aryl; a halogen atom; a mono- or polyhaloalkyl group; or an NO.sub.2, CN or SCN group; n and m denote integers from 1 to 5; p is equal to 1 or 2; and H is a 5-members aromatic heterocycle containing one or more heteroatoms selected from nitrogen, oxygen and sulfur, these heterocyclic nuclei being eventually substituted by one or more alkyl, alkoxy, amino, aryl or aralkyl groups or condensed with a phenyl nucleus, a substituted phenyl nucleus or a 6-members cycloaliphatic nucleus and to their use in ophtalmic optics.
摘要翻译：本发明涉及以下通式的光致变色化合物：其中R a，R b和R c表示氢; 烷基; 芳基; OR，SR，COR或COOR，其中R表示氢，烷基或芳基，式NR1R2的氨基，其中R1和R2表示氢，烷基，环烷基或芳基; 卤素原子; 单卤代烷基或多卤代烷基; 或NO2，CN或SCN基团; n和m表示1至5的整数; p等于1或2; 并且H是含有一个或多个选自氮，氧和硫的杂原子的5-元芳族杂环，这些杂环核最终被一个或多个烷基，烷氧基，氨基，芳基或芳烷基取代或与苯基核稠合，取代的苯基核或6个成员的脂环族核，并用于眼底光学。

2. 发明授权

US5631720A Ophthalmic lenses with heterocyclic chromene compounds 失效
标题翻译：具有杂环色烯化合物的眼科镜片
公开(公告)号：US5631720A
公开(公告)日：1997-05-20
申请号：US625727
申请日：1996-03-29
申请人： Robert Guglielmetti , Jean L. Pozzo , Andre Samat
发明人： Robert Guglielmetti , Jean L. Pozzo , Andre Samat
IPC分类号： C07D491/048 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C07D513/04 , C09D5/00 , C09D7/12 , C09K9/02 , G03C1/685 , G03C1/73 , G02C7/10
CPC分类号： C07D491/04 , C07D493/04 , C07D513/04 , G03C1/685 , G03C1/73
摘要： The invention relates to ophthalmic lenses comprising a transparent organic polymer material and photochromic compounds of general formula ##STR1## wherein R.sup.a, R.sup.b and R.sup.c are hydrogen; alkyl; aryl; OR, SR, COR or COOR, where R denotes hydrogen, alkyl or aryl, amino of formula NR.sub.1 R.sub.2 where R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or an aryl; a halogen atom; a mono- or polyhaloalkyl group; or an NO.sub.2, CN or SCN group; n and m denote integers from 1 to 5; p is equal to 1 or 2; and H is an aromatic heterocycle having the general formula: ##STR2## wherein: X, Y and Z represent independently of each other, a CR.sub.8 radical or a nitrogen atom, and one or two of X, Y and Z is a nitrogen atom and R.sub.8 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl; and R.sub.4 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl.
摘要翻译：本发明涉及包含透明有机聚合物材料和通式（I）的光致变色化合物的眼用透镜，其中Ra，Rb和Rc是氢; 烷基; 芳基; OR，SR，COR或COOR，其中R表示氢，烷基或芳基，式NR1R2的氨基，其中R 1和R 2表示氢，烷基，环烷基或芳基; 卤素原子; 单卤代烷基或多卤代烷基; 或NO2，CN或SCN基团; n和m表示1至5的整数; p等于1或2; H是具有以下通式的芳香族杂环：相互间的相互键合，CR8基或氮原子，X，Y和Z中的一个或两个为氮原子，R8选自氢，C1 -C 1-6烷基和苯基; 并且R 4选自氢，C 1 -C 6烷基和苯基。

3. 发明授权

US6136968A Homoazaadamantane spirooxazines and their use in the field of ophthalmic optics 失效
标题翻译： Homoaza金刚烷螺恶唑嗪及其在眼科光学领域的应用
公开(公告)号：US6136968A
公开(公告)日：2000-10-24
申请号：US230672
申请日：1999-01-29
申请人： Karine Chamontin , Vladimir Lokshin , Andre Samat , Robert Guglielmetti
发明人： Karine Chamontin , Vladimir Lokshin , Andre Samat , Robert Guglielmetti
IPC分类号： G02C7/10 , C07D498/10 , C07D498/20 , C08K5/35 , C08L101/00 , G02B5/23 , G03C1/685
CPC分类号： C07D498/10
摘要： Described are novel reversible photochromic compounds of the homoazaadamantane spirooxazine family. Certain substituents are present on the nitrogen atom of the homoazaadamantane portion of the compound and on the benzene ring fused to the oxazine portion of the compound. These compounds may be represented by the following formula: Also described are compositions, e.g., solvent based mediums and polymerized organic materials, used to produce ophthalmic components, that contain the homoazaadamantane compounds with or without other photochromic compounds.
摘要翻译： PCT No.PCT / FR97 / 01196 Sec。 371日期1999年1月29日第 102（e）1999年1月29日PCT 1997年7月3日PCT公布。出版物WO98 / 04563 日期1998年2月5日描述了高加索金刚烷螺恶嗪族的新型可逆光致变色化合物。某些取代基存在于化合物的高加金刚烷部分的氮原子上和与化合物的恶嗪部分稠合的苯环上。这些化合物可以由下式表示：还描述了用于生产眼用组分的组合物，例如溶剂型介质和聚合的有机材料，其含有具有或不具有其它光致变色化合物的高杂金刚烷化合物。

4. 发明授权

US6019914A Photochromic spirooxazine compounds, their use in the field of ophthalmic optics 失效
标题翻译：光致变色螺恶嗪化合物，它们在眼科光学领域的应用
公开(公告)号：US6019914A
公开(公告)日：2000-02-01
申请号：US926034
申请日：1997-09-09
申请人： Vladimir Lokshin , Karine Chamontin , Robert Guglielmetti , Andre Samat
发明人： Vladimir Lokshin , Karine Chamontin , Robert Guglielmetti , Andre Samat
IPC分类号： G03C1/685 , C07D498/10 , C08J5/00 , C08K5/357 , C07D498/20
CPC分类号： C07D498/10
摘要： The new photochromic compounds according to the invention, of the spiro[indoline-[2,3']-benzoxazine] type, include at least one electron-withdrawing group attached to the benzoxazine structure in 5' or 6' position by a chain containing at least one ethylenic double bond.Application to ophthalmic optics.
摘要翻译：根据本发明的螺[二氢吲哚并[2,3'] - 苯并嗪]型的新型光致变色化合物包括至少一个吸电子基团，其通过含有链的5'或6'位连接到5'或6'位的苯并恶嗪结构至少一个烯属双键。应用于眼科光学。

5. 发明授权

US06312811B1 Photochromic naphtho [2,1-b]pyran compounds containing bithienyl or terthienyl substituents, process for their manufacture, and photochromic materials and articles obtained 失效
标题翻译：含有二噻吩基或三噻吩基取代基的光致变色萘并[2,1-b]吡喃化合物，其制备方法和光致变色材料和制品
公开(公告)号：US06312811B1
公开(公告)日：2001-11-06
申请号：US09349686
申请日：1999-07-08
申请人： Michel Frigoli , Nicole Rebiere-Galy , Corinne Moustrou , Andre Samat , Robert Guglielmetti
发明人： Michel Frigoli , Nicole Rebiere-Galy , Corinne Moustrou , Andre Samat , Robert Guglielmetti
IPC分类号： C03C406
CPC分类号： C07D409/14 , B32B17/10486 , C09K9/02 , G02B5/23 , Y10T428/31504
摘要： The photochromic compounds of the invention correspond to the formula: in which Th2 represents a bithienyl group in one of the positions 5 to 10 of the naphthenic ring system system, R1 denotes a bithienyl or trithienyl group and R2 denotes a bithienyl, trithienyl, aryl, naphthyl, thienyl, furyl, pyrrolyl or N-alkylpyrrolyl group.
摘要翻译：本发明的光致变色化合物对应于下列通式：其中Th2表示环烷系体系的5至10位中的二噻吩基，R1表示双噻吩基或三噻吩基，R2表示双噻吩基，三噻吩基，芳基，萘基，噻吩基，呋喃基，吡咯基或N-烷基吡咯基。

6. 发明授权

US5936016A Photochromic compounds and methods for their use 失效
标题翻译：光致变色化合物及其使用方法
公开(公告)号：US5936016A
公开(公告)日：1999-08-10
申请号：US776025
申请日：1997-01-29
申请人： Pierre Lareginie , Vladimir Lokshin , Andre Samat , Robert Guglielmetti , Elena Zaballos Garcia
发明人： Pierre Lareginie , Vladimir Lokshin , Andre Samat , Robert Guglielmetti , Elena Zaballos Garcia
IPC分类号： G02C7/10 , C07D498/10 , C09K9/02 , G02B1/04 , G02B1/10 , G02B5/23 , G03C1/685 , C08K5/34 , C07D265/00
CPC分类号： C07D498/10 , G03C1/685
摘要： The present invention relates to photochromic compounds of spiro�indoline�2,3'!-naphthoxazine! structure, characterized in that they contain, in the 6' position, a group R.sub.6 chosen from the following groups: cyano and phenylsulfonyl linked via the sulfur atom to carbon 6', and methods of using such compounds.
摘要翻译： PCT No.PCT / FR95 / 01031 Sec。 371日期1997年1月23日 102（e）日期1997年1月23日PCT提交1995年7月31日PCT公布。公开号WO96 / 04590 日期：1996年2月15日本发明涉及螺[二氢吲哚[2,3'] - 萘并恶嗪]结构的光致变色化合物，其特征在于它们在6'位含有选自以下基团的基团R6：氰基和通过硫原子与碳6'连接的苯基磺酰基，以及使用这些化合物的方法。

7. 发明授权

US5529725A Spirooxazines and use thereof in the field of ophthalmic optics 失效
标题翻译：螺恶嗪及其在眼科光学领域的应用
公开(公告)号：US5529725A
公开(公告)日：1996-06-25
申请号：US343958
申请日：1994-11-17
申请人： Robert Guglielmetti , Andre Samat , Pierre Lareginie
发明人： Robert Guglielmetti , Andre Samat , Pierre Lareginie
IPC分类号： C07D498/10 , C07D498/20 , C09K9/02 , G02F1/17 , G03C1/685 , G02B5/23 , C07D265/00
CPC分类号： C07D498/10 , G03C1/685
摘要： The invention relates to photochromic compounds of general formula: ##STR1## in which: R.sup.a and R.sup.b denote hydrogen; alkyl; OR, SR, COR or COOR where R denotes hydrogen, alkyl, aryl or heteroaryl; a group NR.sub.1 R.sub.2 where R.sub.1 R.sub.2 denotes hydrogen, C.sub.4 -C.sub.7 alkyl or cycloalkyl, aryl, or form with the nitrogen a C.sub.4 -C.sub.7 heterocycle; NO.sub.2, CN, SCN or a halogen; a group SO.sub.3 R' where R' denotes hydrogen or an alkali metal; a mono- or polyhaloalkyl; m denotes an integer from 1 to 4 and n is equal to 1 or 2;Cy denotes an aromatic ring or an aromatic or non-aromatic heterocycle;R.sup.c denotes an alkyl, allyl, phenyl or arylalkyl group which is mono- or disubstituted with alkyl, alkoxy or NO.sub.2 ; an alicyclic, an aliphatic hydrocarbon containing one or more hetero atoms;R.sup.d, R.sup.e, R.sup.f and R.sup.g denote hydrogen, alkyl, alkoxy or thioalkyl or form in pairs a 4- to 7-membered cycloalkyl possibly containing hetero atoms which are optionally condensed with an aromatic ring; R.sup.h denotes hydrogen or forms with R.sup.d a 5- or 6-membered cycloalkyl; and the use thereof in ophthalmic optics.
摘要翻译：本发明涉及以下通式的光致变色化合物：其中：R a和R b表示氢; 烷基; OR，SR，COR或COOR，其中R表示氢，烷基，芳基或杂芳基; NR1R2基团，其中R1R2表示氢，C4-C7烷基或环烷基，芳基或与氮一起形成C4-C7杂环; NO2，CN，SCN或卤素; SO 3 R'基团，其中R'表示氢或碱金属; 单或多卤代烷基; m表示1〜4的整数，n表示1或2; Cy表示芳香环或芳族或非芳族杂环; Rc表示被烷基，烷氧基或NO 2单取代或二取代的烷基，烯丙基，苯基或芳基烷基; 脂环族，含有一个或多个杂原子的脂族烃; Rd，Re，Rf和Rg表示氢，烷基，烷氧基或硫代烷基，或成对形成可能含有任选与芳环稠合的杂原子的4-至7-元环烷基; Rh表示氢或与Rd形成5-或6-元环烷基; 以及其在眼科光学中的应用。

8. 发明授权

US5527911A Heterocyclic chromenes 失效
标题翻译：杂环色烯
公开(公告)号：US5527911A
公开(公告)日：1996-06-18
申请号：US33893
申请日：1993-03-19
申请人： Robert Guglielmetti , Jean L. Pozzo , Andre Samat
发明人： Robert Guglielmetti , Jean L. Pozzo , Andre Samat
IPC分类号： C07D491/048 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C07D513/04 , C09D5/00 , C09D7/12 , C09K9/02 , G03C1/685 , G03C1/73 , C07D491/12
CPC分类号： C07D491/04 , C07D493/04 , C07D513/04 , G03C1/685 , G03C1/73
摘要： The invention relates to photochromic compounds of general formula: ##STR1## in which R.sup.a, R.sup.b and R.sup.c denote hydrogen; alkyl; aryl; OR, SR, COR or COOR, in which R denotes hydrogen, alkyl or aryl, amino of formula NR.sub.1 R.sub.2 in which R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl, aryl, R.sub.1 and R.sub.2 being capable of forming with the nitrogen atom, a heterocycle containing 4 to 7 members and capable of containing, in addition, one or more heteroatoms chosen from nitrogen, oxygen, sulfur, a halogen atom; a mono- or polyhaloalkyl group; an NO.sub.2, CN or SCN group; n and m denote integers from 1 to 5 depending on the number of substitutions on the nucleus and p may be equal to 1 or 2 depending on the number of substitutions on the nucleus; H is an aromatic heterocycle having 4 to 7 members containing one or more heteroatoms chosen from nitrogen, oxygen, sulfur, these heterocyclic nuclei being capable of being substituted by one or more alkyl, alkoxy, amino, aryl or aralkyl groups or condensed with an aromatic nucleus, and to their use in ophthalmic optics.
摘要翻译：本发明涉及以下通式的光致变色化合物：其中Ra，Rb和Rc表示氢; 烷基; 芳基; OR，SR，COR或COOR，其中R表示氢，烷基或芳基，式NR1R2的氨基，其中R1和R2表示氢，烷基，环烷基，芳基，R1和R2能够与氮原子一起形成杂环含有4至7个成员并且还能够另外含有一个或多个选自氮，氧，硫，卤素原子的杂原子; 单卤代烷基或多卤代烷基; NO2，CN或SCN组; n和m表示1至5的整数，这取决于核上的取代数，p可以等于1或2，这取决于核上的取代数目; H是具有4至7个成员的芳族杂环，其含有一个或多个选自氮，氧，硫的杂原子，这些杂环核能够被一个或多个烷基，烷氧基，氨基，芳基或芳烷基取代或与芳族稠合核，以及它们在眼科光学中的应用。

9. 发明授权

US4052218A Novel spiro-heterocyclic compounds, their preparation, and use thereof in a thermographic recording material 失效
标题翻译：新型螺旋化合物，其制备方法及其在热成像记录材料中的应用
公开(公告)号：US4052218A
公开(公告)日：1977-10-04
申请号：US579119
申请日：1975-05-19
申请人： Andre Samat , Robert Guglielmetti , Jacques Metzger
发明人： Andre Samat , Robert Guglielmetti , Jacques Metzger
IPC分类号： B41M5/28 , C07D277/64 , C07D513/10 , G03C1/02
CPC分类号： C07D513/10 , B41M5/284 , C07D277/64
摘要： The invention relates to novel thermochromic spiro heterocyclic compounds having one or the other of the following formulae: ##STR1## where R.sub.1 denotes hydrogen atoms or one or more electron-donor groups in positions 5, 6, 7 and 8 in formula (1); R.sub.i ' denotes hydrogen atoms or one or more electron-donor or electron-acceptor groups in positions 4', 5', 6' and 7' and 4", 5", 6" and 7" in formulae (1) and (2); and R.sub.j denotes hydrogen atoms or one or more electron-donor groups in positions 5, 6, 7, 8, 9 and 10 in formula (2). Use in thermographic recording material.

10. 发明授权

US5604280A Ring spiro [fluorene-[2H]-benzopyranes] and their use in ophthalmic optics 失效
标题翻译：环螺[芴 - [2H] - 苯并吡喃]及其在眼科光学中的应用
公开(公告)号：US5604280A
公开(公告)日：1997-02-18
申请号：US417321
申请日：1995-04-05
申请人： Jean L. Pozzo , Robert Guglielmetti , Andr e Samat , Vladimir Lokshin , Guena elle Harie
发明人： Jean L. Pozzo , Robert Guglielmetti , Andr e Samat , Vladimir Lokshin , Guena elle Harie
IPC分类号： G02C7/02 , C07D311/96 , C07D491/052 , C07D491/10 , C07D491/107 , C07D493/10 , C07D498/04 , C07D513/04 , C08K5/1545 , C08K5/3432 , C08K5/3442 , C08K5/3465 , C08K5/35 , C08K5/353 , C08K5/45 , C08K5/47 , C09K9/02 , G02B1/04 , G02F1/17 , G03C1/685 , C07D311/92 , C08K5/15 , C08K5/3495
CPC分类号： C07D491/10 , C07D311/96 , C07D493/10 , G03C1/685 , Y10T428/31
摘要： The invention concerns photochromic compounds with general formula (I): ##STR1## where R.sup.a, R.sup.b and R.sup.c represent hydrogen; alkyl, aryl, OR, SR, COR or COOR, where R represents hydrogen, alkyl or aryl, amino with formula NR.sub.1 R.sub.2, where R.sub.1 and R.sub.2 each represent hydrogen, alkyl, cycloalkyl, or aryl, R.sub.1 and R.sub.2 may together form a heterocycle containing four to seven members with the nitrogen atom and may intracyclically contain one or more heteroatoms selected from nitrogen, oxygen, sulphur, or a halogen atom; a mono- or polyhaloalkyl; an NO.sub.2, CN or SCN group; n and m represent whole numbers from 1 to 4 depending on the number of substitutions on the nucleus and p is 1 or 2 depending on the number of substitutions on the nucleus; H is either an aromatic heterocycle condensed at the 5,6 or 6,7 positions, containing five or six members comprising one or more heteroatoms selected from nitrogen, selenium, oxygen and sulphur or an aromatic carbocycle containing five or six members, condensed at the 7,8 positions; all optionally substituted. The invention also relates to the use of these compounds in ophthalmic optics.
摘要翻译：本发明涉及通式（I）的光致变色化合物：其中R a，R b和R c表示氢; 烷基，芳基，OR，SR，COR或COOR，其中R表示氢，烷基或芳基，具有式NR1R2的氨基，其中R1和R2各自表示氢，烷基，环烷基或芳基，R1和R2可以一起形成含四至七个具有氮原子的成员，并且可以内环内含有一个或多个选自氮，氧，硫或卤素原子的杂原子; 单或多卤代烷基; NO2，CN或SCN组; n和m表示1到4的整数，这取决于核上的取代数，p取决于细胞核上的取代数目，为1或2; H是在5,6或6,7位稠合的芳族杂环，其含有五或六个包含一个或多个选自氮，硒，氧和硫的杂原子或含有五或六个成员的芳族碳环，其在 7,8个职位; 全部可以被取代。本发明还涉及这些化合物在眼科光学中的用途。

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